DOI: 10.1366/0003702971942303. Evaluation of Fourier Transform Near-Infrared for the Simultaneous Analysis of Light Alkene Mixtures

Evaluation of Fourier Transform Near-Infrared for the Simultaneous Analysis of Light Alkene Mixtures

10.1366/0003702971942303

Crossref journal-article

SAGE Publications

Applied Spectroscopy (179)

Abstract

A Fourier transform near-infrared (FT-NIR) spectrometer incorporating a fiber-optic-coupled sample cell was used for simultaneous determination of ethylene and monoalkylated light alkenes in liquid mixtures at room temperature and pressure. Ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, and 1-decene were selected for the evaluation. Several additional alkylated alkenes (e.g., 1,1 dialkylated, cis, trans dialkylated, and trialkylated alkenes) were investigated to determine the effects of the molecular structure on this determination. The first overtone of the asymmetric =CH2 stretch of the monoalkylated alkenes was found to be unique for the light alkenes in the NIR region. This region of the spectrum was used for quantitative analysis using classical least-squares (CLS) regression. Ethylene/1-octene mixtures were studied as an example. The concentrations of these alkenes were determined with an error of less than 1% by weight.

Bibliography

Yalvac, E. D., Seasholtz, M. B., & Crouch, S. R. (1997). Evaluation of Fourier Transform Near-Infrared for the Simultaneous Analysis of Light Alkene Mixtures. Applied Spectroscopy, 51(9), 1303â1310.

Authors 3

E. D. Yalvac (first)
M. B. Seasholtz (additional)
S. R. Crouch (additional)

References 45 Referenced 16

10.1016/0924-2031(94)00054-K
{'key': 'bibr2-0003702971942303', 'volume': '2824', 'author': 'Khettry A.', 'year': '1995', 'journal-title': 'Antec'} / Antec by Khettry A. (1995)
10.1016/0039-9140(93)E0055-I
{'volume-title': 'Polymers for Advanced Technologies', 'year': '1995', 'author': 'Mijovic J.', 'key': 'bibr4-0003702971942303'} / Polymers for Advanced Technologies by Mijovic J. (1995)
{'volume-title': 'Near Infrared Spectroscopy in Food Analysis', 'year': '1980', 'author': 'Osborn B. G.', 'key': 'bibr5-0003702971942303'} / Near Infrared Spectroscopy in Food Analysis by Osborn B. G. (1980)
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{'volume-title': 'Infrared and Raman Spectra', 'year': '1945', 'author': 'Herzberg G.', 'key': 'bibr8-0003702971942303'} / Infrared and Raman Spectra by Herzberg G. (1945)
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{'key': 'bibr11-0003702971942303', 'first-page': '1', 'volume': '49', 'author': 'Plyler E. K.', 'year': '1952', 'journal-title': 'Phys. Rev.'} / Phys. Rev. by Plyler E. K. (1952)
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{'key': 'bibr13-0003702971942303', 'first-page': '1368', 'volume': '21', 'author': 'Wiggins T. A.', 'year': '1953', 'journal-title': 'J. Opt. Soc. Am.'} / J. Opt. Soc. Am. by Wiggins T. A. (1953)
{'key': 'bibr14-0003702971942303', 'first-page': '140', 'volume': '32', 'author': 'Goddu F. R.', 'year': '1960', 'journal-title': 'Anal. Chem.'} / Anal. Chem. by Goddu F. R. (1960)
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{'volume-title': 'Characteristic Frequencies of Organic Compounds', 'year': '1974', 'author': 'Dollish F. R.', 'key': 'bibr22-0003702971942303'} / Characteristic Frequencies of Organic Compounds by Dollish F. R. (1974)
{'volume-title': 'The Interpretation of Vapor-Phase Spectra, Group Frequency Data', 'year': '1984', 'author': 'Nyquist R. A.', 'key': 'bibr23-0003702971942303'} / The Interpretation of Vapor-Phase Spectra, Group Frequency Data by Nyquist R. A. (1984)
{'volume-title': 'The Aldrich Library of FT-IR Spectra', 'year': '1985', 'author': 'Pouchert C. J.', 'key': 'bibr24-0003702971942303'} / The Aldrich Library of FT-IR Spectra by Pouchert C. J. (1985)
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{'volume-title': 'Multivariate Calibration', 'year': '1989', 'author': 'Martens H.', 'key': 'bibr40-0003702971942303'} / Multivariate Calibration by Martens H. (1989)
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10.1002/cem.1180070303
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10.1366/0003702854249376
10.1021/ac00246a007

Dates

Type	When
Created	21 years, 10 months ago (Oct. 17, 2003, 12:32 p.m.)
Deposited	5 months, 3 weeks ago (March 11, 2025, 2:33 a.m.)
Indexed	5 months, 3 weeks ago (March 12, 2025, 12:21 a.m.)
Issued	28 years ago (Sept. 1, 1997)
Published	28 years ago (Sept. 1, 1997)
Published Online	28 years ago (Sept. 1, 1997)
Published Print	28 years ago (Sept. 1, 1997)

Funders 0

None

BibTeX

@article{Yalvac_1997, title={Evaluation of Fourier Transform Near-Infrared for the Simultaneous Analysis of Light Alkene Mixtures}, volume={51}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702971942303}, DOI={10.1366/0003702971942303}, number={9}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Yalvac, E. D. and Seasholtz, M. B. and Crouch, S. R.}, year={1997}, month=sep, pages={1303–1310} }

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  "abstract": "<jats:p> A Fourier transform near-infrared (FT-NIR) spectrometer incorporating a fiber-optic-coupled sample cell was used for simultaneous determination of ethylene and monoalkylated light alkenes in liquid mixtures at room temperature and pressure. Ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, and 1-decene were selected for the evaluation. Several additional alkylated alkenes (e.g., 1,1 dialkylated, cis, trans dialkylated, and trialkylated alkenes) were investigated to determine the effects of the molecular structure on this determination. The first overtone of the asymmetric =CH<jats:sub>2</jats:sub> stretch of the monoalkylated alkenes was found to be unique for the light alkenes in the NIR region. This region of the spectrum was used for quantitative analysis using classical least-squares (CLS) regression. Ethylene/1-octene mixtures were studied as an example. The concentrations of these alkenes were determined with an error of less than 1% by weight. </jats:p>",
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