DOI: 10.4028/www.scientific.net/msf.610-613.506. Investigation on Lithiation Mechanism of Interphase Ni3Sn4 Alloy Used as Anode Material for Lithium-Ion Batteries

Investigation on Lithiation Mechanism of Interphase Ni3Sn4 Alloy Used as Anode Material for Lithium-Ion Batteries

10.4028/www.scientific.net/msf.610-613.506

Crossref journal-article

Trans Tech Publications, Ltd.

Materials Science Forum (2457)

Abstract

Sn-based anode materials have poor cycling performance due to mechanical fatigue caused by volume expansion during lithium insertion and extraction processes. In this work, the mechanism of lithium insertion/extraction in the Ni3Sn4 alloy electrode is investigated using the first-principle plane-wave pseudopotential and experimnetal method. The calculated results indicate that the Ni3Sn4 alloy phase has relatively minor expansion ratio and fluctuating electrochemical potential, which the tendency is consistent with the experimental result. On the other hand, the Sn-Ni alloy thin films with different tin content are prepared by electrodepostion on copper as an anode for lithium-ion batteries. The structural and electrochemical characteristics of Sn-Ni alloy are examined using X-ray diffraction (XRD) and repeated constant current charge/discharge (CC). The results show Tthheat Ni3Sn4 alloy phase has best cyclic stability during the lithium insertion and extraction processes.

Bibliography

Hou, X. H., Hu, S. J., Yu, H. W., Zhao, L. Z., Ru, Q., Tan, C. L., & Li, W. S. (2009). Investigation on Lithiation Mechanism of Interphase Ni3Sn4 Alloy Used as Anode Material for Lithium-Ion Batteries. Materials Science Forum, 610â613, 506â511.

Authors 7

Xian Hua Hou (first)
She Jun Hu (additional)
Hong Wen Yu (additional)
Ling Zhi Zhao (additional)
Qiang Ru (additional)
Chun Lin Tan (additional)
Wei Shan Li (additional)

References 0 Referenced 3

None

Dates

Type	When
Created	16 years, 5 months ago (March 11, 2009, 4:13 p.m.)
Deposited	1 year, 2 months ago (June 26, 2024, 4:25 p.m.)
Indexed	1 year, 2 months ago (June 26, 2024, 8:02 p.m.)
Issued	16 years, 8 months ago (Jan. 2, 2009)
Published	16 years, 8 months ago (Jan. 2, 2009)
Published Online	16 years, 8 months ago (Jan. 2, 2009)

Funders 0

None

BibTeX

@article{Hou_2009, title={Investigation on Lithiation Mechanism of Interphase Ni3Sn4 Alloy Used as Anode Material for Lithium-Ion Batteries}, volume={610–613}, ISSN={1662-9752}, url={http://dx.doi.org/10.4028/www.scientific.net/msf.610-613.506}, DOI={10.4028/www.scientific.net/msf.610-613.506}, journal={Materials Science Forum}, publisher={Trans Tech Publications, Ltd.}, author={Hou, Xian Hua and Hu, She Jun and Yu, Hong Wen and Zhao, Ling Zhi and Ru, Qiang and Tan, Chun Lin and Li, Wei Shan}, year={2009}, month=jan, pages={506–511} }

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