DOI: 10.1557/proc-455-495. Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys

Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys

10.1557/proc-455-495

Crossref journal-article

Springer Science and Business Media LLC

MRS Proceedings (297)

Abstract

ABSTRACTBulk amorphous Pd-Ni-P and Pd-Cu-P alloy rods with diameters ranging from 7 to 25 mm have been synthesized over a wide composition range using a fluxing technique. For most bulk amorphous Pd-Ni-P alloys, the difference ΔT = Tx - Tg between the crystallization temperature Tx and the glass transition temperature Tg is larger than 90 K, while for bulk amorphous Pd-Cu-P alloys, ΔT varies from 27 to 73 K. Pd40Ni40P20 has the highest glass formability, and 300-gram bulk amorphous cylinders, 25 mm in diameter and 50 mm in length, can be easily produced. This size, however, is not an upper limit. The paper presents the glass formation ranges for both ternary alloy systems and data on the thermal stability of the amorphous alloys, as well as their specific heat, density, and elastic properties.

Bibliography

He, Y., & Schwarz, R. B. (1996). Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys. MRS Proceedings, 455.

Authors 2

Y. He (first)
R. B. Schwarz (additional)

References 22 Referenced 13

10.1016/0921-4526(93)90048-B
10.1016/B978-0-408-11030-3.50007-8
10.1080/00107516908204405
10.1016/0001-6160(84)90105-6
13. He Y. and Schwarz R. B. , preprint, Los Alamos National Laboratory, 1996.
10.1063/1.95330
10.1063/1.110520
10.2320/matertrans1989.34.1234
10.2320/matertrans1989.32.1005
10.1016/0022-3093(93)90217-L
10.2320/matertrans1989.32.609
10.1063/1.93645
10.1063/1.1142566
15. He Y. and Schwarz R. B. , unpublished results, Los Alamos National Laboratory, 1996.
10.1063/1.117458
10.2320/matertrans1989.37.181
10.1016/0001-6160(74)90112-6
12. Schwarz R. B. and He Y. , International Symposium on Metastable. Mechanically Alloyed and Nanocry'stalline Materials (ISMNAN-96), Rome, Italy, 20–24 May, 1996, in press.
10.1080/09500839408240503
20. Somieski B. , Hulett L. , He Y. , and Schwarz R. B. , unpublished results, Oak Ridge and Los Alamos National Labs, 1996.
10.1063/1.360537
10.2320/matertrans1989.31.425

Dates

Type	When
Created	14 years, 4 months ago (April 5, 2011, 7:06 p.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 4:53 p.m.)
Indexed	2 months ago (June 26, 2025, 7:26 p.m.)
Issued	29 years, 7 months ago (Jan. 1, 1996)
Published	29 years, 7 months ago (Jan. 1, 1996)
Published Online	14 years, 6 months ago (Feb. 10, 2011)
Published Print	29 years, 7 months ago (Jan. 1, 1996)

