DOI: 10.1557/jmr.1995.1345. Extended x-ray absorption fine structure determination of local structure in sol-gel-derived lead titanate, lead zirconate, and lead zirconate titanate

Extended x-ray absorption fine structure determination of local structure in sol-gel-derived lead titanate, lead zirconate, and lead zirconate titanate

10.1557/jmr.1995.1345

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

We report on extended x-ray absorption fine structure (EXAFS) measurements for partially heat-treated gels in the lead zirconate titanate system (PZT). Self-consistent results obtained from the titanium and zirconium K-edges and the lead LIll-edge were used to determine bonding pathways between cations. For lead titantate (PT) and PZT gels, separate networks of predominantly Ti-O-Ti, Zr-O-Zr, and Pb-O-Pb linkages were observed. For lead zirconate (PZ) gels, both Zr-O-Pb and Zr-O-Zr linkages were observed. The results indicate heterogeneity at the molecular level. These findings are discussed in terms of the evolution of structure for PZT materials prepared by our sol-gel method.

Bibliography

Sengupta, S. S., Ma, L., Adler, D. L., & Payne, D. A. (1995). Extended x-ray absorption fine structure determination of local structure in sol-gel-derived lead titanate, lead zirconate, and lead zirconate titanate. Journal of Materials Research, 10(6), 1345â1348.

Authors 4

S.S. Sengupta (first)
L. Ma (additional)
D.L. Adler (additional)
D.A. Payne (additional)

References 22 Referenced 44

10.1126/science.238.4834.1664
10.1109/58.4153
10.1016/0022-3697(90)90156-A
10.1103/PhysRevB.48.17445
10.1007/978-3-642-50031-2
10.1063/1.1140311
10.1111/j.1151-2916.1991.tb04328.x
{'key': 'S0884291400078080_ref005', 'volume-title': 'X-Ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS and XANES', 'author': 'Koningsberger', 'year': '1988'} / X-Ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS and XANES by Koningsberger (1988)
10.1063/1.341613
10.1103/PhysRevB.41.8139
{'key': 'S0884291400078080_ref019', 'first-page': '61', 'volume': '57', 'author': 'Li', 'year': '1988', 'journal-title': 'J. Can. Ceram. Soc.'} / J. Can. Ceram. Soc. by Li (1988)
10.1080/13642818808208469
{'key': 'S0884291400078080_ref011', 'volume': '3', 'author': 'Turrillas', 'journal-title': 'J. Mater. Chem.'} / J. Mater. Chem. by Turrillas
16Self-absorption at the Ti K-edge is not important in the PT and PZT materials, due to the heavy absorption of Pb which effectively dilutes the Ti. For TiO2, the sample was less than one absorption length (7 μm) thick.
10.1016/0168-9002(91)90642-4
{'key': 'S0884291400078080_ref015', 'first-page': '107', 'volume': '36', 'author': 'Budd', 'year': '1985', 'journal-title': 'Brit. Ceram. Proc.'} / Brit. Ceram. Proc. by Budd (1985)
22 Lakeman C. D. E. , Xu Z. , and Payne D. A. , unpublished results.
10.1016/0022-3093(91)90125-P
10.1557/JMR.1993.0339
10.1002/bbpc.19910951020
10.1063/1.108288
10.1103/RevModPhys.53.769

Dates

Type	When
Created	17 years, 11 months ago (Sept. 27, 2007, 8:25 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 4:55 p.m.)
Indexed	2 months ago (June 24, 2025, 7:29 a.m.)
Issued	30 years, 2 months ago (June 1, 1995)
Published	30 years, 2 months ago (June 1, 1995)
Published Online	14 years, 5 months ago (March 3, 2011)
Published Print	30 years, 2 months ago (June 1, 1995)

Funders 0

None

BibTeX

@article{Sengupta_1995, title={Extended x-ray absorption fine structure determination of local structure in sol-gel-derived lead titanate, lead zirconate, and lead zirconate titanate}, volume={10}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1995.1345}, DOI={10.1557/jmr.1995.1345}, number={6}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Sengupta, S.S. and Ma, L. and Adler, D.L. and Payne, D.A.}, year={1995}, month=jun, pages={1345–1348} }

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