DOI: 10.1346/ccmn.1977.0250608. Qualitative and Quantitative Study of Stacking Faults in a Hydrazine Treated Kaolinite

Qualitative and Quantitative Study of Stacking Faults in a Hydrazine Treated Kaolinite—Relationship with the Infrared Spectra

10.1346/ccmn.1977.0250608

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractArtificial stacking faults can be created within a well-crystallized kaolinite by intercalating and removing hydrazine. X-ray powder patterns with electron microscopy show that the created defects are ±b/3 translations with a proportion 0.30. The infrared spectrum of the treated kaolinite is not modified with respect to the starting one. On the other hand, a natural kaolinite containing defects by displacement of Al vacancies in a similar proportion shows an infrared spectrum significantly different from that of a well-crystallized kaolinite. The modification of the infrared spectra of natural disordered kaolinites is then related to the presence of defects by change of Al vacancy positions

Bibliography

Barrios, J., PlanÃ§on, A., Cruz, M. I., & Tchoubar, C. (1977). Qualitative and Quantitative Study of Stacking Faults in a Hydrazine Treated KaoliniteâRelationship with the Infrared Spectra. Clays and Clay Minerals, 25(6), 422â429.

Authors 4

J. Barrios (first)
A. Plançon (additional)
M. I. Cruz (additional)
C. Tchoubar (additional)

References 28 Referenced 56

10.1180/claymin.1969.008.2.02
10.1126/science.145.3637.1189
Cruz, M. I. , Jacobs, H. and Fripiat, J. J. (1972) The nature of the interlayer bonding in kaolin minerals: Proc. Int. Clay Conf., Madrid, pp. 35–46.
10.1107/S0021889875011429
Samudacheata, N. (1975) Etude des hydroxyles de la kaolinite par spectroscopie infrarouge: Thèse, Université de Louvain.
10.1346/CCMN.1977.0250609
{'key': 'S0009860400003542_bib3', 'first-page': '59', 'article-title': 'Caractérisation des minéraux kaolinitiques par diverses techniques', 'volume': '3', 'author': 'de Kimpe', 'year': '1966', 'journal-title': 'Bull. Gr. Fr. Arg.'} / Bull. Gr. Fr. Arg. / Caractérisation des minéraux kaolinitiques par diverses techniques by de Kimpe (1966)
10.1107/S0021889876011369
{'key': 'S0009860400003542_bib8', 'first-page': '471', 'article-title': 'Hydroxyl orientation in kaolinite, dickite and nacrite', 'volume': '58', 'author': 'Giese', 'year': '1973', 'journal-title': 'Am. Miner.'} / Am. Miner. / Hydroxyl orientation in kaolinite, dickite and nacrite by Giese (1973)
10.1016/0371-1951(64)80165-X
{'key': 'S0009860400003542_bib13', 'first-page': '31', 'article-title': 'Correlation of paper-coating quality with degree of crystal perfection of kaolinite', 'volume': '4', 'author': 'Murray', 'year': '1956', 'journal-title': 'Clays and Clay Minerals'} / Clays and Clay Minerals / Correlation of paper-coating quality with degree of crystal perfection of kaolinite by Murray (1956)
{'volume-title': 'Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures', 'year': '1976', 'author': 'van der Marel', 'key': 'S0009860400003542_bib22'} / Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures by van der Marel (1976)
Jacobs, H. and Stercks, M. (1970) Contribution à l'étude de l'intercalation du dimethylsulfoxyde dans le réseau de la kaolinite: Proc. Reunion Hispano-Belge Miner. Arg., Madrid.
Mata-Arjona, A. , Ruiz-Amil, A. and Inara-Martin, E. (1970) Cinetica del proceso de sorcion del dimetilsulfoxido en caolinita: estudio por difraccion de rayos X: Proc. Reunion Hispano-Belge Miner. Arg., Madrid.
10.1180/mono-4
