DOI: 10.1351/pac200173020311. Copper complexes for catalytic, aerobic oxidation of hydrocarbons

Copper complexes for catalytic, aerobic oxidation of hydrocarbons

10.1351/pac200173020311

Crossref journal-article

Walter de Gruyter GmbH

Pure and Applied Chemistry (374)

Abstract

Abstract Catalytic oxidation of hydrocarbons can be performed efficiently upon treatment with tert-butylhydroperoxide or peracetic acid in the presence of a low-valent ruthenium catalyst. Furthermore, aerobic oxidation of hydrocarbons can be performed in the presence of acetaldehyde using ruthenium, iron, and copper catalysts. Copper derived from copper chloride/crown ether or copper chloride/crown ether/alkaline metal salts have proved to be efficient catalysts. Further study revealed that specific copper complexes formed from copper salts and acetonitrile are convenient and highly useful catalysts for the aerobic oxidation of unactivated hydrocarbons.

Bibliography

Murahashi, S.-I., Komiya, N., Hayashi, Y., & Kumano, T. (2001). Copper complexes for catalytic, aerobic oxidation of hydrocarbons. Pure and Applied Chemistry, 73(2), 311â314.

Authors 4

Shun-Ichi Murahashi (first)
Naruyoshi Komiya (additional)
Yukiko Hayashi (additional)
Tatsuyuki Kumano (additional)

References 0 Referenced 40

None

Dates

Type	When
Created	17 years, 10 months ago (Oct. 14, 2007, 11:16 a.m.)
Deposited	3 years, 6 months ago (March 5, 2022, 1:54 p.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 6:02 p.m.)
Issued	24 years, 8 months ago (Jan. 1, 2001)
Published	24 years, 8 months ago (Jan. 1, 2001)
Published Online	16 years, 8 months ago (Jan. 1, 2009)
Published Print	24 years, 8 months ago (Jan. 1, 2001)

Funders 0

None

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