DOI: 10.1557/jmr.1995.0692. Synthesis and characterization of TiO<sub>2</sub> thin films on organic self-assembled monolayers: Part I. Film formation from aqueous solutions

Synthesis and characterization of TiO2 thin films on organic self-assembled monolayers: Part I. Film formation from aqueous solutions

10.1557/jmr.1995.0692

Crossref journal-article

Springer Science and Business Media LLC

Journal of Materials Research (297)

Abstract

Self-assembled monolayers (SAMs) bearing sulfonate (-SO3H) surface functional groups, on single-crystal Si wafers, were used as substrates for the deposition of TiO2 thin films from aqueous solutions. Polycrystalline TiO2 thin films over 50 nm thick formed in 2 h by hydrolysis of TiCl4 in aqueous HCI solutions at 80 °C. The films were pore-free, showed excellent adherence and uniformity, and consisted of anatase crystallites 2–4 nm in diameter. Annealing at temperatures up to 600 °C caused coarsening of the anatase grains, but no loss of adherence or structural integrity.

Bibliography

Shin, H., Collins, R. J., De Guire, M. R., Heuer, A. H., & Sukenik, C. N. (1995). Synthesis and characterization of TiO2 thin films on organic self-assembled monolayers: Part I. Film formation from aqueous solutions. Journal of Materials Research, 10(3), 692â698.

Authors 5

H. Shin (first)
R.J. Collins (additional)
M.R. De Guire (additional)
A.H. Heuer (additional)
C.N. Sukenik (additional)

References 37 Referenced 130

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Dates

Type	When
Created	17 years, 11 months ago (Sept. 27, 2007, 8:23 a.m.)
Deposited	4 years, 6 months ago (Feb. 24, 2021, 4:54 p.m.)
Indexed	2 weeks, 1 day ago (Aug. 12, 2025, 5:40 p.m.)
Issued	30 years, 5 months ago (March 1, 1995)
Published	30 years, 5 months ago (March 1, 1995)
Published Online	14 years, 5 months ago (March 3, 2011)
Published Print	30 years, 5 months ago (March 1, 1995)

Funders 0

None

BibTeX

@article{Shin_1995, title={Synthesis and characterization of TiO2 thin films on organic self-assembled monolayers: Part I. Film formation from aqueous solutions}, volume={10}, ISSN={2044-5326}, url={http://dx.doi.org/10.1557/jmr.1995.0692}, DOI={10.1557/jmr.1995.0692}, number={3}, journal={Journal of Materials Research}, publisher={Springer Science and Business Media LLC}, author={Shin, H. and Collins, R.J. and De Guire, M.R. and Heuer, A.H. and Sukenik, C.N.}, year={1995}, month=mar, pages={692–698} }

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