{'key': 'S0009860400003542_bib28', 'article-title': 'Electron diffraction determination of the structure of kaolinite', 'volume': '130', 'author': 'Zvyagin', 'year': '1960', 'journal-title': 'Dokl. Akad. Nauk S.S.S.R.'} / Dokl. Akad. Nauk S.S.S.R. / Electron diffraction determination of the structure of kaolinite by Zvyagin (1960)
{'key': 'S0009860400003542_bib7', 'first-page': '149', 'article-title': "Observation sur la notion d'ordre et de désordre de certains minéraux du groupe de la kaolinite", 'volume': '14', 'author': 'Fleurence', 'year': '1964', 'journal-title': 'Bull. Gr. Fr. Arg.'} / Bull. Gr. Fr. Arg. / Observation sur la notion d'ordre et de désordre de certains minéraux du groupe de la kaolinite by Fleurence (1964)
{'key': 'S0009860400003542_bib25', 'first-page': '157', 'article-title': 'Infrared studies of proton delocalization in kaolinite', 'volume': '22', 'author': 'White', 'year': '1970', 'journal-title': 'Bull. Gr. Fr. Arg.'} / Bull. Gr. Fr. Arg. / Infrared studies of proton delocalization in kaolinite by White (1970)
10.1346/CCMN.1977.0250610
10.1346/CCMN.1976.0240502
10.1007/BF00388013
10.1016/0095-8522(66)90029-8
{'key': 'S0009860400003542_bib1', 'first-page': '49', 'article-title': 'Randomness in the structures of kaolinitic clay minerals', 'volume': '46', 'author': 'Brindley', 'year': '1946', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. / Randomness in the structures of kaolinitic clay minerals by Brindley (1946)
{'key': 'S0009860400003542_bib24', 'first-page': '287', 'article-title': 'Kaolinit-Einlagerungs-Veirbindungen', 'volume': '1', 'author': 'Weiss', 'year': '1963', 'journal-title': 'Proc. Int. Clay Conf.'} / Proc. Int. Clay Conf. / Kaolinit-Einlagerungs-Veirbindungen by Weiss (1963)
Jacobs, H. (1971) Etude des hydroxyles de la kaolinite par spectroscopie infrarouge: Thèse, Université Catholique de Louvain.
{'key': 'S0009860400003542_bib27', 'first-page': '723', 'article-title': 'Potassium acetate intercalation in kaolinite and its removal; effect of material characteristics', 'volume': '1', 'author': 'Wiewiora', 'year': '1969', 'journal-title': 'Proc. Int. Clay. Conf.'} / Proc. Int. Clay. Conf. / Potassium acetate intercalation in kaolinite and its removal; effect of material characteristics by Wiewiora (1969)
Noel, C. (1972) Interprétation quantitative des bandes de valence OH des phyllosilicates et des amphiboles: Thèse, Université de Louvain.
{'key': 'S0009860400003542_bib14', 'first-page': '683', 'article-title': 'A refinement of the dickite structure and some remarks on polymorphism in kaolin minerals', 'volume': '32', 'author': 'Newnham', 'year': '1961', 'journal-title': 'Miner. Mag.'} / Miner. Mag. / A refinement of the dickite structure and some remarks on polymorphism in kaolin minerals by Newnham (1961)

Dates

Type	When
Created	19 years ago (Aug. 25, 2006, 3:33 a.m.)
Deposited	4 weeks, 1 day ago (Aug. 4, 2025, 7:32 a.m.)
Indexed	2 weeks, 5 days ago (Aug. 14, 2025, 8:07 p.m.)
Issued	47 years, 9 months ago (Dec. 1, 1977)
Published	47 years, 9 months ago (Dec. 1, 1977)
Published Online	1 year, 2 months ago (July 1, 2024)
Published Print	47 years, 9 months ago (Dec. 1, 1977)

Funders 0

None

BibTeX

@article{Barrios_1977, title={Qualitative and Quantitative Study of Stacking Faults in a Hydrazine Treated Kaolinite—Relationship with the Infrared Spectra}, volume={25}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1977.0250608}, DOI={10.1346/ccmn.1977.0250608}, number={6}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Barrios, J. and Plançon, A. and Cruz, M. I. and Tchoubar, C.}, year={1977}, month=dec, pages={422–429} }

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