Funders 0

None

BibTeX

@article{He_1996, title={Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys}, volume={455}, ISSN={1946-4274}, url={http://dx.doi.org/10.1557/proc-455-495}, DOI={10.1557/proc-455-495}, journal={MRS Proceedings}, publisher={Springer Science and Business Media LLC}, author={He, Y. and Schwarz, R. B.}, year={1996} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        6,
        26
      ]
    ],
    "date-time": "2025-06-26T23:26:48Z",
    "timestamp": 1750980408665
  },
  "reference-count": 22,
  "publisher": "Springer Science and Business Media LLC",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2011,
            2,
            10
          ]
        ],
        "date-time": "2011-02-10T00:00:00Z",
        "timestamp": 1297296000000
      },
      "content-version": "unspecified",
      "delay-in-days": 5519,
      "URL": "https://www.cambridge.org/core/terms"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1996
      ]
    ]
  },
  "abstract": "<jats:title>ABSTRACT</jats:title><jats:p>Bulk amorphous Pd-Ni-P and Pd-Cu-P alloy rods with diameters ranging from 7 to 25 mm have been synthesized over a wide composition range using a fluxing technique. For most bulk amorphous Pd-Ni-P alloys, the difference <jats:italic>\u0394T</jats:italic> = <jats:italic>T<jats:sub>x</jats:sub></jats:italic> - <jats:italic>T<jats:sub>g</jats:sub></jats:italic> between the crystallization temperature <jats:italic>T<jats:sub>x</jats:sub></jats:italic> and the glass transition temperature <jats:italic>T<jats:sub>g</jats:sub></jats:italic> is larger than 90 K, while for bulk amorphous Pd-Cu-P alloys, <jats:italic>\u0394T</jats:italic> varies from 27 to 73 K. Pd<jats:sub>40</jats:sub>Ni<jats:sub>40</jats:sub>P<jats:sub>20</jats:sub> has the highest glass formability, and 300-gram bulk amorphous cylinders, 25 mm in diameter and 50 mm in length, can be easily produced. This size, however, is not an upper limit. The paper presents the glass formation ranges for both ternary alloy systems and data on the thermal stability of the amorphous alloys, as well as their specific heat, density, and elastic properties.</jats:p>",
  "DOI": "10.1557/proc-455-495",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2011,
        4,
        5
      ]
    ],
    "date-time": "2011-04-05T23:06:59Z",
    "timestamp": 1302044819000
  },
  "source": "Crossref",
  "is-referenced-by-count": 13,
  "title": "Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys",
  "prefix": "10.1557",
  "volume": "455",
  "author": [
    {
      "given": "Y.",
      "family": "He",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "R. B.",
      "family": "Schwarz",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "297",
  "published-online": {
    "date-parts": [
      [
        2011,
        2,
        10
      ]
    ]
  },
  "reference": [
    {
      "key": "S1946427400210282_ref021",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0921-4526(93)90048-B"
    },
    {
      "key": "S1946427400210282_ref019",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/B978-0-408-11030-3.50007-8"
    },
    {
      "key": "S1946427400210282_ref018",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00107516908204405"
    },
    {
      "key": "S1946427400210282_ref014",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0001-6160(84)90105-6"
    },
    {
      "key": "S1946427400210282_ref013",
      "unstructured": "13. He Y. and Schwarz R. B. , preprint, Los Alamos National Laboratory, 1996."
    },
    {
      "key": "S1946427400210282_ref010",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.95330"
    },
    {
      "key": "S1946427400210282_ref005",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.110520"
    },
    {
      "key": "S1946427400210282_ref004",
      "doi-asserted-by": "publisher",
      "DOI": "10.2320/matertrans1989.34.1234"
    },
    {
      "key": "S1946427400210282_ref003",
      "doi-asserted-by": "publisher",
      "DOI": "10.2320/matertrans1989.32.1005"
    },
    {
      "key": "S1946427400210282_ref016",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-3093(93)90217-L"
    },
    {
      "key": "S1946427400210282_ref002",
      "doi-asserted-by": "publisher",
      "DOI": "10.2320/matertrans1989.32.609"
    },
    {
      "key": "S1946427400210282_ref009",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.93645"
    },
    {
      "key": "S1946427400210282_ref022",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1142566"
    },
    {
      "key": "S1946427400210282_ref015",
      "unstructured": "15. He Y. and Schwarz R. B. , unpublished results, Los Alamos National Laboratory, 1996."
    },
    {
      "key": "S1946427400210282_ref011",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.117458"
    },
    {
      "key": "S1946427400210282_ref017",
      "doi-asserted-by": "publisher",
      "DOI": "10.2320/matertrans1989.37.181"
    },
    {
      "key": "S1946427400210282_ref008",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0001-6160(74)90112-6"
    },
    {
      "key": "S1946427400210282_ref012",
      "unstructured": "12. Schwarz R. B. and He Y. , International Symposium on Metastable. Mechanically Alloyed and Nanocry'stalline Materials (ISMNAN-96), Rome, Italy, 20\u201324 May, 1996, in press."
    },
    {
      "key": "S1946427400210282_ref006",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/09500839408240503"
    },
    {
      "key": "S1946427400210282_ref020",
      "unstructured": "20. Somieski B. , Hulett L. , He Y. , and Schwarz R. B. , unpublished results, Oak Ridge and Los Alamos National Labs, 1996."
    },
    {
      "key": "S1946427400210282_ref007",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.360537"
    },
    {
      "key": "S1946427400210282_ref001",
      "doi-asserted-by": "publisher",
      "DOI": "10.2320/matertrans1989.31.425"
    }
  ],
  "container-title": "MRS Proceedings",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S1946427400210282",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2021,
        2,
        24
      ]
    ],
    "date-time": "2021-02-24T21:53:32Z",
    "timestamp": 1614203612000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "http://link.springer.com/10.1557/PROC-455-495"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1996
      ]
    ]
  },
  "references-count": 22,
  "alternative-id": [
    "S1946427400210282"
  ],
  "URL": "http://dx.doi.org/10.1557/PROC-455-495",
  "relation": {},
  "ISSN": [
    "0272-9172",
    "1946-4274"
  ],
  "subject": [],
  "container-title-short": "MRS Proc.",
  "published": {
    "date-parts": [
      [
        1996
      ]
    ]
  },
  "article-number": "495"
}