DOI: 10.1557/jmr.1995.1327. Coating of uniform inorganic particles with polymers: III. Polypyrrole on different metal oxides

Coating of uniform inorganic particles with polymers: III. Polypyrrole on different metal oxides

10.1557/jmr.1995.1327

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

Five kinds of uniform metal oxide particles (α-Fe2O3, CeO2, CuO, NiO, and SiO2) were coated with polypyrrole by reacting the dispersed solids with pyrrole in a water/ethanol medium without the use of a soluble oxidant. When the process was carried out in air, all particles were coated with the polymer, although the thickness of the layer varied on different cores. In CuO dispersions, independent polypyrrole particles were produced in addition to coated spheres. While oxygen is the major oxidant that initiates the polymerization of pyrrole, some metal oxides may also affect the reaction both in terms of the amount and the composition of the shell. Thus, α-Fe2O3 and SiO2 were found to be inactive in the polymerization, while CeCh and CuO react with the adsorbed pyrrole molecules through a reductive-dissolution process, in which the monomers are oxidized, causing a release of reduced metal ions.

Bibliography

Huang, C.-L., & Matijevic, E. (1995). Coating of uniform inorganic particles with polymers: III. Polypyrrole on different metal oxides. Journal of Materials Research, 10(5), 1327â1336.

Authors 2

Chin-Lin Huang (first)
Egon Matijevic (additional)

References 26 Referenced 67

10.1016/0022-2852(61)90242-9
10.1063/1.445237
10.1039/f19878301507
10.1557/JMR.1994.1140
10.1080/00268948208072174
10.1006/jcis.1993.1080
10.1016/S0021-9797(78)80011-3
10.1021/la00079a005
10.1016/0032-5910(90)80052-Z
10.1006/jcis.1993.1400
10.1002/app.1993.070480807
{'key': 'S0884291400078079_ref005', 'author': 'Huang', 'year': '1995', 'journal-title': 'J. Colloid Interface Sci.'} / J. Colloid Interface Sci. by Huang (1995)
10.1007/BF02649904
10.1080/00268948508080109
10.1007/BF00654585
{'key': 'S0884291400078079_ref016', 'first-page': '280', 'volume-title': 'Chemical Dissolution of Metal Oxides', 'author': 'Blesa', 'year': '1994'} / Chemical Dissolution of Metal Oxides by Blesa (1994)
{'key': 'S0884291400078079_ref017', 'volume-title': 'Aquatic Surface Chemistry', 'author': 'Stone', 'year': '1987'} / Aquatic Surface Chemistry by Stone (1987)
{'key': 'S0884291400078079_ref022', 'first-page': '68', 'volume-title': 'Advances in HeterocycUc Chemistry', 'volume': '15', 'author': 'Gardini', 'year': '1973'} / Advances in HeterocycUc Chemistry by Gardini (1973)
10.1016/0927-7757(94)02952-0
10.1016/0040-6090(94)90845-1
10.1016/0021-9797(91)90234-Y
{'key': 'S0884291400078079_ref020', 'volume-title': 'Emulsion Polymerisation', 'author': 'Blackley', 'year': '1975'} / Emulsion Polymerisation by Blackley (1975)
10.1016/S0022-0728(83)80561-0
10.1295/koron.40.697
10.1016/0021-9797(68)90272-5
10.1039/c39860001293

Dates

Type	When
Created	17 years, 11 months ago (Sept. 27, 2007, 8:24 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 4:55 p.m.)
Indexed	1 year, 2 months ago (May 31, 2024, 10:54 p.m.)
Issued	30 years, 3 months ago (May 1, 1995)
Published	30 years, 3 months ago (May 1, 1995)
Published Online	14 years, 5 months ago (March 3, 2011)
Published Print	30 years, 3 months ago (May 1, 1995)

Funders 0

None

BibTeX

@article{Huang_1995, title={Coating of uniform inorganic particles with polymers: III. Polypyrrole on different metal oxides}, volume={10}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1995.1327}, DOI={10.1557/jmr.1995.1327}, number={5}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Huang, Chin-Lin and Matijevic, Egon}, year={1995}, month=may, pages={1327–1336} }

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