DOI: 10.1557/proc-369-179. Vanadium Pentoxide Gels from Liquid Crystals to Lithium Batteries

Vanadium Pentoxide Gels from Liquid Crystals to Lithium Batteries

10.1557/proc-369-179

Crossref journal-article

Springer Science and Business Media LLC

MRS Proceedings (297)

Abstract

AbstractVanadium pentoxide gels V205.nH20 are formed via the condensation of vanadic acid in aqueous solutions. They exhibit both ionic and electronic conductivity and could therefore be used as cathode materials in lithium batteries or electrochromic display devices. The polymerization process leads to ribbon-like vanadium pentoxide particles. In a given range of concentration, sols and gels exhibit a homogeneous lyotropic nematic phase in which the ribbons align in the same direction. Ordered fluid phases are thus obtained leading to oriented films when deposited onto flat substrates. Moreover, mixed oxides MxV205 (M = Na+, K+,Ba2+, Al3+, Fe3+,Fe3+,...) exhibiting some preferred orientation are obtained via ion exchange.These compounds exhibit improved lectrochemical properties (specific capacity, cycling properties) compared to usual mixed oxides prepared via solid state reactions.

Bibliography

Livage, J., Baffier, N., Pereira-Ramos, J. P., & Davidson, P. (1994). Vanadium Pentoxide Gels from Liquid Crystals to Lithium Batteries. MRS Proceedings, 369.

Authors 4

J. Livage (first)
N. Baffier (additional)
J.P. Pereira-Ramos (additional)
P. Davidson (additional)

References 38 Referenced 9

10.1149/1.2221035
10.1016/0022-4596(91)90237-C
10.1016/0022-0728(91)85430-W
10.1016/0025-5408(78)90198-8
{'key': 'S194642740035730X_ref019', 'first-page': '478', 'volume': '98', 'author': 'Aldebert', 'year': '1984', 'journal-title': 'J. Colloids Interface Sci.'} / J. Colloids Interface Sci. by Aldebert (1984)
10.1016/0166-6622(84)80240-1
{'key': 'S194642740035730X_ref009', 'volume': '301', 'author': 'Lemerle', 'year': '1978', 'journal-title': 'J. Chem. Res.'} / J. Chem. Res. by Lemerle (1978)
10.1557/PROC-293-261
10.1080/02678299408027861
10.1016/0378-7753(87)80107-6
10.1016/0167-2738(92)90234-G
10.1103/PhysRevLett.61.1851
10.1016/0021-9797(83)90236-9
{'key': 'S194642740035730X_ref036', 'first-page': '197', 'volume': '152', 'author': 'Maingot', 'year': '1994', 'journal-title': 'Mat. Sci. Forum'} / Mat. Sci. Forum by Maingot (1994)
{'key': 'S194642740035730X_ref021', 'first-page': '417', 'volume': '22', 'author': 'Bouhaouss', 'year': '1985', 'journal-title': 'Rev. Chim. Miner.'} / Rev. Chim. Miner. by Bouhaouss (1985)
10.1016/0021-9797(91)90344-8
10.1021/la00037a045
{'key': 'S194642740035730X_ref004', 'volume-title': 'Sol-Gel Technology', 'author': 'Klein', 'year': '1988'} / Sol-Gel Technology by Klein (1988)
{'key': 'S194642740035730X_ref003', 'first-page': '155', 'volume': '77', 'author': 'Henry', 'year': '1992', 'journal-title': 'Structure and Bonding'} / Structure and Bonding by Henry (1992)
10.1149/1.2086601
10.1016/0021-9797(83)90237-0
10.1016/0025-5408(89)90161-X
10.1080/13642812.1983.9728310
10.1016/0167-2738(94)90414-6
10.1016/0167-2738(93)90305-M
10.1021/cm00016a006
10.1016/0025-5408(81)90266-X
10.1016/0025-5408(83)90157-5
10.1016/0022-0728(90)85116-M
10.1021/ic00137a043
10.1039/ft9908602623
10.1016/0167-2738(88)90449-3
10.1016/0167-2738(90)90165-N
10.1016/S0167-2738(88)80164-4
10.1002/zaac.19251470111
10.1016/0167-2738(88)90353-0
{'key': 'S194642740035730X_ref005', 'volume-title': 'Sol-Gel Science', 'author': 'Brinker', 'year': '1990'} / Sol-Gel Science by Brinker (1990)
10.1103/PhysRevB.40.12229

Dates

Type	When
Created	14 years, 4 months ago (April 5, 2011, 12:47 p.m.)
Deposited	4 years, 5 months ago (Feb. 24, 2021, 4:05 p.m.)
Indexed	1 year, 2 months ago (May 23, 2024, 9:54 a.m.)
Issued	31 years, 7 months ago (Jan. 1, 1994)
Published	31 years, 7 months ago (Jan. 1, 1994)
Published Online	14 years, 6 months ago (Feb. 16, 2011)
Published Print	31 years, 7 months ago (Jan. 1, 1994)

Funders 0

None

BibTeX

@article{Livage_1994, title={Vanadium Pentoxide Gels from Liquid Crystals to Lithium Batteries}, volume={369}, ISSN={1946-4274}, url={http://dx.doi.org/10.1557/proc-369-179}, DOI={10.1557/proc-369-179}, journal={MRS Proceedings}, publisher={Springer Science and Business Media LLC}, author={Livage, J. and Baffier, N. and Pereira-Ramos, J.P. and Davidson, P.}, year={1994} }

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