DOI: 10.1346/ccmn.1978.0260601. The Influence of Aluminum on Iron Oxides. Part I. The Influence of Al on Fe Oxide Formation from the Fe(II) System

The Influence of Aluminum on Iron Oxides. Part I. The Influence of Al on Fe Oxide Formation from the Fe(II) System

10.1346/ccmn.1978.0260601

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractThe influence of Al on the products formed by aerial oxidation at pH 5.5-7 and 20°C of Fe(II) chloride, sulfate and carbonate solutions, was examined. In all cases Al at levels Al/Al + Fe = 0.09−0.30 inhibited the formation of y phases (lepidocrocite and maghemite) in favor of goethite under conditions where, in the absence of Al, these y phases formed. The influence of Al in these laboratory studies was supported by field observations.At higher levels of Al, ferrihydrite formation was favored. This effect of Al was seen to be the result of a slowing down in the hydrolysis/oxidation rate of the Fe(II) system.The presence of Al not only changed the direction of mineral formation, but also caused the formation of Al substitued goethites which resembled in particle size and morphology the natural aluminiferous goethite extracted from a soil.

Bibliography

Taylor, R. M., & Schwertmann, U. (1978). The Influence of Aluminum on Iron Oxides. Part I. The Influence of Al on Fe Oxide Formation from the Fe(II) System. Clays and Clay Minerals, 26(6), 373â383.

Authors 2

R. M. Taylor (first)
U. Schwertmann (additional)

References 19 Referenced 98

10.1180/claymin.1976.011.3.02
10.1002/zaac.19633260313
10.1002/zaac.19502620110
{'key': 'S0009860400004183_bib15', 'first-page': '145', 'volume-title': 'Minerals in the Soil Environment', 'author': 'Schwertmann', 'year': '1977'} / Minerals in the Soil Environment by Schwertmann (1977)
10.1002/zaac.19592980511
10.1111/j.1365-2389.1961.tb00919.x
{'key': 'S0009860400004183_bib13', 'first-page': '645', 'article-title': 'The influence of organic compounds on the formation of iron oxides', 'volume': '1', 'author': 'Schwertmann', 'year': '1968', 'journal-title': 'Trans. 9th Int. Congr. Soil Sci.'} / Trans. 9th Int. Congr. Soil Sci. / The influence of organic compounds on the formation of iron oxides by Schwertmann (1968)
10.1180/claymin.1959.004.21.02
10.1346/CCMN.1975.0230105
10.1002/zaac.19754120212
{'key': 'S0009860400004183_bib2', 'first-page': '131', 'article-title': 'Röntgenographische Untersuchungen über den Mineralbestand sedimentärer Eisenerze', 'volume': '2', 'author': 'Correns', 'year': '1942', 'journal-title': 'Nachr. Ges. Wiss. Göttingen Math. Phys. Kl. Heft'} / Nachr. Ges. Wiss. Göttingen Math. Phys. Kl. Heft / Röntgenographische Untersuchungen über den Mineralbestand sedimentärer Eisenerze by Correns (1942)
10.1180/claymin.1974.010.4.07
10.1002/zaac.19703780210
Stauffer, T. E. and Lovell, H. L. (1968) The oxygenation of Fe(II)-relationship to coal mine drainage treatment: Coal Res. Board, Com. of Pennsylvania, Special Research Report SR-69.
{'key': 'S0009860400004183_bib11', 'first-page': '104', 'article-title': 'Experimentelle Untersuchungen über die sedimentäre Bildung von Goethit und Hämatit', 'volume': '20', 'author': 'Schellmann', 'year': '1959', 'journal-title': 'Chem. Erde'} / Chem. Erde / Experimentelle Untersuchungen über die sedimentäre Bildung von Goethit und Hämatit by Schellmann (1959)
10.1002/zaac.19723910111
10.1180/claymin.1974.010.4.08
10.2136/sssaj1977.03615995004100050042x
10.1180/claymin.1967.007.2.10

Dates

Type	When
Created	19 years ago (Aug. 25, 2006, 3:34 a.m.)
Deposited	3 weeks, 1 day ago (Aug. 4, 2025, 7:32 a.m.)
Indexed	1 week, 4 days ago (Aug. 14, 2025, 8:07 p.m.)
Issued	46 years, 8 months ago (Dec. 1, 1978)
Published	46 years, 8 months ago (Dec. 1, 1978)
Published Online	1 year, 1 month ago (July 1, 2024)
Published Print	46 years, 8 months ago (Dec. 1, 1978)

Funders 0

None

BibTeX

@article{Taylor_1978, title={The Influence of Aluminum on Iron Oxides. Part I. The Influence of Al on Fe Oxide Formation from the Fe(II) System}, volume={26}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1978.0260601}, DOI={10.1346/ccmn.1978.0260601}, number={6}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Taylor, R. M. and Schwertmann, U.}, year={1978}, month=dec, pages={373–383} }

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