DOI: 10.1346/ccmn.1981.0290502. Kinetic Model of Zeolite Paragenesis in Tuffaceous Sediments

Kinetic Model of Zeolite Paragenesis in Tuffaceous Sediments

10.1346/ccmn.1981.0290502

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractThe sequence of mineral reactions involving zeolites and other authigenic phases in tuffaceous sedimentary rocks can be explained by growth- and dissolution-reaction kinetics. Kinetic factors may determine the specific authigenic phases which form and the temporal and spatial constraints on the solution composition during irreversible dissolution and growth reactions in glass-bearing rocks. The glass phase generates a high level of supersaturation with respect to a variety of aluminosilicates in the pore fluid. The sequence of assemblages formed during a series of metastable reactions resembles an Ostwald step sequence. Metastable reactions occur because formation of less stable phases such as gels, clays, and disordered zeolites may lower the total free energy of the glass-bearing system faster than the growth of the stable assemblage including ordered feldspars, quartz, and micas. Eventually, after a series of steps, the most stable silicate assemblage for the bulk composition, temperature, and pressure may form. However, the formation of intermediate metastable phases can delay the attainment of equilibrium by as much as tens of millions of years.

Bibliography

Dibble, W. E., & Tiller, W. A. (1981). Kinetic Model of Zeolite Paragenesis in Tuffaceous Sediments. Clays and Clay Minerals, 29(5), 323â330.

Authors 2

W. E. Dibble (first)
W. A. Tiller (additional)

References 22 Referenced 70

10.1180/claymin.1972.009.3.05
{'key': 'S0009860400009563_CR21', 'first-page': '145', 'volume-title': 'Natural Zeolites: Occurrence, Properties, Use', 'author': 'Surdam', 'year': '1978'} / Natural Zeolites: Occurrence, Properties, Use by Surdam (1978)
10.1515/9781501508585-007
{'key': 'S0009860400009563_CR6', 'first-page': '31', 'volume-title': 'Natural Zeolites: Occurrence, Properties, Use', 'author': 'Gottardi', 'year': '1978'} / Natural Zeolites: Occurrence, Properties, Use by Gottardi (1978)
10.1130/0016-7606(1972)83[689:AAMITT]2.0.CO;2
{'key': 'S0009860400009563_CR15', 'first-page': '57', 'article-title': 'Authigenic minerals of the Green River Formation', 'volume': '10', 'author': 'Milton', 'year': '1971', 'journal-title': 'Univ. Wyo. Contrib. Geol.'} / Univ. Wyo. Contrib. Geol. / Authigenic minerals of the Green River Formation by Milton (1971)
10.1346/CCMN.1979.0270408
Guillemette, R. N. Liou, J. G. and Dickson, F. W. , (1980) The effect of glassy vs. crystalline starting materials on andesite-water interactions Proc. 3rd Int. Symp. Water-Rock Interaction 168–169.
10.1130/SPE85-p1
10.2475/ajs.279.4.435
10.1016/0016-7037(81)90265-9
10.1126/science.170.3961.977
10.1515/9781501508585-009 / Mineralogy and Geology of Natural Zeolites / Zeolites in open hydrologic systems by Hay (1977)
10.3133/pp830
{'key': 'S0009860400009563_CR5', 'first-page': '53', 'article-title': 'Kinetics of metamorphic reactions', 'volume': '73', 'author': 'Fyfe', 'year': '1958', 'journal-title': 'Metamorphic Reactions and Metamorphic Facies'} / Metamorphic Reactions and Metamorphic Facies / Kinetics of metamorphic reactions by Fyfe (1958)
Potter, J. , (1981) Experimental rock-water interactions at temperatures to 300°C: Implications for fluid flow, solute transport, and silicate mineral zoning in crustal geothermal systems .
10.1515/9780691209401
10.1346/CCMN.1977.0250308
10.1126/science.161.3837.160 / Science / Gels composed of sodium-aluminum silicate, Lake Magadi, Kenya by Eugster (1968)
Mariner, R. H. , (1971) Experimental evaluation of authigenic mineral reactions in the Pliocene Moonstone Formation .
Sheppard, R. A. and Gude, A. J. , (1969) Diagenesis of tuffs in the Barstow Formation, Mud Hills, San Bernardino County, California U.S. Geol. Surv. Prof. Pap. . (10.3133/pp634)
Sheppard, R. A. and Gude, A. J. , (1968) Distribution and genesis of authigenic silicate minerals in tuffs of Pleistocene Lake Tecopa, Inyo County, California U.S. Geol. Surv. Prof. Pap. . (10.3133/pp597)

Dates

Type	When
Created	19 years ago (Aug. 25, 2006, 3:35 a.m.)
Deposited	3 weeks, 2 days ago (Aug. 5, 2025, 5:32 a.m.)
Indexed	2 weeks ago (Aug. 14, 2025, 8:20 p.m.)
Issued	43 years, 10 months ago (Oct. 1, 1981)
Published	43 years, 10 months ago (Oct. 1, 1981)
Published Online	1 year, 1 month ago (July 1, 2024)
Published Print	43 years, 10 months ago (Oct. 1, 1981)

Funders 0

None

BibTeX

@article{Dibble_1981, title={Kinetic Model of Zeolite Paragenesis in Tuffaceous Sediments}, volume={29}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1981.0290502}, DOI={10.1346/ccmn.1981.0290502}, number={5}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Dibble, W. E. and Tiller, W. A.}, year={1981}, month=oct, pages={323–330} }

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