DOI: 10.1366/0003702854249204. The Structure of Hexane Soot II: Extraction Studies

The Structure of Hexane Soot II: Extraction Studies

10.1366/0003702854249204

Crossref journal-article

SAGE Publications

Applied Spectroscopy (179)

Abstract

Successive extraction of soluble components of hexane soot with a suite of solvents has been followed by CGC/MS, FT-IR, UV/Vis, fluorescence, and NMR spectroscopic analysis of these extracts. From these studies, additional understanding of the structure and reactivity of this material has emerged. A significant portion of the soot is extractable as polynuclear aromatic and aliphatic compounds, while the nonextractable solid structure, with both aromatic and aliphatic portions, contains such carbon-oxygen functionalities as acid anhydride, carbonyl, and ether linkages. A model of hexane soot as formed in flame is proposed on the basis of this work.

Bibliography

Akhter, M. S., Chughtai, A. R., & Smith, D. M. (1985). The Structure of Hexane Soot II: Extraction Studies. Applied Spectroscopy, 39(1), 154â167.

Authors 3

M. S. Akhter (first)
A. R. Chughtai (additional)
D. M. Smith (additional)

References 70 Referenced 62

10.1366/0003702854249114
{'key': 'bibr2-0003702854249204', 'first-page': '30', 'volume': '12', 'author': 'Falk H. L.', 'year': '1952', 'journal-title': 'Cancer Res.'} / Cancer Res. by Falk H. L. (1952)
10.1021/ac50007a020
10.1021/es60100a002
10.1080/0002889758507234
10.1080/00039896.1962.10663219
{'key': 'bibr7-0003702854249204', 'first-page': '40', 'volume': '12', 'author': 'Falk H. L.', 'year': '1952', 'journal-title': 'Cancer Res.'} / Cancer Res. by Falk H. L. (1952)
{'key': 'bibr8-0003702854249204', 'first-page': '103', 'volume': '14', 'author': 'Steiner P. E.', 'year': '1954', 'journal-title': 'Cancer Res.'} / Cancer Res. by Steiner P. E. (1954)
10.1021/es60011a003
Lee F. S. C., Prater T. J., and Ferris F., in Polynuclear Aromatic Hydrocarbons, Jones P. W. and Leber P., Eds. (Ann Arbor Science, Ann Arbor, 1979), p. 83.
10.1007/978-1-4757-6137-5_4
10.1021/ac60361a039
10.1021/ac60358a002
10.1021/es60151a008
10.1021/ac50036a043
10.1016/S0021-9673(01)98903-4
Clar E., Polycyclic Hydrocarbons (Academic Press, London, 1964), Vol. 1, p. 267; Vol. 2, pp. 58, 64, 129, 238.
{'volume-title': 'Ultraviolet Spectra of Aromatic Compounds', 'year': '1951', 'author': 'Friedel R. A.', 'key': 'bibr18-0003702854249204'} / Ultraviolet Spectra of Aromatic Compounds by Friedel R. A. (1951)
{'volume-title': 'Handbook of Ultraviolet and Visible Absorption Spectra of Organic Compounds', 'year': '1967', 'author': 'Hirayama K.', 'key': 'bibr19-0003702854249204'} / Handbook of Ultraviolet and Visible Absorption Spectra of Organic Compounds by Hirayama K. (1967)
10.1016/B978-0-12-440840-1.50012-6
10.1021/ac60348a036
10.1016/S0040-4020(01)98542-4
10.1021/ja00907a024
10.1016/S0040-4020(01)96950-9
10.1038/physci240018a0
10.1021/ac60321a033
{'volume-title': 'Handbook of Fluorescence Spectra of Aromatic Molecules', 'year': '1965', 'author': 'Berlman I. D.', 'key': 'bibr27-0003702854249204'} / Handbook of Fluorescence Spectra of Aromatic Molecules by Berlman I. D. (1965)
10.1021/ac60329a054
10.1021/ac50031a052
10.1021/ac50037a041
10.1016/0016-2361(78)90017-0
10.1098/rspa.1956.0152
10.1021/ja01561a017
10.1139/v63-136
10.1063/1.1732906
10.1021/ja01594a030
Rao C. N. R., Chemical Applications of IR Spectroscopy (Academic Press, New York, 1963), p. 182.
10.1016/0371-1951(51)80008-0
10.1021/ac50009a032
10.1093/chromsci/18.8.345
10.1016/S0021-9673(01)80450-7
10.1021/ac50042a043
10.1021/ac50005a037
10.1002/bms.1200040311
{'volume-title': 'Registry of Mass Spectra Data', 'year': '1974', 'author': 'Stenhagen E.', 'key': 'bibr45-0003702854249204'} / Registry of Mass Spectra Data by Stenhagen E. (1974)
{'key': 'bibr46-0003702854249204', 'volume-title': 'Compilation of Mass Spectra Data', 'volume': '1', 'author': 'Cornue A.', 'year': '1979'} / Compilation of Mass Spectra Data by Cornue A. (1979)
MSSS: Mass Spectral Search System (Data base), a component of the NIH-EPA chemical information system.
10.1093/chromsci/20.10.441
10.1093/chromsci/17.8.449
10.1021/es60172a016
10.1021/ac00236a028
10.1021/es60112a007
10.1021/es60014a001
10.1016/0004-6981(76)90045-7
10.1016/0004-6981(76)90025-1
10.1021/ac60358a002
10.1021/es00096a009
10.1021/ac00255a004
10.1021/ac50051a048
10.1016/0016-2361(80)90235-5
10.1021/jo01046a533
10.1021/ja01540a051
Clar E. and Zander M., J. Chem. Soc. 1861 (1958). (10.1039/jr9580001861)
10.1021/jo01031a017
10.1021/ja01238a052
Badger G. M., J. Chem. Soc. 4417 (1957). (10.1039/jr9570004417)
10.1021/ja01286a042
10.1021/ja01854a010
Clar E., Kelly W., and Wright J. W., J. Chem. Soc. 1108 (1954). (10.1039/jr9540001108)
10.1016/0040-4020(66)80056-X

