DOI: 10.1366/0003702934334543. Comparison of Electron and Infrared Spectroscopy with Thermal Analysis to Study Molecular Weight Effects in PVC-PMMA Blends

Comparison of Electron and Infrared Spectroscopy with Thermal Analysis to Study Molecular Weight Effects in PVC-PMMA Blends

10.1366/0003702934334543

Crossref journal-article

SAGE Publications

Applied Spectroscopy (179)

Abstract

The effects of homopolymer molecular weight on the miscibility of PVC/PMMA solvent cast blends were studied. Two significantly different molecular weights were chosen for each of the homopolymers, and a series of blends was prepared from the four possible homopolymer-homopolymer combinations. Angle-dependent ESCA results suggest that the surfaces of the blends are enriched with PMMA. The extent of this enrichment is dependent on molecular weight, with the most enrichment seen in blends containing the lower-molecular-weight PMMA homopolymer. Differential scanning calorimetry (DSC) results are also presented.

Bibliography

Burkhardt, C. A., & Gardella, J. A. (1993). Comparison of Electron and Infrared Spectroscopy with Thermal Analysis to Study Molecular Weight Effects in PVC-PMMA Blends. Applied Spectroscopy, 47(10), 1636â1642.

Authors 2

Cindy A. Burkhardt (first)
Joseph A. Gardella (additional)

References 33 Referenced 7

{'volume-title': 'Polymer Blends', 'year': '1978', 'author': 'Krause S.', 'key': 'bibr1-0003702934334543'} / Polymer Blends by Krause S. (1978)
{'volume-title': 'Polymer-Polymer Miscibility', 'year': '1979', 'author': 'Olabisi O.', 'key': 'bibr2-0003702934334543'} / Polymer-Polymer Miscibility by Olabisi O. (1979)
Sheldon R. P., in Composite Polymeric Materials (Elsevier, New York, 1982), p. 145.
10.1002/pen.760282104
10.1002/pol.1982.180200203
10.1021/ma00028a034
Robeson L. M., in Polymer Compatibility and Incompatibility, Solc K. Ed. (Harwood Academic, New York, 1981), p. 179.
10.1016/0032-3861(75)90054-3
10.1016/0032-3861(82)90342-1
{'key': 'bibr10-0003702934334543', 'first-page': '290', 'volume': '24', 'author': 'Jager H.', 'year': '1983', 'journal-title': 'Polym. Commun.'} / Polym. Commun. by Jager H. (1983)
{'issue': '1', 'key': 'bibr11-0003702934334543', 'first-page': '476', 'volume': '29', 'author': 'Parmer J. F.', 'year': '1988', 'journal-title': 'Polym. Prepr.'} / Polym. Prepr. by Parmer J. F. (1988)
10.1021/ma00206a045
10.1021/ma00205a004
Clark D. T., in Handbook of X-ray and Ultraviolet Photoelectron Spectroscopy, Briggs D. Ed. (Heydon and Son Ltd., London, 1977), pp. 211–247.
10.1016/0169-4332(88)90025-6
10.1007/978-1-4684-8610-0
10.1103/PhysRevLett.62.280
10.1007/978-1-4684-8610-0_7
10.1021/ma50006a033
10.1021/ma00157a028
10.1021/ma00185a049
10.1002/pola.1989.080270413
10.1021/ma00202a020
10.1021/ma00003a024
10.1021/ma00202a019
{'key': 'bibr26-0003702934334543', 'first-page': '252', 'volume': '26', 'author': 'Busscher H. J.', 'year': '1985', 'journal-title': 'Polym. Commun.'} / Polym. Commun. by Busscher H. J. (1985)
10.1021/ma60009a005
10.1002/pol.1982.130201003
10.1007/978-1-4613-9987-2_49
10.1016/0368-2048(82)85028-7
10.1021/ma00193a014
{'key': 'bibr32-0003702934334543', 'first-page': '151', 'volume': '27', 'author': 'Nandi A. K.', 'year': '1986', 'journal-title': 'Polym. Commun.'} / Polym. Commun. by Nandi A. K. (1986)
10.1016/0021-9797(69)90322-1

Dates

Type	When
Created	20 years, 1 month ago (July 3, 2005, 9:49 p.m.)
Deposited	5 months, 3 weeks ago (March 10, 2025, 6:28 p.m.)
Indexed	5 months, 3 weeks ago (March 10, 2025, 7:40 p.m.)
Issued	31 years, 11 months ago (Oct. 1, 1993)
Published	31 years, 11 months ago (Oct. 1, 1993)
Published Online	31 years, 11 months ago (Oct. 1, 1993)
Published Print	31 years, 11 months ago (Oct. 1, 1993)

Funders 0

None

BibTeX

@article{Burkhardt_1993, title={Comparison of Electron and Infrared Spectroscopy with Thermal Analysis to Study Molecular Weight Effects in PVC-PMMA Blends}, volume={47}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702934334543}, DOI={10.1366/0003702934334543}, number={10}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Burkhardt, Cindy A. and Gardella, Joseph A.}, year={1993}, month=oct, pages={1636–1642} }

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