DOI: 10.1557/jmr.2001.0114. Thermodynamic stability of tetragonal zirconia nanocrystallites

Thermodynamic stability of tetragonal zirconia nanocrystallites

10.1557/jmr.2001.0114

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

The thermodynamic stability of tetragonal (t-) ZrO2nanocrystallites below the bulk stability temperature 1200 °C was studied through specially synthesized crystallites that exhibited an extremely slow coarsening rate. The nanocrystallites were mechanically transformed to the monoclinic (m-) structure, and, because the crystallite size was kept below approximately 20 nm, thet-structure was completely recovered solely by thermal treatments between 900 and 1100 °C. These results gave strong evidence to the notion that, for sufficiently small crystallite size, nanocrystallinet-ZrO2is not just kinetically metastable but can be truly thermodynamically more stable than thempolymorph in air below 1200 °C.

Bibliography

Wu, N.-L., Wu, T.-F., & Rusakova, I. A. (2001). Thermodynamic stability of tetragonal zirconia nanocrystallites. Journal of Materials Research, 16(3), 666â669.

Authors 3

Nae-Lih Wu (first)
Ton-Fon Wu (additional)
Irene A. Rusakova (additional)

References 31 Referenced 48

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Dates

Type	When
Created	17 years, 5 months ago (March 5, 2008, 9:39 p.m.)
Deposited	1 year, 6 months ago (Feb. 23, 2024, 1:51 a.m.)
Indexed	1 year, 3 months ago (May 15, 2024, 2:19 p.m.)
Issued	24 years, 6 months ago (March 1, 2001)
Published	24 years, 6 months ago (March 1, 2001)
Published Online	12 years, 9 months ago (Nov. 26, 2012)
Published Print	24 years, 6 months ago (March 1, 2001)

Funders 0

None

BibTeX

@article{Wu_2001, title={Thermodynamic stability of tetragonal zirconia nanocrystallites}, volume={16}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.2001.0114}, DOI={10.1557/jmr.2001.0114}, number={3}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Wu, Nae-Lih and Wu, Ton-Fon and Rusakova, Irene A.}, year={2001}, month=mar, pages={666–669} }

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