DOI: 10.2118/15905-pa. Water Content of CO2 in Equilibrium With Liquid Water and/or Hydrates

Water Content of CO2 in Equilibrium With Liquid Water and/or Hydrates

10.2118/15905-pa

Crossref journal-article

Society of Petroleum Engineers (SPE)

SPE Formation Evaluation (861)

Abstract

Summary Experimentally measured water content in CO2-rich fluid in the gaseous or liquid state in equilibrium with liquid water or hydrate is presented for pressures ranging from 100 to 2,000 psia [0.69 to 13.79 MPa] and temperatures from −19 to 77°F [−28.33 to 25.0°C]. The water content of the CO2-rich phase along the three-phase equilibria, i.e., liquid water/liquid CO2/gas to the three-phase critical endpoint, is also reported. The experimental results from this study on the water content in the CO2-rich phases have been combined with earlier research results of the CO2/water binary system in the hydrate-free region from 77 to 200°F [25.0 to 93.33°C] and pressures to 3,000 psia [20.69 MPa] to produce a comprehensive plot. The high degree of complexity in the phase behavior of a CO2/water binary system, which exhibits several pairs of equilibrium phases for the conditions, is shown. To make the data more intelligible than they are in their raw form, the data are presented in terms of the pressure enhancement of the water content along isotherms. Finally, the activity coefficients of water in the CO2-rich phases are summarized.

Bibliography

Song, K. Y., & Kobayashi, R. (1987). Water Content of CO2 in Equilibrium With Liquid Water and/or Hydrates. SPE Formation Evaluation, 2(04), 500â508.

Authors 2

Kyoo Y. Song (first)
Riki Kobayashi (additional)

