DOI: 10.1557/jmr.1998.0337. Chemical Attachment of Organic Functional Groups to Single-walled Carbon Nanotube Material

Chemical Attachment of Organic Functional Groups to Single-walled Carbon Nanotube Material

10.1557/jmr.1998.0337

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

We have subjected single-walled carbon nanotube materials (SWNTM's) to a variety of organic functionalization reactions. These reactions include radioactive photolabeling studies using diradical and nitrene sources, and treatment with dichlorocarbene and Birch reduction conditions. All of the reactions provide evidence for chemical attachment to the SWNTM's, but because of the impure nature of the staring materials, we are unable to ascertain the site of reaction. In the case of dichlorocarbene we are able to show the presence of chlorine in the SWNT bundles, but as a result of the large amount of amorphous carbon that is attached to the tube walls, we cannot distinguish between attachment of dichlorocarbene to the walls of the SWNT's and reaction with the amorphous carbon.

Bibliography

Chen, Y., Haddon, R. C., Fang, S., Rao, A. M., Eklund, P. C., Lee, W. H., Dickey, E. C., Grulke, E. A., Pendergrass, J. C., Chavan, A., Haley, B. E., & Smalley, R. E. (1998). Chemical Attachment of Organic Functional Groups to Single-walled Carbon Nanotube Material. Journal of Materials Research, 13(9), 2423â2431.

Authors 12

Y. Chen (first)
R. C. Haddon (additional)
S. Fang (additional)
A. M. Rao (additional)
P. C. Eklund (additional)
W. H. Lee (additional)
E. C. Dickey (additional)
E. A. Grulke (additional)
J. C. Pendergrass (additional)
A. Chavan (additional)
B. E. Haley (additional)
R. E. Smalley (additional)

References 29 Referenced 261

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Dates

Type	When
Created	17 years, 5 months ago (March 13, 2008, 6:42 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 5:07 p.m.)
Indexed	1 week ago (Aug. 26, 2025, 3:01 a.m.)
Issued	27 years ago (Sept. 1, 1998)
Published	27 years ago (Sept. 1, 1998)
Published Online	14 years, 7 months ago (Jan. 31, 2011)
Published Print	27 years ago (Sept. 1, 1998)

Funders 0

None

BibTeX

@article{Chen_1998, title={Chemical Attachment of Organic Functional Groups to Single-walled Carbon Nanotube Material}, volume={13}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1998.0337}, DOI={10.1557/jmr.1998.0337}, number={9}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Chen, Y. and Haddon, R. C. and Fang, S. and Rao, A. M. and Eklund, P. C. and Lee, W. H. and Dickey, E. C. and Grulke, E. A. and Pendergrass, J. C. and Chavan, A. and Haley, B. E. and Smalley, R. E.}, year={1998}, month=sep, pages={2423–2431} }

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