DOI: 10.1524/zkri.1991.194.3-4.199. Synthesis and crystal structure of Co(PO<sub>3</sub>OH)

Synthesis and crystal structure of Co(PO3OH) · H2O

10.1524/zkri.1991.194.3-4.199

Crossref journal-article

Walter de Gruyter GmbH

Zeitschrift für Kristallographie - Crystalline Materials (374)

Abstract

Abstract Syntheses under moderate hydrothermal conditions yielded single crystals of the compound Co(PO3OH) · H2O: a = 15.956(3) Å, c = 7.703(2) Å, space group R[unk], Z = 18. The crystal structure was determined from 932 X-ray reflections with sinθ/λ ≤ 0.70 Å−1; Refinement gave R = 0.032. Slightly distorted CoO6 octahedra (Co – O from 2.052(2) to 2.174(2) Å, 〈2.111 Å〉) share two common O – O edges resulting in helical ∞ 1[CoO4] rows parallel to [001]. These rows are interconnected by protonated phosphate tetrahedra. Within the phosphate tetrahedron the P – O distance to the hydroxyl group is 1.585(2) Å, the three other P – O distances range from 1.519(2) to 1.530(2) Å. The hydrogen bonds line the surface of unoccupied channels of diameter 4.63 Å running in [001]; O – H … O range from 2.654(4) to 2.720(5) Å.

Bibliography

Effenberger, H., Parik, R., Pertlik, F., & Rieck, B. (Eds.). (1991). Synthesis and crystal structure of Co(PO3OH) Â· H2O. Zeitschrift FÃ¼r Kristallographie - Crystalline Materials, 194(3â4), 199â206.

Authors 0

None

References 15 Referenced 6

{'key': 'p_1', 'first-page': '122', 'volume': '103', 'author': 'Bari H.', 'year': '1980', 'journal-title': 'Bull. Mineral.'} / Bull. Mineral. by Bari H. (1980)
10.1016/0025-5408(80)90070-7
{'key': 'p_6', 'first-page': '244', 'volume': '41', 'year': '1985', 'journal-title': 'Acta Crystallogr.'} / Acta Crystallogr. (1985)
10.1107/S0567740876006869 / Acta Crystallogr. by Brown I. D. (1976)
{'key': 'p_9', 'first-page': '129', 'volume': '103', 'author': 'Catti M.', 'year': '1980', 'journal-title': 'Bull. Mineral.'} / Bull. Mineral. by Catti M. (1980)
{'key': 'p_10', 'first-page': '1248', 'volume': '64', 'author': 'Catti M.', 'year': '1979', 'journal-title': 'Am. Mineral.'} / Am. Mineral. by Catti M. (1979)
{'key': 'p_11', 'first-page': '271', 'volume': '94', 'author': 'Corbridge D. E. C.', 'year': '1971', 'journal-title': 'Mineral. Cristallogr.'} / Mineral. Cristallogr. by Corbridge D. E. C. (1971)
10.1107/S0567740872002080 / Acta Crystallogr. by Ferraris G. (1972)
10.1524/zkri.1983.164.1-2.25 / Z. Kristallogr. by Herak R. (1983)
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{'key': 'p_20', 'first-page': '316', 'volume': '138', 'author': 'Jahrb', 'year': '1980', 'journal-title': 'Miner. Abh.'} / Miner. Abh. by Jahrb (1980)
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{'key': 'p_22', 'first-page': '194', 'volume': '43', 'author': 'Riou A.', 'year': '1987', 'journal-title': 'Acta Crystallogr.'} / Acta Crystallogr. by Riou A. (1987)
10.1107/S0365110X67003202
10.1002/zaac.19794540121

Dates

Type	When
Created	14 years, 11 months ago (Aug. 25, 2010, 6:21 a.m.)
Deposited	4 months, 2 weeks ago (April 8, 2025, 5:52 a.m.)
Indexed	4 months, 2 weeks ago (April 9, 2025, 12:15 a.m.)
Issued	34 years, 6 months ago (Feb. 1, 1991)
Published	34 years, 6 months ago (Feb. 1, 1991)
Published Online	15 years ago (Aug. 25, 2010)
Published Print	34 years, 6 months ago (Feb. 1, 1991)

Funders 0

None

BibTeX

@article{1991, title={Synthesis and crystal structure of Co(PO3OH) · H2O}, volume={194}, ISSN={2196-7105}, url={http://dx.doi.org/10.1524/zkri.1991.194.3-4.199}, DOI={10.1524/zkri.1991.194.3-4.199}, number={3–4}, journal={Zeitschrift für Kristallographie - Crystalline Materials}, publisher={Walter de Gruyter GmbH}, year={1991}, month=feb, pages={199–206} }

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