References 20 Referenced 117

10.1021/ja01847a030 / J. Am. Chem. Soc. / Vapor Phase Composition of Carbon Dioxide-Water Mixtures at Various Temperatures and Pressures to 700 Atmospheres by Wiebe (1941)
10.1021/i160034a008 / lnd. Eng. Chem. Fundam. / Experimental Measurement of Hydrate Numbers for Methane and Ethane and Comparison with Theoretical Values, by Galloway (1970)
{'issue': '9', 'key': '2022022319304151700_R3', 'first-page': '49', 'article-title': 'Catalytic Reforming Improved by Moisture Metering', 'volume': '69', 'author': 'Bloch', 'year': '1973', 'journal-title': 'Chem. Eng. Prog.'} / Chem. Eng. Prog. / Catalytic Reforming Improved by Moisture Metering by Bloch (1973)
{'key': '2022022319304151700_R4', 'article-title': 'Final Revised Report on the Water Content of Carbon Dioxide Gas and Liquid in Equilibrium with Liquid Water and with Gas Hydrates,', 'author': 'Kobayashi', 'year': '1979'} / Final Revised Report on the Water Content of Carbon Dioxide Gas and Liquid in Equilibrium with Liquid Water and with Gas Hydrates, by Kobayashi (1979)
{'key': '2022022319304151700_R5', 'article-title': 'Vapor-Liquid and Liquid-Liquid Equilibria: Water-Methane, Water-Carbon Dioxide, Water-Hydrogen Sulfide, Water-nPentane, Water-Methane-nPentane', 'author': 'Gillespie', 'year': '1982'} / Vapor-Liquid and Liquid-Liquid Equilibria: Water-Methane, Water-Carbon Dioxide, Water-Hydrogen Sulfide, Water-nPentane, Water-Methane-nPentane by Gillespie (1982)
{'key': '2022022319304151700_R6', 'first-page': '1', 'article-title': 'Clathrate Solutions', 'volume': 'II', 'author': 'van der Waals', 'year': '1959', 'journal-title': 'Adv. Chem. Phys.'} / Adv. Chem. Phys. / Clathrate Solutions by van der Waals (1959)
10.1002/aic.690100530 / AIChEJ / Hydrates at High Pressures: Part II. Application of Statistical Mechanics to the Study of Hydrates of Methane, Argon, and Nitrogen by Saito (1964)
10.1021/i260041a006 / lnd. Eng. Chem. Process Des. Develop. / Dissociation Pressures of Gas Hydrates Formed by Gas Mixtures by Parrish (1972)
Sloan, E.D. : "Phase Equilibria of Natural Gas Hydrates," paper 67F presented at the 1983 AIChE Summer Natl. Meeting, Denver, Aug. 28–31.
Erickson, D.D. : "Development of a Natural Gas Hydrate Prediction Computer Program,"MS thesis, Colorado School of Mines, Golden (1982).
Dewan, A.K.R. : "Water Saturation Prediction for CO2-Rich Mixtures Containing Traces of CH4 and N2," paper 27B presented at the 1985 AIChE Natl. Meeting, Houston, March 24–28.
10.1021/i160057a011 / lnd. Eng. Chem. Fund. / A New Two-Constant Equation of State by Peng (1976)
10.1016/0009-2509(72)80096-4 / Chem. Eng. Sci. / Equilibrium Constants from a Modified Redlich-Kwong Equation of State by Soave (1972)
{'key': '2022022319304151700_R14', 'volume-title': 'Carbon Dioxide, International Thermodynamic Tables of the Fluid State', 'author': 'Angus', 'year': '1976'} / Carbon Dioxide, International Thermodynamic Tables of the Fluid State by Angus (1976)
10.1021/i160060a016 / lnd. Eng. Chem. Fund. / Water Content of Methane Gas in Equilibrium with Hydrates by Sloan (1976)
10.1021/i100008a013 / Ind. Eng. Chem. Fund. / Measurement and Interpretation of the Water Content of a Methane-Propane Mixture in the Gaseous State in Equilibrium with Hydrate by Song (1982)
10.1021/i160076a015 / Experimental Thermodynamic Parameters for the Prediction of Natural Gas Hydrate Dissociation Conditions by Dharmawardhana (1980)
{'key': '2022022319304151700_R18', 'volume-title': 'Chemical Engineering Handbook', 'author': 'Perry', 'year': '1973', 'edition': 'fifth edition'} / Chemical Engineering Handbook by Perry (1973)
{'key': '2022022319304151700_R19', 'article-title': 'Table of Thermal Properties of Gases,', 'year': '1955', 'journal-title': 'U.S. Dept, of Commerce, NBS circular'} / U.S. Dept, of Commerce, NBS circular / Table of Thermal Properties of Gases, (1955)
{'key': '2022022319304151700_R20', 'first-page': '21', 'article-title': 'A Review and Discussion of Gas Hydrates', 'author': 'Schroeder', 'journal-title': "Ahren's Sammlung chemischer und chemisch-technischer Vorträge (1926-28) ."} / Ahren's Sammlung chemischer und chemisch-technischer Vorträge (1926-28) . / A Review and Discussion of Gas Hydrates by Schroeder

Dates

Type	When
Created	17 years, 8 months ago (Dec. 6, 2007, 7:12 p.m.)
Deposited	3 years, 6 months ago (Feb. 23, 2022, 2:39 p.m.)
Indexed	1 month, 1 week ago (July 24, 2025, 7:35 a.m.)
Issued	37 years, 9 months ago (Dec. 1, 1987)
Published	37 years, 9 months ago (Dec. 1, 1987)
Published Online	37 years, 9 months ago (Dec. 1, 1987)
Published Print	37 years, 9 months ago (Dec. 1, 1987)

Funders 0

None

BibTeX

@article{Song_1987, title={Water Content of CO2 in Equilibrium With Liquid Water and/or Hydrates}, volume={2}, ISSN={2469-8512}, url={http://dx.doi.org/10.2118/15905-pa}, DOI={10.2118/15905-pa}, number={04}, journal={SPE Formation Evaluation}, publisher={Society of Petroleum Engineers (SPE)}, author={Song, Kyoo Y. and Kobayashi, Riki}, year={1987}, month=dec, pages={500–508} }

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