DOI: 10.1557/jmr.1995.3149. Phase transformations in rapid thermal processed lead zirconate titanate

Phase transformations in rapid thermal processed lead zirconate titanate

10.1557/jmr.1995.3149

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

The crystallization kinetics of the pyrochlore to perovskite phase transformation in lead zirconate titanate (PZT) thin films have been analyzed using rapid thermal processing (RTP). Sol-gel PZT thin films, fabricated on platinum electrodes, were annealed at 550 °C to 650 °C with hold times ranging from 1 s to 5 min. Glancing angle x-ray diffraction (XRD) was used for depth profiling to identify the location of phases in the films. Transmission electron microscopy (TEM) provided information on grain structure, nucleation, and growth. The phase information was correlated to the ferroelectric and dielectric properties. The perovskite phase nucleated in the pyrochlore phase throughout the film thickness, and at 650 °C the transformation was complete in 15 s. Fast growing (100) PZT nucleated at the platinum and consumed a small-grained matrix until a columnar structure was obtained. A ramp rate of 100 °C/s was sufficiently fast to prevent transformation during heating and allowed the direct application of an Avrami model for transformation kinetics. An activation energy of 610 kJ/mol was determined.

Bibliography

Griswold, E. M., Weaver, L., Sayer, M., & Calder, I. D. (1995). Phase transformations in rapid thermal processed lead zirconate titanate. Journal of Materials Research, 10(12), 3149â3159.

Authors 4

Ellen M. Griswold (first)
L. Weaver (additional)
M. Sayer (additional)
I.D. Calder (additional)

References 26 Referenced 46

{'key': 'S0884291400080468_ref025', 'first-page': '15', 'volume-title': 'Ferroelectric Thin Films III', 'volume': '310', 'author': 'Voigt', 'year': '1993'} / Ferroelectric Thin Films III by Voigt (1993)
10.1007/BF01113575
{'key': 'S0884291400080468_ref022', 'first-page': '1103', 'volume': '7', 'author': 'Avrami', 'year': '1939', 'journal-title': 'Chem. Phys.'} / Chem. Phys. by Avrami (1939)
10.1103/PhysRevLett.74.3848
10.1143/JJAP.33.2675
10.1111/j.1151-2916.1994.tb04602.x
10.1080/10584589508019359 / J. Integrated Ferroelectrics by Sayer (1995)
10.1016/0040-6090(93)90540-6
10.1080/10584589508012305
10.1557/JMR.1993.0339
7 Kingon A. et al., in Proceedings of NATO Advanced Studies Workshop on Ferroelectric Thin Films, Italy, lune 1994.
10.1063/1.109943
10.1111/j.1151-2916.1994.tb05394.x
10.1557/JMR.1994.2968
{'key': 'S0884291400080468_ref001', 'volume-title': 'Ferroelectric Thin Films III', 'volume': '310', 'author': 'Tuttle', 'year': '1993'} / Ferroelectric Thin Films III by Tuttle (1993)
10.1063/1.355889
{'key': 'S0884291400080468_ref016', 'author': 'Weaver', 'year': '1995', 'journal-title': 'J. Res. Micros. Techniques'} / J. Res. Micros. Techniques by Weaver (1995)
{'key': 'S0884291400080468_ref024', 'first-page': '85', 'volume-title': 'Ferroelectric Films', 'volume': '25', 'author': 'Kwok', 'year': '1992'} / Ferroelectric Films by Kwok (1992)
10.1063/1.351307
10.1111/j.1151-2916.1993.tb03936.x
10.1143/JJAP.33.260
10.1063/1.351726
{'key': 'S0884291400080468_ref026', 'first-page': '389', 'volume-title': 'Ferroelectric Thin Films IV', 'volume': '361–C5', 'author': 'Griswold', 'year': '1995'} / Ferroelectric Thin Films IV by Griswold (1995)
10.1139/p91-043
10.1111/j.1151-2916.1994.tb05398.x
{'key': 'S0884291400080468_ref014', 'first-page': '1', 'volume-title': 'Proceedings of 3rd International Symposium on Integrated Ferroelectrics (ISIF 91)', 'author': 'Sayer', 'year': '1991'} / Proceedings of 3rd International Symposium on Integrated Ferroelectrics (ISIF 91) by Sayer (1991)

Dates

Type	When
Created	17 years, 11 months ago (Sept. 27, 2007, 8:27 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 4:58 p.m.)
Indexed	1 year, 6 months ago (Feb. 20, 2024, 3:59 a.m.)
Issued	29 years, 8 months ago (Dec. 1, 1995)
Published	29 years, 8 months ago (Dec. 1, 1995)
Published Online	14 years, 5 months ago (March 3, 2011)
Published Print	29 years, 8 months ago (Dec. 1, 1995)

Funders 0

None

BibTeX

@article{Griswold_1995, title={Phase transformations in rapid thermal processed lead zirconate titanate}, volume={10}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1995.3149}, DOI={10.1557/jmr.1995.3149}, number={12}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Griswold, Ellen M. and Weaver, L. and Sayer, M. and Calder, I.D.}, year={1995}, month=dec, pages={3149–3159} }

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