Abstract
AbstractThe hybrid halide perovskites combine the low-cost processing characteristics of organic materials with the performance factors of inorganic compounds. Recently the power conversion efficiencies of perovskite photovoltaic solar cells have reached a respective value of ∼20%. The charge transport properties were indirectly approximated in these compounds because of lack of available field-effect transistors (FETs). Here we report the fabrication and room-temperature operation of FETs based on the hybrid perovskites. We obtained balanced electron and hole transport with mobilities of ∼1 cm2/Vs. We also found that the yield, as well as the operational and environmental stability of the fabricated transistors is limited.
References
32
Referenced
141
-
J.B. Goodenough: Metallic oxides. Progr. Solid State Chem. 5, 145 (1971).
(
10.1016/0079-6786(71)90018-5
) / Metallic oxides. Progr. Solid State Chem. by JB Goodenough (1971) -
B.B. Van Aken, T.T.M. Palstra, A. Filippetti, and N.A. Spaldin: The origin of ferroelectricity in magnetoelectric YMnO3. Nat. Mater. 3, 164 (2004).
(
10.1038/nmat1080
) / Nat. Mater. by BB Van Aken (2004) -
M.A. Green, A. Ho-Baillie, and H.J. Snaith: The emergence of perovskite solar cells. Nat. Photonics 8, 506 (2014).
(
10.1038/nphoton.2014.134
) / Nat. Photonics by MA Green (2014) -
S.A. Bretschneider, J. Weickert, J.A. Dorman, and L. Schmidt-Mende: Research update: physical and electrical characteristics of lead halide perovskites for solar cell applications. APL Mater. 2, 040701 (2014).
(
10.1063/1.4871795
) / APL Mater. by SA Bretschneider (2014) -
H. Zhou, Q. Chen, G. Li, S. Luo, T.-B. Song, H.-S. Duan, Z. Hong, J. You, Y. Liu, and Y. Yang: Interface engineering of highly efficient perovskite solar cells. Science 345, 542 (2014).
(
10.1126/science.1254050
) / Science by H Zhou (2014) -
Z.-K. Tan, R.S. Moghaddam, M.L. Lai, P. Docampo, R. Higler, F. Deschler, M. Price, A. Sadhanala, L.M. Pazos, D. Credgington, F. Hanusch, T. Bein, H.J. Snaith, and R.H. Friend: Bright light-emitting diodes based on organometal halide perovskite. Nat. Nano 9, 687 (2014).
(
10.1038/nnano.2014.149
) / Nat. Nano by Z-K Tan (2014) -
C.C. Stoumpos, C.D. Malliakas, and M.G. Kanatzidis: Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. Inorg. Chem. 52, 9019 (2013).
(
10.1021/ic401215x
) / Inorg. Chem. by CC Stoumpos (2013) -
G. Xing, N. Mathews, S.S. Lim, N. Yantara, X. Liu, D. Sabba, M. Grätzel, S. Mhaisalkar, and T.C. Sum: Low-temperature solution-processed wavelength-tunable perovskites for lasing. Nat. Mater. 13, 476 (2014).
(
10.1038/nmat3911
) / Nat. Mater. by G Xing (2014) -
Q. Dong, Y. Fang, Y. Shao, P. Mulligan, J. Qiu, L. Cao, and J. Huang: Electron–hole diffusion lengths >175 μm in solution-grown CH3NH3PbI3 single crystals. Science 347, 967 (2015).
(
10.1126/science.aaa5760
) / Science by Q Dong (2015) - C. Zhang, D. Sun, C.X. Sheng, Y.X. Zhai, K. Mielczarek, A. Zakhidov, and Z.V. Vardeny: Magnetic field effects in hybrid perovskite devices. Nat. Phys., doi:10.1038/nphys3277, Published online 16 March 2015. / Nat. Phys. by C Zhang (2015)
-
D. Giovanni, H. Ma, J. Chua, M. Grätzel, R. Ramesh, S. Mhaisalkar, N. Mathews, and T.C. Sum: Highly spin-polarized carrier dynamics and ultralarge photoinduced magnetization in CH3NH3PbI3 perovskite thin films. Nano Lett. 15, 1553 (2015).
