DOI: 10.1557/proc-359-111. Inorganic Fullerenes of MX<sub>2</sub> (M=W,Mo;X=S,Se)

Inorganic Fullerenes of MX2 (M=W,Mo;X=S,Se)

10.1557/proc-359-111

Crossref journal-article

Springer Science and Business Media LLC

MRS Proceedings (297)

Abstract

ABSTRACTThe gas-phase reaction between MoO3-x and H2S in a reducing atmosphere and at elevated temperatures (800° to 950°C) has been used to synthesize large quantities of an almost pure nested inorganic fullerenes (IFs) phase of MoS2. A uniform IF phase with a relatively narrow size distribution was obtained. The x-ray spectra of the different samples show that as the average size of the IF decreases the van der Waals gap along the c axis increases, largely because of the strain involved in folding of the lamella. Large amount of quite uniform nanotubes were obtained under modified preparation conditions.In the second part of this work MoS2 nested fullerenes were grown on Ti and Nb and Mo oxide substrates. In one set of conditions hollow nested fullerenes of MoS2 were collected on a titanium oxide matrix, and analyzed by local area energy dispersive analysis. Under different flow conditions of the reacting gasses nested fullerenes with endohedral metal oxides were obtained and analyzed by electron diffraction.

Bibliography

Tenne, R., Margulis, L., Feldman, Y., & Homyonfer, M. (1994). Inorganic Fullerenes of MX2 (M=W,Mo;X=S,Se). MRS Proceedings, 359.

Authors 4

R. Tenne (first)
L. Margulis (additional)
Y. Feldman (additional)
M. Homyonfer (additional)

References 22 Referenced 1

10.1126/science.259.5093.346
10.1016/0040-6090(94)90896-6
10.1007/BF01106824
10.1139/v75-514 / Can. J. Chem. by Amberg (1975)
10.1016/0040-6090(89)90017-5
10.1126/science.242.4882.1139
10.1021/ja00084a035
10.1038/360444a0
10.1038/318162a0
10.1021/j100194a011
10.1103/PhysRevLett.70.3023
10.1038/365113b0
16. Feldmann Y. , Wasserman E. , Srolovitz D. , and Tenne R. , Science, in press.
10.1021/ja00215a008
10.1038/354056a0
10.1103/PhysRevB.48.1907
10.1002/zaac.18950080122
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10.1016/0022-0248(80)90013-5
10.1142/S0217979290001042
10.1038/359707a0
10.1038/361333a0

Dates

Type	When
Created	14 years, 4 months ago (April 5, 2011, 7:19 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 3:59 p.m.)
Indexed	2 years, 5 months ago (March 16, 2023, 1:07 a.m.)
Issued	31 years, 8 months ago (Jan. 1, 1994)
Published	31 years, 8 months ago (Jan. 1, 1994)
Published Online	14 years, 6 months ago (Feb. 15, 2011)
Published Print	31 years, 8 months ago (Jan. 1, 1994)

Funders 0

None

BibTeX

@article{Tenne_1994, title={Inorganic Fullerenes of MX2 (M=W,Mo;X=S,Se)}, volume={359}, ISSN={1946-4274}, url={http://dx.doi.org/10.1557/proc-359-111}, DOI={10.1557/proc-359-111}, journal={MRS Proceedings}, publisher={Springer Science and Business Media LLC}, author={Tenne, R. and Margulis, L. and Feldman, Y. and Homyonfer, M.}, year={1994} }

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