DOI: 10.1346/ccmn.1992.0400611. Vibrational Probe Studies of Water Interactions with Montmorillonite

Vibrational Probe Studies of Water Interactions with Montmorillonite

10.1346/ccmn.1992.0400611

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractInteraction of water with montmorillonite exchanged with Na+, K+, Co2+, and Cu2+ cations as a function of water content was examined using an FTIR/gravimetric cell designed to collect spectroscopic and sorption data simultaneously. Correlation of water desorption isotherms with infrared spectra of the clay-water complex showed that the position of the HOH bending band of water decreased as a function of water content. The largest decreases in frequency were observed for Cu2+ and Co2+; smaller decreases were found for Na+ and K+. In addition, the molar absorptivity of sorbed water increased upon decreasing the water content. The decrease in frequency and the concomitant increase in molar absorptivity were attributed to polarization effects on the sorbed water molecules by exchangeable cations. The interference fringes of a self supporting clay film permitted d-spacings to be determined optically and, therefore, changes in frequency, molar absorptivity, and water sorption behavior to be related directly to changes in interlayer spacing. The d-spacings obtained from the interference fringes were consistently larger by approximately 0.5 Å than those determined using powder XRD.

Bibliography

Johnston, C. T., Sposito, G., & Erickson, C. (1992). Vibrational Probe Studies of Water Interactions with Montmorillonite. Clays and Clay Minerals, 40(6), 722â730.

Authors 3

C. T. Johnston (first)
G. Sposito (additional)
C. Erickson (additional)

References 38 Referenced 113

10.1346/CCMN.1989.0370105
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10.1346/CCMN.1968.0160508
10.1021/j100156a065
10.1021/j100349a034
{'volume-title': 'Instrumental Surface Analysis of Geologic Materials', 'year': '1990', 'author': 'Johnston', 'key': 'S0009860400018917_CR13'} / Instrumental Surface Analysis of Geologic Materials by Johnston (1990)
10.1021/la00050a015
10.1016/0021-9797(83)90071-1
10.1346/CCMN.1989.0370409
10.1021/ja01126a002
10.1021/j100621a010
10.1021/ja00217a008
{'key': 'S0009860400018917_CR22', 'first-page': '1', 'article-title': 'Beitrage zur frage des wasserhaltes der minerale kaolinit, halloysit und montmorillonit', 'volume': '11', 'author': 'Mehmel', 'year': '1937', 'journal-title': 'Chem. Erde.'} / Chem. Erde. / Beitrage zur frage des wasserhaltes der minerale kaolinit, halloysit und montmorillonit by Mehmel (1937)
10.2136/sssaj1974.03615995003800030014x
{'volume-title': 'Chemistry of Soil Constituents', 'year': '1978', 'author': 'Farmer', 'key': 'S0009860400018917_CR7'} / Chemistry of Soil Constituents by Farmer (1978)
{'volume-title': 'Fourier Transform Infrared Spectrometry', 'year': '1986', 'author': 'Griffiths', 'key': 'S0009860400018917_CR11'} / Fourier Transform Infrared Spectrometry by Griffiths (1986)
10.1346/CCMN.1974.0220108
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{'key': 'S0009860400018917_CR38', 'first-page': '970', 'article-title': 'Variations in interlayer cation sites of clay minerals as studied by 133Cs MAS nuclear magnetic resonance spectroscopy', 'volume': '75', 'author': 'Weiss', 'year': '1990', 'journal-title': 'Amer. Miner.'} / Amer. Miner. / Variations in interlayer cation sites of clay minerals as studied by 133Cs MAS nuclear magnetic resonance spectroscopy by Weiss (1990)
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10.1346/CCMN.1982.0300306
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{'volume-title': 'Data Handbook for Clay Materials and Other Non-metallic Minerals', 'year': '1979', 'author': 'Van Olphen', 'key': 'S0009860400018917_CR35'} / Data Handbook for Clay Materials and Other Non-metallic Minerals by Van Olphen (1979)
10.1002/chin.199204011
{'volume-title': 'Geochemical Processes at Mineral Surfaces. ACS Symposium Series, Vol. 323', 'year': '1986', 'author': 'Voudrias', 'key': 'S0009860400018917_CR36'} / Geochemical Processes at Mineral Surfaces. ACS Symposium Series, Vol. 323 by Voudrias (1986)
{'key': 'S0009860400018917_CR10', 'first-page': '128', 'article-title': 'Multinuclear and pulsed gradient magnetic resonance studies of Na cations and of water reorientation at the interface of a clay', 'volume': '83', 'author': 'Grandjean', 'year': '1989', 'journal-title': 'J. Mag. Res.'} / J. Mag. Res. / Multinuclear and pulsed gradient magnetic resonance studies of Na cations and of water reorientation at the interface of a clay by Grandjean (1989)
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10.1180/claymin.1964.005.32.04

Dates

Type	When
Created	19 years ago (Aug. 25, 2006, 3:44 a.m.)
Deposited	3 weeks, 4 days ago (Aug. 13, 2025, 1:25 a.m.)
Indexed	3 weeks, 2 days ago (Aug. 14, 2025, 10:31 p.m.)
Issued	32 years, 9 months ago (Dec. 1, 1992)
Published	32 years, 9 months ago (Dec. 1, 1992)
Published Online	1 year, 6 months ago (Feb. 28, 2024)
Published Print	32 years, 9 months ago (Dec. 1, 1992)

Funders 0

None

BibTeX

@article{Johnston_1992, title={Vibrational Probe Studies of Water Interactions with Montmorillonite}, volume={40}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1992.0400611}, DOI={10.1346/ccmn.1992.0400611}, number={6}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Johnston, C. T. and Sposito, G. and Erickson, C.}, year={1992}, month=dec, pages={722–730} }

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