(
10.1021/nl5039314
) / Nano Lett. by D Giovanni (2015) -
J.-H. Im, J. Chung, S.-J. Kim, and N.-G. Park: Synthesis, structure, and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer (CH3CH2NH3)PbI3. Nanoscale Res. Lett. 7, 353 (2012).
(
10.1186/1556-276X-7-353
) / Nanoscale Res. Lett. by J-H Im (2012) -
S. Pang, H. Hu, J. Zhang, S. Lv, Y. Yu, F. Wei, T. Qin, H. Xu, Z. Liu, and G. Cui: NH2CHvNH2PbI3: an alternative organolead iodide perovskite sensitizer for mesoscopic solar cells. Chem. Mater. 26, 1485 (2014).
(
10.1021/cm404006p
) / Chem. Mater. by S Pang (2014) -
Y. Tidhar, E. Edri, H. Weissman, D. Zohar, G. Hodes, D. Cahen, B. Rybtchinski, and S. Kirmayer: Crystallization of methyl ammonium lead halide perovskites: implications for photovoltaic applications. J. Am. Chem. Soc. 136, 13249 (2014).
(
10.1021/ja505556s
) / J. Am. Chem. Soc. by Y Tidhar (2014) -
J.H. Noh, S.H. Im, J.H. Heo, T.N. Mandal, and S.I. Seok: Chemical management for colorful, efficient, and stable inorganic–organic hybrid nanostructured solar cells. Nano Lett. 13, 1764 (2013).
(
10.1021/nl400349b
) / Nano Lett. by JH Noh (2013) -
B. Cai, Y. Xing, Z. Yang, W.-H. Zhang, and J. Qiu: High performance hybrid solar cells sensitized by organolead halide perovskites. Energy Environ. Sci. 6, 1480 (2013).
(
10.1039/c3ee40343b
) / Energy Environ. Sci. by B Cai (2013) -
C.X. Sheng, C. Zhang, Y. Zhai, K. Mielczarek, W. Wang, W. Ma, A. Zakhidov, and Z.V. Vardeny: Exciton versus free carrier photogeneration in organometal trihalide perovskites probed by broadband ultrafast polarization memory dynamics. Phys. Rev. Lett. 114, 116601 (2015).
(
10.1103/PhysRevLett.114.116601
) / Phys. Rev. Lett. by CX Sheng (2015) -
B.-W. Park, B. Philippe, T. Gustafsson, K. Sveinbjörnsson, A. Hagfeldt, E.M.J. Johansson, and G. Boschloo: Enhanced crystallinity in organic–inorganic lead halide perovskites on mesoporous TiO2 via disorder–order phase transition. Chem. Mater. 26, 4466 (2014).
(
10.1021/cm501541p
) / Chem. Mater. by B-W Park (2014) -
A. Kojima, K. Teshima, Y. Shirai, and T. Miyasaka: Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131, 6050 (2009).
(
10.1021/ja809598r
) / J. Am. Chem. Soc. by A Kojima (2009) -
M.M. Lee, J. Teuscher, T. Miyasaka, T.N. Murakami, and H.J. Snaith: Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338, 643 (2012).
(
10.1126/science.1228604
) / Science by MM Lee (2012) -
A. Mei, X. Li, L. Liu, Z. Ku, T. Liu, Y. Rong, M. Xu, M. Hu, J. Chen, Y. Yang, M. Grätzel, and H. Han: A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability. Science 345, 295 (2014).
(
10.1126/science.1254763
) / Science by A Mei (2014) -
S.D. Stranks, G.E. Eperon, G. Grancini, C. Menelaou, M.J.P. Alcocer, T. Leijtens, L.M. Herz, A. Petrozza, and H.J. Snaith: Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342, 341 (2013).
(
10.1126/science.1243982
) / Science by SD Stranks (2013) -
C. Wehrenfennig, G.E. Eperon, M.B. Johnston, H.J. Snaith, and L.M. Herz: High charge carrier mobilities and lifetimes in organolead trihalide perovskites. Adv. Mater. 26, 1584 (2014).
