Abstract
Gold particles smaller than 2 nm in diameter were grown in glass. Their optical absorption spectrum did not show the usual plasma absorption band for gold particles; this band was spread by the small particle size. The absorption spectrum was calculated from the bulk optical properties of gold, modified for the small particle size; there was good agreement between calculated and measured spectra. The smallest particles containing from 20 to 40 gold atoms showed a λ−4 dependence of absorption on wavelength λ. This result implies that the absorption in these particles was entirely from free electrons at wavelengths above 0.3 μm.
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Dates
Type | When |
---|---|
Created | 17 years, 5 months ago (March 5, 2008, 8:57 p.m.) |
Deposited | 4 years, 6 months ago (Feb. 24, 2021, 5:01 p.m.) |
Indexed | 3 months ago (May 26, 2025, 7:44 a.m.) |
Issued | 28 years, 10 months ago (Nov. 1, 1996) |
Published | 28 years, 10 months ago (Nov. 1, 1996) |
Published Online | 14 years, 7 months ago (Jan. 31, 2011) |
Published Print | 28 years, 10 months ago (Nov. 1, 1996) |
@article{Doremus_1996, title={Optical properties of nanosized gold particles}, volume={11}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1996.0358}, DOI={10.1557/jmr.1996.0358}, number={11}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Doremus, Robert H. and Rao, Pratima}, year={1996}, month=nov, pages={2834–2840} }