DOI: 10.1366/0003702944028434. Can High-Pressure Raman Spectroscopy Be Simplified? A Microscale Optical-Fiber Capillary Cell for the Study of Supercritical Fluids

Can High-Pressure Raman Spectroscopy Be Simplified? A Microscale Optical-Fiber Capillary Cell for the Study of Supercritical Fluids

10.1366/0003702944028434

Crossref journal-article

SAGE Publications

Applied Spectroscopy (179)

Abstract

This paper reports the design of a simple and inexpensive optical fiber capillary flow cell which is ideally suited to Raman spectroscopy and, in particular, the analysis of high-pressure supercritical fluid solutions. Light is delivered directly to the solution by use of optical fibers which run along the bore of the capillary. For maximum efficiency of light collection, the capillary is mounted directly onto and along the axis of the entrance slit of a dispersive Raman spectrometer. The Raman spectra of supercritical carbon dioxide (scCO2) solutions of gases (e.g., nitrogen and hydrogen), and solid solutes (e.g., naphthalene) are presented.

Bibliography

Howdle, S. M., Stanley, K., Popov, V. K., & Bagratashvili, V. N. (1994). Can High-Pressure Raman Spectroscopy Be Simplified? A Microscale Optical-Fiber Capillary Cell for the Study of Supercritical Fluids. Applied Spectroscopy, 48(2), 214â218.

Authors 4

Steven M. Howdle (first)
Keith Stanley (additional)
Vladimir K. Popov (additional)
Viktor N. Bagratashvili (additional)

References 22 Referenced 22

{'volume-title': 'Supercritical Fluid Extraction: Principle and Practice', 'year': '1986', 'author': 'McHugh M. A.', 'key': 'bibr1-0003702944028434'} / Supercritical Fluid Extraction: Principle and Practice by McHugh M. A. (1986)
10.1021/bk-1992-0488.ch010
10.1021/j100347a076
{'key': 'bibr4-0003702944028434', 'first-page': '201', 'volume-title': 'Supercritical Fluid Engineering Science, ACS Symposium Series 514', 'volume': '114', 'author': 'Brennecke J. F.', 'year': '1993'} / Supercritical Fluid Engineering Science, ACS Symposium Series 514 by Brennecke J. F. (1993)
(a) Poliakoff Infrared: M., Howdle S. M., Whalley J. M., Healy M. A., in Proceedings of the International Symposium on Supercritical Fluids, Perrut M. Ed. (Societe Frangaise de Chimie, Paris, France, 1988), p. 967.
10.1016/0896-8446(91)90042-5
10.1063/1.442650
10.1366/0003702904086344
10.1002/jrs.1250240710
{'key': 'bibr10-0003702944028434', 'first-page': '96', 'volume': '1055', 'author': 'Heiman D.', 'year': '1989', 'journal-title': 'SPIE'} / SPIE by Heiman D. (1989)
10.1063/1.96103
10.1366/0003702884427889
10.1063/1.1139366
{'key': 'bibr14-0003702944028434', 'first-page': '2', 'volume-title': 'Fresnius J. Anal. Chem.', 'volume': '338', 'author': 'Gantner E.', 'year': '1990'} / Fresnius J. Anal. Chem. by Gantner E. (1990)
10.1021/ac00189a010
10.1366/0003702924123520
McCormick R. M., Zagursky R. J., Anal. Chem. 63, 750 (1991); Supelchem U.K. Ltd., Information Note No. 2487A (Supelchem, Essex, U.K., 1992). (10.1021/ac00007a020)
10.1366/0003702864507657
10.1021/ja00168a027
{'volume-title': 'Ph.D. Thesis', 'year': '1989', 'author': 'Howdle S. M.', 'key': 'bibr20-0003702944028434'} / Ph.D. Thesis by Howdle S. M. (1989)
10.1063/1.1680252
10.1016/0009-2614(93)90084-E

Dates

Type	When
Created	15 years, 10 months ago (Oct. 14, 2009, 10:57 a.m.)
Deposited	5 months, 3 weeks ago (March 10, 2025, 4:01 p.m.)
Indexed	5 months, 3 weeks ago (March 11, 2025, 12:32 a.m.)
Issued	31 years, 7 months ago (Feb. 1, 1994)
Published	31 years, 7 months ago (Feb. 1, 1994)
Published Online	31 years, 7 months ago (Feb. 1, 1994)
Published Print	31 years, 7 months ago (Feb. 1, 1994)

Funders 0

None

BibTeX

@article{Howdle_1994, title={Can High-Pressure Raman Spectroscopy Be Simplified? A Microscale Optical-Fiber Capillary Cell for the Study of Supercritical Fluids}, volume={48}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702944028434}, DOI={10.1366/0003702944028434}, number={2}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Howdle, Steven M. and Stanley, Keith and Popov, Vladimir K. and Bagratashvili, Viktor N.}, year={1994}, month=feb, pages={214–218} }

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