(
10.1002/adma.201305172
) / Adv. Mater. by C Wehrenfennig (2014) -
L. Etgar, P. Gao, Z. Xue, Q. Peng, A.K. Chandiran, B. Liu, M.K. Nazeeruddin, and M. Grätzel: Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells. J. Am. Chem. Soc. 134, 17396 (2012).
(
10.1021/ja307789s
) / J. Am. Chem. Soc. by L Etgar (2012) -
C.R. Kagan, D.B. Mitzi, and C.D. Dimitrakopoulos: Organic–inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science 286, 945 (1999).
(
10.1126/science.286.5441.945
) / Science by CR Kagan (1999) -
D.B. Mitzi, C.D. Dimitrakopoulos, and L.L. Kosbar: Structurally tailored organic–inorganic perovskites: optical properties and solution-processed channel materials for thin-film transistors. Chem. Mater. 13, 3728 (2001).
(
10.1021/cm010105g
) / Chem. Mater. by DB Mitzi (2001) -
X.Y. Chin, D. Cortecchia, J. Yin, A. Bruno, and C. Soci: Lead Iodide Perovskite Light-Emitting Field-Effect Transistor, arXiv:1501.04407, 2015.
(
10.1038/ncomms8383
) / Lead Iodide Perovskite Light-Emitting Field-Effect Transistor by XY Chin (2015) -
S. De Wolf, J. Holovsky, S.-J. Moon, P. Löper, B. Niesen, M. Ledinsky, F.-J. Haug, J.-H. Yum, and C. Ballif: Organometallic halide perovskites: sharp optical absorption edge and its relation to photovoltaic performance. J. Phys. Chem. Lett. 5, 1035 (2014).
(
10.1021/jz500279b
) / J. Phys. Chem. Lett. by S De Wolf (2014) -
M. Liu, M.B. Johnston, and H.J. Snaith: Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 501, 395 (2013).
(
10.1038/nature12509
) / Nature by M Liu (2013) -
J.W. Ward, M.A. Loth, R.J. Kline, M. Coll, C. Ocal, J.E. Anthony, and O.D. Jurchescu: Tailored interfaces for self-patterning organic thin-film transistors. J. Mater. Chem. 22, 19047 (2012).
(
10.1039/c2jm33974a
) / J. Mater. Chem. by JW Ward (2012) -
A. Abrusci, S.D. Stranks, P. Docampo, H.-L. Yip, A. K.Y. Jen, and H.J. Snaith: High-performance perovskite-polymer hybrid solar cells via electronic coupling with fullerene monolayers. Nano Lett. 13, 3124 (2013).
(
10.1021/nl401044q
) / Nano Lett. by A Abrusci (2013) -
Z. Xiao, Q. Dong, C. Bi, Y. Shao, Y. Yuan, and J. Huang: Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement. Adv. Mater. 26, 6503 (2014).
(
10.1002/adma.201401685
) / Adv. Mater. by Z Xiao (2014)
Dates
Type | When |
---|---|
Created | 10 years, 3 months ago (May 4, 2015, 3:25 a.m.) |
Deposited | 4 years, 6 months ago (Feb. 14, 2021, 5:47 a.m.) |
Indexed | 3 weeks ago (Aug. 5, 2025, 8:35 a.m.) |
Issued | 10 years, 2 months ago (June 1, 2015) |
Published | 10 years, 2 months ago (June 1, 2015) |
Published Online | 10 years, 2 months ago (June 1, 2015) |
Published Print | 10 years, 2 months ago (June 1, 2015) |
@article{Mei_2015, title={Electrostatic gating of hybrid halide perovskite field-effect transistors: balanced ambipolar transport at room-temperature}, volume={5}, ISSN={2159-6867}, url={http://dx.doi.org/10.1557/mrc.2015.21}, DOI={10.1557/mrc.2015.21}, number={2}, journal={MRS Communications}, publisher={Springer Science and Business Media LLC}, author={Mei, Y. and Zhang, C. and Vardeny, Z. V. and Jurchescu, O. D.}, year={2015}, month=jun, pages={297–301} }