Abstract
A new one-dimensional coordination polymer [Co(CCl3COO)2(CH3OH)2(μ-4,4’-bipy)]n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4’-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) Å ] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.
Dates
Type | When |
---|---|
Created | 7 years, 7 months ago (Jan. 19, 2018, 8:35 a.m.) |
Deposited | 4 years, 2 months ago (June 22, 2021, 12:42 p.m.) |
Indexed | 2 years, 5 months ago (March 5, 2023, 8:29 a.m.) |
Issued | 20 years, 8 months ago (Jan. 1, 2005) |
Published | 20 years, 8 months ago (Jan. 1, 2005) |
Published Online | 11 years, 3 months ago (June 2, 2014) |
Published Print | 20 years, 8 months ago (Jan. 1, 2005) |
@article{Talukder_2005, title={A New One-Dimensional Coordination Polymer [Co(CCl3COO)2(CH3OH)2(μ-4,4’-bipy)]n: Synthesis and Structural Aspects}, volume={60}, ISSN={0932-0776}, url={http://dx.doi.org/10.1515/znb-2005-0106}, DOI={10.1515/znb-2005-0106}, number={1}, journal={Zeitschrift für Naturforschung B}, publisher={Walter de Gruyter GmbH}, author={Talukder, Pritha and Datta, Amitabha and Mitra, Samiran and Rosair, Georgina}, year={2005}, month=jan, pages={33–36} }