Dates

Type	When
Created	20 years, 2 months ago (June 18, 2005, 11:24 a.m.)
Deposited	5 months, 3 weeks ago (March 10, 2025, 5:37 p.m.)
Indexed	2 months ago (June 30, 2025, 6:21 p.m.)
Issued	40 years, 8 months ago (Jan. 1, 1985)
Published	40 years, 8 months ago (Jan. 1, 1985)
Published Online	40 years, 8 months ago (Jan. 1, 1985)
Published Print	40 years, 8 months ago (Jan. 1, 1985)

Funders 0

None

BibTeX

@article{Akhter_1985, title={The Structure of Hexane Soot II: Extraction Studies}, volume={39}, ISSN={1943-3530}, url={http://dx.doi.org/10.1366/0003702854249204}, DOI={10.1366/0003702854249204}, number={1}, journal={Applied Spectroscopy}, publisher={SAGE Publications}, author={Akhter, M. S. and Chughtai, A. R. and Smith, D. M.}, year={1985}, month=jan, pages={154–167} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        6,
        30
      ]
    ],
    "date-time": "2025-06-30T22:21:35Z",
    "timestamp": 1751322095634,
    "version": "3.38.0"
  },
  "reference-count": 70,
  "publisher": "SAGE Publications",
  "issue": "1",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1985,
            1,
            1
          ]
        ],
        "date-time": "1985-01-01T00:00:00Z",
        "timestamp": 473385600000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://journals.sagepub.com/page/policies/text-and-data-mining-license"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1985,
        1
      ]
    ]
  },
  "abstract": "<jats:p> Successive extraction of soluble components of hexane soot with a suite of solvents has been followed by CGC/MS, FT-IR, UV/Vis, fluorescence, and NMR spectroscopic analysis of these extracts. From these studies, additional understanding of the structure and reactivity of this material has emerged. A significant portion of the soot is extractable as polynuclear aromatic and aliphatic compounds, while the nonextractable solid structure, with both aromatic and aliphatic portions, contains such carbon-oxygen functionalities as acid anhydride, carbonyl, and ether linkages. A model of hexane soot as formed in flame is proposed on the basis of this work. </jats:p>",
  "DOI": "10.1366/0003702854249204",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        6,
        18
      ]
    ],
    "date-time": "2005-06-18T15:24:05Z",
    "timestamp": 1119108245000
  },
  "page": "154-167",
  "source": "Crossref",
  "is-referenced-by-count": 62,
  "title": "The Structure of Hexane Soot II: Extraction Studies",
  "prefix": "10.1177",
  "volume": "39",
  "author": [
    {
      "given": "M. S.",
      "family": "Akhter",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Denver, Denver, Colorado 80208"
        }
      ]
    },
    {
      "given": "A. R.",
      "family": "Chughtai",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Denver, Denver, Colorado 80208"
        }
      ]
    },
    {
      "given": "D. M.",
      "family": "Smith",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Denver, Denver, Colorado 80208"
        }
      ]
    }
  ],
  "member": "179",
  "published-online": {
    "date-parts": [
      [
        1985,
        1,
        1
      ]
    ]
  },
  "reference": [
    {
      "key": "bibr1-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1366/0003702854249114"
    },
    {
      "key": "bibr2-0003702854249204",
      "first-page": "30",
      "volume": "12",
      "author": "Falk H. L.",
      "year": "1952",
      "journal-title": "Cancer Res."
    },
    {
      "key": "bibr3-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50007a020"
    },
    {
      "key": "bibr4-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60100a002"
    },
    {
      "key": "bibr5-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/0002889758507234"
    },
    {
      "key": "bibr6-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00039896.1962.10663219"
    },
    {
      "key": "bibr7-0003702854249204",
      "first-page": "40",
      "volume": "12",
      "author": "Falk H. L.",
      "year": "1952",
      "journal-title": "Cancer Res."
    },
    {
      "key": "bibr8-0003702854249204",
      "first-page": "103",
      "volume": "14",
      "author": "Steiner P. E.",
      "year": "1954",
      "journal-title": "Cancer Res."
