Abstract
Near-infrared surface-enhanced Raman scattering (NIR SERS) was detected with high sensitivity for two model compounds, crystal violet and the DNA base adenine, adsorbed on silver and gold colloidal particles in aqueous solutions. The NIR SERS spectra were measured with a fiber-optic probe with the use of a Ti:sapphire laser at 850 nm as the excitation source and a charge-coupled device (CCD) as the detection system. In a step to achieve the optimal electromagnetic SERS-enhancement conditions, silver and gold sols were modified to shift their extinction spectra more to the NIR region. Surface enhancement factors for both crystal violet and adenine were estimated to be on the order of 106 and 108 for gold and silver, respectively. A larger enhancement factor was observed for adenine with NIR excitation than with visible excitation. The benefits of NIR SERS and its potential applications are discussed.
References
31
Referenced
99
10.1366/0003702894202940
10.1002/jrs.1250220903
10.1002/jrs.1250220904
10.1366/0003702894204074
10.1021/ac00190a012
- Angel S. M. and Myrick M. L, in Handbook of Near-Infrared Analysis, Burns D. A. and Ciurczak E. W, Eds. (Marcel Dekker, New York, 1992), p. 225.
10.1016/0009-2614(93)89028-G
10.1016/0009-2614(93)89340-N
10.1021/ja00210a016
10.1366/0003702924125555
- Otto A., in Topics in Applied Physics, Vol. 54, Light Scattering in Solids, Cardona M. and Güntherodt G, Eds. (Springer, Berlin, 1984), Vol. 4, p. 289.
10.1021/j100214a025
10.1007/978-1-4615-9257-0_16
10.1016/S0022-0728(77)80224-6
10.1016/0009-2614(82)83054-6
{'key': 'bibr16-0003702944029776', 'first-page': '339', 'volume': '36', 'author': 'Baranov A. V.', 'year': '1982', 'journal-title': 'JETP Lett.'}
/ JETP Lett. by Baranov A. V. (1982)10.1016/S0009-2614(90)87084-5
10.1016/0038-1098(83)90194-1
10.1002/jrs.1250170611
10.1002/jrs.1250240209
10.1016/0039-6028(85)90309-7
10.1135/cccc19860167
10.1021/j100316a046
10.1016/0022-2860(84)87131-8
10.1366/0003702914335427
10.1016/0924-2031(93)80009-5
10.1021/j100287a028
{'key': 'bibr28-0003702944029776', 'first-page': '1977', 'volume': '24', 'author': 'Wang D. S.', 'year': '1981', 'journal-title': 'Phys. Rev.'}
/ Phys. Rev. by Wang D. S. (1981)10.1103/PhysRevB.27.7251
10.1016/B978-0-08-054721-3.50017-4
10.1021/j100173a048
Dates
Type | When |
---|---|
Created | 20 years, 2 months ago (May 31, 2005, 7:36 p.m.) |
Deposited | 5 months, 2 weeks ago (March 10, 2025, 6:12 p.m.) |
Indexed | 5 months ago (March 22, 2025, 4:50 a.m.) |
Issued | 31 years ago (Aug. 1, 1994) |
Published | 31 years ago (Aug. 1, 1994) |
Published Online | 31 years ago (Aug. 1, 1994) |
Published Print | 31 years ago (Aug. 1, 1994) |
@article{Kneipp_1994, title={Near-Infrared Surface-Enhanced Raman Scattering (NIR SERS) on Colloidal Silver and Gold}, volume={48}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702944029776}, DOI={10.1366/0003702944029776}, number={8}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Kneipp, Katrin and Dasari, Ramachandra R. and Wang, Yang}, year={1994}, month=aug, pages={951–955} }