DOI: 10.1557/jmr.1998.0353. Preparation of β–SiC Nanorods with and Without Amorphous SiO<sub>2</sub> Wrapping Layers

Preparation of β–SiC Nanorods with and Without Amorphous SiO2 Wrapping Layers

10.1557/jmr.1998.0353

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

Preparation of β–SiC nanorods with and without amorphous SiO2 wrapping layers was achieved by carbothermal reduction of sol-gel derived silica xerogels containing carbon nanoparticles. The β–SiC nanorods with amorphous SiO2 wrapping layers were obtained by carboreduction at 1650 °C for 1.5 h, and at the end of 1.5 h the temperature was steeply raised to 1800 °C and held for 30 min; they are typically up to 20 µm in length. The diameters of the center thinner β–SiC nanorods within the amorphous SiO2 wrapping layers are in the range 10–30 nm, while the outer diameters of the corresponding amorphous SiO2 wrapping layers are between 20 and 70 nm. The β–SiC nanorods without amorphous SiO2 wrapping layers were produced by carbothermal reduction only at 1650 °C for 2.5 h, and their diameters are in agreement with those of the center thinner β–SiC nanorods wrapped in amorphous SiO2 layers. Large quantities of SiC rod nuclei and the nanometer-sized nucleus sites on carbon nanoparticles are both favorable to the formation of much thinner β–SiC nanorods. The formation of the outer amorphous SiO2 wrapping layer is from the combination reaction of decomposed SiO vapor and O2.

Bibliography

Meng, G. W., Zhang, L. D., Mo, C. M., Zhang, S. Y., Qin, Y., Feng, S. P., & Li, H. J. (1998). Preparation of Î²âSiC Nanorods with and Without Amorphous SiO2 Wrapping Layers. Journal of Materials Research, 13(9), 2533â2538.

Authors 7

G. W. Meng (first)
L. D. Zhang (additional)
C. M. Mo (additional)
S. Y. Zhang (additional)
Y. Qin (additional)
S. P. Feng (additional)
H. J. Li (additional)

References 36 Referenced 150

10.1126/science.269.5226.966
10.1016/0022-0248(67)90031-0
10.1016/0022-0248(82)90149-X
10.1016/0025-5408(69)90032-4
10.1063/1.118711
10.1126/science.277.5330.1287
10.1126/science.274.5293.1701
10.1038/364430a0
10.1126/science.273.5276.765
10.1063/1.113716
10.1038/354056a0
10.1016/0025-5408(90)90026-X / Mater. Res. Bull. by Julre (1990)
10.1016/0022-0248(71)90100-X
10.1103/PhysRevB.51.11229
10.1007/BF00557132
10.1007/BF00353022
{'key': 'S0884291400045891_ref027', 'first-page': '39', 'volume': '4', 'author': 'Wanger', 'year': '1964', 'journal-title': 'Appl. Phys. Lett.'} / Appl. Phys. Lett. by Wanger (1964)
10.1007/BF02403970
10.1016/S0009-2614(96)01441-8
10.1038/369301a0
10.1007/BF00542919 / J. Mater. Sci. by Tadahiro (1992)
10.1126/science.264.5156.249
10.1016/S0965-9773(97)00177-3
10.1126/science.267.5195.222
10.1126/science.277.5334.1971
10.1007/BF01113906
10.1111/j.1151-2916.1991.tb06856.x
10.1111/j.1151-2916.1963.tb11733.x
10.1126/science.273.5283.1836
10.1063/1.120550
{'key': 'S0884291400045891_ref036', 'volume': '62', 'author': 'Wei', 'year': '1983', 'journal-title': 'J. Am. Ceram. Soc.'} / J. Am. Ceram. Soc. by Wei (1983)
10.1038/360444a0
10.1038/375769a0
10.1111/j.1151-2916.1972.tb13430.x
10.1016/0009-2614(94)00342-4
10.1007/BF01026309

Dates

Type	When
Created	17 years, 5 months ago (March 13, 2008, 6:42 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 5:07 p.m.)
Indexed	3 months ago (May 31, 2025, 8:25 p.m.)
Issued	27 years ago (Sept. 1, 1998)
Published	27 years ago (Sept. 1, 1998)
Published Online	14 years, 7 months ago (Jan. 31, 2011)
Published Print	27 years ago (Sept. 1, 1998)

Funders 0

None

BibTeX

@article{Meng_1998, title={Preparation of β–SiC Nanorods with and Without Amorphous SiO2 Wrapping Layers}, volume={13}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1998.0353}, DOI={10.1557/jmr.1998.0353}, number={9}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Meng, G. W. and Zhang, L. D. and Mo, C. M. and Zhang, S. Y. and Qin, Y. and Feng, S. P. and Li, H. J.}, year={1998}, month=sep, pages={2533–2538} }

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