DOI: 10.1515/znb-1983-1019. Chirale Erkennung von Naturstoffen an optisch aktiven Polysiloxanen Chiral Recognition of Natural Products on Optically Active Polysiloxanes

Chirale Erkennung von Naturstoffen an optisch aktiven Polysiloxanen Chiral Recognition of Natural Products on Optically Active Polysiloxanes

10.1515/znb-1983-1019

Crossref journal-article

Walter de Gruyter GmbH

Zeitschrift für Naturforschung B (374)

Abstract

Abstract Polysiloxanes with chiral peptide side chains have been synthesized and used as stationary phases in gas chromatography. With these phases amino acid enantiomers can be separated as N-acyl esters. Due to temperature stability up to 230 °C all protein amino acids can be separated and the racemization of synthetic biologically active peptides controlled. The phases can be used to assign the absolute configuration of amino acids. A variety of other classes of compounds can be separated into their enantiomers using the chiral polysiloxanes, like hydroxy acids, sulfoxides, phosphorous compounds, glycols, atrop isomers, amines and alcohols. Various applications of these phases are described including investigations of enantiomer selectivity in nature.

Bibliography

Bayer, E. (1983). Chirale Erkennung von Naturstoffen an optisch aktiven Polysiloxanen Chiral Recognition of Natural Products on Optically Active Polysiloxanes. Zeitschrift FÃ¼r Naturforschung B, 38(10), 1281â1291.

Authors 1

Ernst Bayer (first)

References 0 Referenced 63

None

Dates

Type	When
Created	10 years, 6 months ago (Feb. 21, 2015, 6:30 a.m.)
Deposited	4 years, 2 months ago (June 23, 2021, 8:14 a.m.)
Indexed	1 year, 8 months ago (Jan. 4, 2024, 1:03 p.m.)
Issued	41 years, 11 months ago (Oct. 1, 1983)
Published	41 years, 11 months ago (Oct. 1, 1983)
Published Online	11 years, 3 months ago (June 2, 2014)
Published Print	41 years, 11 months ago (Oct. 1, 1983)

Funders 0

None

BibTeX

@article{Bayer_1983, title={Chirale Erkennung von Naturstoffen an optisch aktiven Polysiloxanen Chiral Recognition of Natural Products on Optically Active Polysiloxanes}, volume={38}, ISSN={0932-0776}, url={http://dx.doi.org/10.1515/znb-1983-1019}, DOI={10.1515/znb-1983-1019}, number={10}, journal={Zeitschrift für Naturforschung B}, publisher={Walter de Gruyter GmbH}, author={Bayer, Ernst}, year={1983}, month=oct, pages={1281–1291} }

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