    },
    {
      "key": "bibr9-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60011a003"
    },
    {
      "key": "bibr10-0003702854249204",
      "unstructured": "Lee F. S. C., Prater T. J., and Ferris F., in Polynuclear Aromatic Hydrocarbons, Jones P. W. and Leber P., Eds. (Ann Arbor Science, Ann Arbor, 1979), p. 83."
    },
    {
      "key": "bibr11-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-1-4757-6137-5_4"
    },
    {
      "key": "bibr12-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60361a039"
    },
    {
      "key": "bibr13-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60358a002"
    },
    {
      "key": "bibr14-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60151a008"
    },
    {
      "key": "bibr15-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50036a043"
    },
    {
      "key": "bibr16-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0021-9673(01)98903-4"
    },
    {
      "key": "bibr17-0003702854249204",
      "unstructured": "Clar E., Polycyclic Hydrocarbons (Academic Press, London, 1964), Vol. 1, p. 267; Vol. 2, pp. 58, 64, 129, 238."
    },
    {
      "volume-title": "Ultraviolet Spectra of Aromatic Compounds",
      "year": "1951",
      "author": "Friedel R. A.",
      "key": "bibr18-0003702854249204"
    },
    {
      "volume-title": "Handbook of Ultraviolet and Visible Absorption Spectra of Organic Compounds",
      "year": "1967",
      "author": "Hirayama K.",
      "key": "bibr19-0003702854249204"
    },
    {
      "key": "bibr20-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/B978-0-12-440840-1.50012-6"
    },
    {
      "key": "bibr21-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60348a036"
    },
    {
      "key": "bibr22-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0040-4020(01)98542-4"
    },
    {
      "key": "bibr23-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00907a024"
    },
    {
      "key": "bibr24-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0040-4020(01)96950-9"
    },
    {
      "key": "bibr25-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/physci240018a0"
    },
    {
      "key": "bibr26-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60321a033"
    },
    {
      "volume-title": "Handbook of Fluorescence Spectra of Aromatic Molecules",
      "year": "1965",
      "author": "Berlman I. D.",
      "key": "bibr27-0003702854249204"
    },
    {
      "key": "bibr28-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60329a054"
    },
    {
      "key": "bibr29-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50031a052"
    },
    {
      "key": "bibr30-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50037a041"
    },
    {
      "key": "bibr31-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0016-2361(78)90017-0"
    },
    {
      "key": "bibr32-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1098/rspa.1956.0152"
    },
    {
      "key": "bibr33-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01561a017"
    },
    {
      "key": "bibr34-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1139/v63-136"
    },
    {
      "key": "bibr35-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1732906"
    },
    {
      "key": "bibr36-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01594a030"
    },
    {
      "key": "bibr37-0003702854249204",
      "unstructured": "Rao C. N. R., Chemical Applications of IR Spectroscopy (Academic Press, New York, 1963), p. 182."
    },
    {
      "key": "bibr38-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0371-1951(51)80008-0"
    },
    {
      "key": "bibr39-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50009a032"
    },
    {
      "key": "bibr40-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1093/chromsci/18.8.345"
    },
    {
      "key": "bibr41-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0021-9673(01)80450-7"
    },
    {
      "key": "bibr42-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50042a043"
    },
    {
      "key": "bibr43-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50005a037"
    },
    {
      "key": "bibr44-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bms.1200040311"
