Abstract
ABSTRACTMicroporous zeolites can be synthesized using organic structure-directing molecules whose function is to organize inorganic species into particular topologies that then spontaneously self-assemble into the final crystalline materials. Extension of the zeolite assembly process to the use of organic molecular aggregates as structure-directing agents yields ordered mesoporous materials like MCM–41 and MCM–48. A unifying picture of the assembly processes ocurring in the syntheses of micro- and mesoporous materials is presented.
References
17
Referenced
28
- 7 Burkett S.L. and Davis M.E. , J. Phys. Chem. (in press).
10.1126/science.261.5126.1299
10.1016/0144-2449(87)90018-2
10.1016/0021-9797(73)90305-6
10.1107/S0365110X61002503
10.1051/jphys:019870048090155900
10.1038/359710a0
10.1016/0927-6513(93)80059-4
10.1016/0927-6513(93)80058-3
10.1021/ja00053a020
{'key': 'S1946427400377806_ref006', 'first-page': '203', 'volume': '198', 'author': 'Kresge', 'year': '1993', 'journal-title': 'U.S. Patent No. 5'}
/ U.S. Patent No. 5 by Kresge (1993)10.1126/science.262.5139.1543
10.1021/cm00022a005
10.1007/BF01490251
{'key': 'S1946427400377806_ref013', 'first-page': '102', 'volume': '5', 'author': 'Kresge', 'year': '1992', 'journal-title': 'U.S. Patent No.'}
/ U.S. Patent No. by Kresge (1992){'key': 'S1946427400377806_ref016', 'volume-title': 'J. Indus. Phenom.', 'author': 'Lobo'}
/ J. Indus. Phenom. by Lobo10.1126/science.261.5126.1286
Dates
Type | When |
---|---|
Created | 14 years, 4 months ago (April 6, 2011, 9:50 a.m.) |
Deposited | 4 years, 6 months ago (Feb. 24, 2021, 3:50 p.m.) |
Indexed | 1 month, 2 weeks ago (July 7, 2025, 9:07 a.m.) |
Issued | 31 years, 7 months ago (Jan. 1, 1994) |
Published | 31 years, 7 months ago (Jan. 1, 1994) |
Published Online | 14 years, 6 months ago (Feb. 21, 2011) |
Published Print | 31 years, 7 months ago (Jan. 1, 1994) |
@article{Davis_1994, title={Synthesis of (Alumino) Silicate Materials Using Organic Molecules and Self-Assembled Organic Aggregates as Structure-Directing Agents}, volume={346}, ISSN={1946-4274}, url={http://dx.doi.org/10.1557/proc-346-831}, DOI={10.1557/proc-346-831}, journal={MRS Proceedings}, publisher={Springer Science and Business Media LLC}, author={Davis, Mark E. and Chen, Cong-Yan and Burkett, Sandra L. and Lobo, Raul F.}, year={1994} }