DOI: 10.1524/zkri.1993.208.part-1.35. Synthesis and structure of Ba2LaAg5S6 and Ba2YAg5S6

Synthesis and structure of Ba2LaAg5S6 and Ba2YAg5S6

10.1524/zkri.1993.208.part-1.35

Crossref journal-article

Walter de Gruyter GmbH

Zeitschrift für Kristallographie - Crystalline Materials (374)

Abstract

Abstract The new quaternary sulfides Ba2LaAg5S6 and Ba2YAg5S6 have been synthesized by the reaction among BaS, La2S3 or Y2S3, Ag, and S at 1000[unk]C. The crystal structure of Ba2LaAg5S6 has been determined by X-ray diffraction techniques. Crystal data: space group C2/m, M = 1145.3, Z = 2, a = 13.909(9), b = 4.229(3), c = 11.213(7) Å, β = 94.81(3)[unk] (T = 115 K), V = 657.2 Å3, R w(F2) = 0.191 for 1611 observations and 45 variables, R(F) = 0.069 for 1594 observations having F o 2 > 2σ(F o 2). The structure has a three-dimensional framework with channels that accommodate barium ions. The lanthanum atoms have octahedral coordination and silver atoms exhibit both tetrahedral and linear coordination. From Weissenberg photography Ba2YAg5S6 has cell dimensions at room temperature of a = 14.02(2), b = 4.18(1), c = 11.28(2) Å, β = 95.0(2)[unk] and appears to be isostructural with Ba2LaAg5S6.

Bibliography

Wu, P., & Ibers, J. A. (Eds.). (1993). Synthesis and structure of Ba2LaAg5S6 and Ba2YAg5S6. Zeitschrift FÃ¼r Kristallographie - Crystalline Materials, 208(1), 35â41.

Authors 0

None

References 10 Referenced 10

10.1063/1.1680242
{'key': 'p_2', 'first-page': '881', 'volume': '85', 'author': 'Iandelli', 'year': '1955', 'journal-title': 'Gazz. Chim. Ital.'} / Gazz. Chim. Ital. by Iandelli (1955)
10.1016/0022-5088(85)90370-4
10.1021/ic00017a018 / Inorg. Chem. by Lu Y.-J.
10.1016/0022-4596(91)90204-U
10.1016/S0022-4596(05)80239-7
10.1016/0022-4596(92)90182-U
10.1021/ic50178a057
{'key': 'p_13', 'first-page': '126', 'volume': '49', 'author': 'Wu P.', 'year': '1993', 'journal-title': 'Sect.'} / Sect. by Wu P. (1993)
10.1016/0022-4596(92)90047-Y

Dates

Type	When
Created	15 years, 1 month ago (July 28, 2010, 5:45 a.m.)
Deposited	4 months, 2 weeks ago (April 8, 2025, 6:26 a.m.)
Indexed	4 months, 2 weeks ago (April 9, 2025, 12:17 a.m.)
Issued	32 years, 7 months ago (Jan. 1, 1993)
Published	32 years, 7 months ago (Jan. 1, 1993)
Published Online	15 years, 1 month ago (July 28, 2010)
Published Print	32 years, 7 months ago (Jan. 1, 1993)

Funders 0

None

BibTeX

@article{1993, title={Synthesis and structure of Ba2LaAg5S6 and Ba2YAg5S6}, volume={208}, ISSN={2196-7105}, url={http://dx.doi.org/10.1524/zkri.1993.208.part-1.35}, DOI={10.1524/zkri.1993.208.part-1.35}, number={1}, journal={Zeitschrift für Kristallographie - Crystalline Materials}, publisher={Walter de Gruyter GmbH}, year={1993}, month=jan, pages={35–41} }

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  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The new quaternary sulfides Ba<jats:sub>2</jats:sub>LaAg<jats:sub>5</jats:sub>S<jats:sub>6</jats:sub> and Ba<jats:sub>2</jats:sub>YAg<jats:sub>5</jats:sub>S<jats:sub>6</jats:sub> have been synthesized by the reaction among BaS, La<jats:sub>2</jats:sub>S<jats:sub>3</jats:sub> or Y<jats:sub>2</jats:sub>S<jats:sub>3</jats:sub>, Ag, and S at 1000[unk]C. The crystal structure of Ba<jats:sub>2</jats:sub>LaAg<jats:sub>5</jats:sub>S<jats:sub>6</jats:sub> has been determined by X-ray diffraction techniques. Crystal data: space group <jats:italic>C</jats:italic>2/<jats:italic>m</jats:italic>, <jats:italic>M</jats:italic> = 1145.3, <jats:italic>Z</jats:italic> = 2, <jats:italic>a</jats:italic> = 13.909(9), <jats:italic>b</jats:italic> = 4.229(3), <jats:italic>c</jats:italic> = 11.213(7) \u00c5, <jats:italic>\u03b2</jats:italic> = 94.81(3)[unk] (<jats:italic>T</jats:italic> = 115 K), <jats:italic>V</jats:italic> = 657.2 \u00c5<jats:sup>3</jats:sup>, <jats:italic>R</jats:italic>\n                  <jats:sub>w</jats:sub>(F<jats:sup>2</jats:sup>) = 0.191 for 1611 observations and 45 variables, <jats:italic>R</jats:italic>(<jats:italic>F</jats:italic>) = 0.069 for 1594 observations having <jats:italic>F</jats:italic>\n                  <jats:sub>o</jats:sub>\n                  <jats:sup>2</jats:sup> &gt; 2<jats:italic>\u03c3</jats:italic>(<jats:italic>F</jats:italic>\n                  <jats:sub>o</jats:sub>\n                  <jats:sup>2</jats:sup>). The structure has a three-dimensional framework with channels that accommodate barium ions. The lanthanum atoms have octahedral coordination and silver atoms exhibit both tetrahedral and linear coordination. From Weissenberg photography Ba<jats:sub>2</jats:sub>YAg<jats:sub>5</jats:sub>S<jats:sub>6</jats:sub> has cell dimensions at room temperature of <jats:italic>a</jats:italic> = 14.02(2), <jats:italic>b</jats:italic> = 4.18(1), <jats:italic>c</jats:italic> = 11.28(2) \u00c5, <jats:italic>\u03b2</jats:italic> = 95.0(2)[unk] and appears to be isostructural with Ba<jats:sub>2</jats:sub>LaAg<jats:sub>5</jats:sub>S<jats:sub>6</jats:sub>.</jats:p>",
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