DOI: 10.1557/jmr.2005.0398. Tailoring singlewalled carbon nanotubes for hydrogen storage

Tailoring singlewalled carbon nanotubes for hydrogen storage

10.1557/jmr.2005.0398

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

Hydrogen isotherms on a variety of single-walled carbon nanotube (SWNT) samples were measured using a differential pressure adsorption apparatus, which provides highly accurate data. A number of these SWNT samples were modified by a non-destructive cutting process, which reduced the aspect ratio of the nanotube bundles by two orders of magnitude. There were no apparent differences in the microporosity of SWNT as a function of aspect ratio. The adsorption of helium on SWNT is shown to be non-negligible and results in artificially low hydrogen capacities using conventional adsorption methodology. With no accounting for helium adsorption, the hydrogen adsorption results show that cut and uncut SWNT have similar hydrogen capacities of <1 wt% at 25 °C and pressures up to 110 bar. However, an analysis of hydrogen capacity versus N2Brunauer–Emmett–Teller surface area suggests that there is an enhanced heat of adsorption of hydrogen for SWNT versus activated carbon.

Bibliography

Haas, M. K., Zielinski, J. M., Dantsin, G., Coe, C. G., Pez, G. P., & Cooper, A. C. (2005). Tailoring singlewalled carbon nanotubes for hydrogen storage. Journal of Materials Research, 20(12), 3214â3223.

Authors 6

M.K. Haas (first)
J.M. Zielinski (additional)
G. Dantsin (additional)
C.G. Coe (additional)
G.P. Pez (additional)
A.C. Cooper (additional)

References 51 Referenced 29

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10.1016/j.cplett.2004.11.104

Dates

Type	When
Created	19 years, 8 months ago (Dec. 14, 2005, 5:47 a.m.)
Deposited	4 years, 1 month ago (July 21, 2021, 9:04 a.m.)
Indexed	10 months, 2 weeks ago (Oct. 5, 2024, 8:33 p.m.)
Issued	19 years, 8 months ago (Dec. 1, 2005)
Published	19 years, 8 months ago (Dec. 1, 2005)
Published Online	19 years, 8 months ago (Dec. 1, 2005)

Funders 0

None

BibTeX

@article{Haas_2005, title={Tailoring singlewalled carbon nanotubes for hydrogen storage}, volume={20}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.2005.0398}, DOI={10.1557/jmr.2005.0398}, number={12}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Haas, M.K. and Zielinski, J.M. and Dantsin, G. and Coe, C.G. and Pez, G.P. and Cooper, A.C.}, year={2005}, month=dec, pages={3214–3223} }

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