DOI: 10.1366/0003702884429247. Reaction of Nitrogen Oxides with Black Carbon: An FT-IR Study

Reaction of Nitrogen Oxides with Black Carbon: An FT-IR Study

10.1366/0003702884429247

Crossref journal-article

SAGE Publications

Applied Spectroscopy (179)

Abstract

Qualitative and quantitative studies of the reaction of black carbon with the oxides of nitrogen, including NO, NO2/N2O4, N2O, and N2O3, have been carried out with the use of Fourier transform infrared spectroscopy (FT-IR). The active reactant is shown to be NO2, whether it acts as a disproportionation product or as an impurity in the gas under study. FT-IR spectra of the surface species identify them as resulting from reaction of carbon with NO2. For paraffin candle soot which was exposed simultaneously to oxygen atoms, and nitric oxide at 298 K, the surface species also are due to NO2, formed by oxidative adsorption of NO on the soot surface.

Bibliography

Smith, D. M., Welch, W. F., Graham, S. M., Chughtai, A. R., Wicke, B. G., & Grady, K. A. (1988). Reaction of Nitrogen Oxides with Black Carbon: An FT-IR Study. Applied Spectroscopy, 42(4), 674â680.

Authors 6

D. M. Smith (first)
W. F. Welch (additional)
S. M. Graham (additional)
A. R. Chughtai (additional)
Brian G. Wicke (additional)
Karen A. Grady (additional)

References 16 Referenced 33

10.1021/es00146a017
{'key': 'bibr2-0003702884429247', 'first-page': '184', 'volume': '289', 'author': 'Keifer J. R.', 'year': '1981', 'journal-title': 'SPIE'} / SPIE by Keifer J. R. (1981)
10.1366/0003702854249114
10.1366/0003702854249204
10.1021/j150666a046
10.1016/0008-6223(85)90096-X
10.1016/0008-6223(85)90097-1
10.1366/0003702864815385
10.1366/0003702874448805
10.1016/0010-2180(86)90031-3
10.1016/0010-2180(87)90030-7
Wicke B. G. and Grady K. A., Carbon, 26; accepted for publication (1987). (10.1111/j.2044-8309.1987.tb00788.x)
Cotton F. A. and Wilkinson G., Advanced Inorganic Chemistry (Interscience Publishers, John Wiley and Sons, New York, 1972), 3rd ed., p. 355; Herzberg G., Infrared and Raman Spectra of Polyatomic Molecules (D. Van Nostrand Co., Princeton, New Jersey, 1968).
10.1098/rspa.1958.0173
10.1063/1.438878
10.1063/1.448185

Dates

Type	When
Created	20 years, 1 month ago (July 13, 2005, 1:43 a.m.)
Deposited	5 months, 2 weeks ago (March 10, 2025, 11:16 p.m.)
Indexed	2 months ago (June 27, 2025, 9:45 a.m.)
Issued	37 years, 3 months ago (May 1, 1988)
Published	37 years, 3 months ago (May 1, 1988)
Published Online	37 years, 3 months ago (May 1, 1988)
Published Print	37 years, 3 months ago (May 1, 1988)

Funders 0

None

BibTeX

@article{Smith_1988, title={Reaction of Nitrogen Oxides with Black Carbon: An FT-IR Study}, volume={42}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702884429247}, DOI={10.1366/0003702884429247}, number={4}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Smith, D. M. and Welch, W. F. and Graham, S. M. and Chughtai, A. R. and Wicke, Brian G. and Grady, Karen A.}, year={1988}, month=may, pages={674–680} }

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