DOI: 10.1524/zkri.1980.153.3-4.277. Die Strukturchemie der Kupfer(I)Halogenid-Lewisbase Addukte Darstellung und Kristallstruktur von (CuI)<sub>2</sub>

Die Strukturchemie der Kupfer(I)Halogenid-Lewisbase Addukte Darstellung und Kristallstruktur von (CuI)2 · (2-Methylpyridin)

10.1524/zkri.1980.153.3-4.277

Crossref journal-article

Walter de Gruyter GmbH

Zeitschrift für Kristallographie - Crystalline Materials (374)

Abstract

Abstract The 2:1 adduct of CuI and 2-methyl pyridine (pic) can be prepared from a stoichiometric mixture of CuI in CH3CN and pic in ethanol at 60° C. It forms colorless, airstable needles, which show a red luminescence (γ max = 15200 cm−1). (CuI)2 · pic crystallizes monoclinic in the space group P21/c with the lattice constants a = 422.5(2) pm, b = 1079.2(3) pm, c = 2190.7(7) pm, β = 92.67(4)°, Z = 4. It has a “double ribbon” structure with alternating Cu and I atoms. The Cu atoms are tetrahedral coordinated by 4I atoms or 3I atoms and one pic, respectively.

Bibliography

StrÃ¤hle, J., Hiller, W., Eitel, E., & Oelkrug, D. (Eds.). (1980). Die Strukturchemie der Kupfer(I)Halogenid-Lewisbase Addukte Darstellung und Kristallstruktur von (CuI)2 Â· (2-Methylpyridin). Zeitschrift FÃ¼r Kristallographie - Crystalline Materials, 153(3â4), 277â284.

Authors 0

None

References 10 Referenced 10

Dates

Type	When
Created	14 years, 11 months ago (Sept. 16, 2010, 8:46 a.m.)
Deposited	4 months, 2 weeks ago (April 8, 2025, 6:12 a.m.)
Indexed	4 months, 2 weeks ago (April 9, 2025, 12:16 a.m.)
Issued	45 years, 6 months ago (Feb. 1, 1980)
Published	45 years, 6 months ago (Feb. 1, 1980)
Published Online	14 years, 11 months ago (Sept. 16, 2010)
Published Print	45 years, 6 months ago (Feb. 1, 1980)

Funders 0

None

BibTeX

@article{1980, title={Die Strukturchemie der Kupfer(I)Halogenid-Lewisbase Addukte Darstellung und Kristallstruktur von (CuI)2 · (2-Methylpyridin)}, volume={153}, ISSN={2196-7105}, url={http://dx.doi.org/10.1524/zkri.1980.153.3-4.277}, DOI={10.1524/zkri.1980.153.3-4.277}, number={3–4}, journal={Zeitschrift für Kristallographie - Crystalline Materials}, publisher={Walter de Gruyter GmbH}, year={1980}, month=feb, pages={277–284} }

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