DOI: 10.1557/jmr.2001.0460. High-temperature thermoelectric properties of n-type BayNixCo4−xSb12

High-temperature thermoelectric properties of n-type BayNixCo4−xSb12

10.1557/jmr.2001.0460

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

Effects of Ba filling fraction and Ni content on the thermoelectric properties of n-type BayNixCo4−xSb12 (x = 0−0.1, y = 0−0.4) were investigated at temperature range of 300 to 900 K. Thermal conductivity decreased with increasing Ba filling fraction and temperature. When y was fixed at 0.3, thermal conductivity decreased with increasing Ni content and reached a minimum value at about x = 0.05. Lattice thermal conductivity decreased with increasing Ni content, monotonously (y ≤ 0.1). Electron concentration and electrical conductivity increased with increasing Ba filling fraction and Ni content. Seebeck coefficient increased with increasing temperature and decreased with increasing Ba filling fraction and Ni content. The maximum ZT value of 1.25 was obtained at about 900 K for n-type Ba0.3Ni0.05Co3.95Sb12.

Bibliography

Tang, X. F., Zhang, L. M., Yuan, R. Z., Chen, L. D., Goto, T., Hirai, T., Dyck, J. S., Chen, W., & Uher, C. (2001). High-temperature thermoelectric properties of n-type BayNixCo4âxSb12. Journal of Materials Research, 16(12), 3343â3346.

Authors 9

X. F. Tang (first)
L. M. Zhang (additional)
R. Z. Yuan (additional)
L. D. Chen (additional)
T. Goto (additional)
T. Hirai (additional)
J. S. Dyck (additional)
W. Chen (additional)
C. Uher (additional)

References 26 Referenced 39

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Dates

Type	When
Created	17 years, 5 months ago (March 5, 2008, 9:41 p.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 3:08 p.m.)
Indexed	1 year, 7 months ago (Jan. 30, 2024, 6:18 a.m.)
Issued	23 years, 9 months ago (Dec. 1, 2001)
Published	23 years, 9 months ago (Dec. 1, 2001)
Published Online	14 years, 7 months ago (Jan. 31, 2011)
Published Print	23 years, 9 months ago (Dec. 1, 2001)

Funders 0

None

BibTeX

@article{Tang_2001, title={High-temperature thermoelectric properties of n-type BayNixCo4‚àíxSb12}, volume={16}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.2001.0460}, DOI={10.1557/jmr.2001.0460}, number={12}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Tang, X. F. and Zhang, L. M. and Yuan, R. Z. and Chen, L. D. and Goto, T. and Hirai, T. and Dyck, J. S. and Chen, W. and Uher, C.}, year={2001}, month=dec, pages={3343‚Äì3346} }

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  "abstract": "<jats:p>Effects of Ba filling fraction and Ni content on the thermoelectric properties of <jats:italic>n</jats:italic>-type Ba<jats:sub><jats:italic>y</jats:italic></jats:sub>Ni<jats:sub><jats:italic>x</jats:italic></jats:sub>Co<jats:sub>4\u2212<jats:italic>x</jats:italic></jats:sub>Sb<jats:sub>12</jats:sub> (<jats:italic>x</jats:italic> = 0\u22120.1, <jats:italic>y</jats:italic> = 0\u22120.4) were investigated at temperature range of 300 to 900 K. Thermal conductivity decreased with increasing Ba filling fraction and temperature. When <jats:italic>y</jats:italic> was fixed at 0.3, thermal conductivity decreased with increasing Ni content and reached a minimum value at about <jats:italic>x</jats:italic> = 0.05. Lattice thermal conductivity decreased with increasing Ni content, monotonously (<jats:italic>y</jats:italic> \u2264 0.1). Electron concentration and electrical conductivity increased with increasing Ba filling fraction and Ni content. Seebeck coefficient increased with increasing temperature and decreased with increasing Ba filling fraction and Ni content. The maximum <jats:italic>ZT</jats:italic> value of 1.25 was obtained at about 900 K for <jats:italic>n</jats:italic>-type Ba<jats:sub>0.3</jats:sub>Ni<jats:sub>0.05</jats:sub>Co<jats:sub>3.95</jats:sub>Sb<jats:sub>12</jats:sub>.</jats:p>",
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