    },
    {
      "volume-title": "Registry of Mass Spectra Data",
      "year": "1974",
      "author": "Stenhagen E.",
      "key": "bibr45-0003702854249204"
    },
    {
      "key": "bibr46-0003702854249204",
      "volume-title": "Compilation of Mass Spectra Data",
      "volume": "1",
      "author": "Cornue A.",
      "year": "1979"
    },
    {
      "key": "bibr47-0003702854249204",
      "unstructured": "MSSS: Mass Spectral Search System (Data base), a component of the NIH-EPA chemical information system."
    },
    {
      "key": "bibr48-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1093/chromsci/20.10.441"
    },
    {
      "key": "bibr49-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1093/chromsci/17.8.449"
    },
    {
      "key": "bibr50-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60172a016"
    },
    {
      "key": "bibr51-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac00236a028"
    },
    {
      "key": "bibr52-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60112a007"
    },
    {
      "key": "bibr53-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es60014a001"
    },
    {
      "key": "bibr54-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(76)90045-7"
    },
    {
      "key": "bibr55-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(76)90025-1"
    },
    {
      "key": "bibr56-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac60358a002"
    },
    {
      "key": "bibr57-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00096a009"
    },
    {
      "key": "bibr58-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac00255a004"
    },
    {
      "key": "bibr59-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ac50051a048"
    },
    {
      "key": "bibr60-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0016-2361(80)90235-5"
    },
    {
      "key": "bibr61-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo01046a533"
    },
    {
      "key": "bibr62-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01540a051"
    },
    {
      "key": "bibr63-0003702854249204",
      "doi-asserted-by": "crossref",
      "unstructured": "Clar E. and Zander M., J. Chem. Soc. 1861 (1958).",
      "DOI": "10.1039/jr9580001861"
    },
    {
      "key": "bibr64-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo01031a017"
    },
    {
      "key": "bibr65-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01238a052"
    },
    {
      "key": "bibr66-0003702854249204",
      "doi-asserted-by": "crossref",
      "unstructured": "Badger G. M., J. Chem. Soc. 4417 (1957).",
      "DOI": "10.1039/jr9570004417"
    },
    {
      "key": "bibr67-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01286a042"
    },
    {
      "key": "bibr68-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01854a010"
    },
    {
      "key": "bibr69-0003702854249204",
      "doi-asserted-by": "crossref",
      "unstructured": "Clar E., Kelly W., and Wright J. W., J. Chem. Soc. 1108 (1954).",
      "DOI": "10.1039/jr9540001108"
    },
    {
      "key": "bibr70-0003702854249204",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0040-4020(66)80056-X"
    }
  ],
  "container-title": "Applied Spectroscopy",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://journals.sagepub.com/doi/pdf/10.1366/0003702854249204",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://journals.sagepub.com/doi/pdf/10.1366/0003702854249204",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2025,
        3,
        10
      ]
    ],
    "date-time": "2025-03-10T21:37:36Z",
    "timestamp": 1741642656000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://journals.sagepub.com/doi/10.1366/0003702854249204"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1985,
        1
      ]
    ]
  },
  "references-count": 70,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1985,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1366/0003702854249204"
  ],
  "URL": "http://dx.doi.org/10.1366/0003702854249204",
  "relation": {},
  "ISSN": [
    "0003-7028",
    "1943-3530"
  ],
  "subject": [],
  "container-title-short": "Appl Spectrosc",
  "published": {
    "date-parts": [
      [
        1985,
        1
      ]
    ]
  }
}