DOI: 10.1346/ccmn.1977.0250310. Synthesis and Swelling Properties of Saponites with Increasing Layer Charge

Synthesis and Swelling Properties of Saponites with Increasing Layer Charge

10.1346/ccmn.1977.0250310

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractNine synthetic Na-saponites with charge densities varying between 0.33 and 1.0 have been prepared. Their swelling properties and structural organization in water, ethylene glycol and glycerol show discontinuities in the physico-chemical behaviour of these samples. The layer charge densities caused changes in swelling properties and structural organization of the minerals. These changes also depended upon the nature of the solvation liquid and the interlayer cation involved.Electron diffraction patterns of the Ba-saponites showed no abnormal diffusion making honeycomblike patterns between Bragg reflections.The results indicate criteria for estimating the layer charge of tetrahedrally substituted trioctahedral 2/1 phyllosilicates.There is no upper limit until x = 1 for the layer charge x which is specific to the smectite-group. Consequently, the changes in the swelling properties observed when x = 0.5-0.6 and x = 0.8-0.9 come from the modifications of the interlayer structure, which are mainly a function of cation-liquid and silicate layer-liquid interactions. Consequently, there is an overlap between the saponite and the vermi-culite mineral groups.

Bibliography

Suquet, H., Iiyama, J. T., Kodama, H., & Pezerat, H. (1977). Synthesis and Swelling Properties of Saponites with Increasing Layer Charge. Clays and Clay Minerals, 25(3), 231â242.

Authors 4

H. Suquet (first)
J. T. Iiyama (additional)
H. Kodama (additional)
H. Pezerat (additional)

References 29 Referenced 73

10.1097/00010694-195101000-00001
Besson, G. (1972) Etude par microdiffraction électronique des relations d'ordre–désordre dans les substitutions des phyllosilicates. Thèse 3e cycle, Orléans, France.
{'key': 'S0009860400003311_bib13', 'first-page': '833', 'article-title': 'Effet de chauffage sur les montmorillonites saturées de cations de petit rayon', 'volume': '275', 'author': 'Glaeser', 'year': '1967', 'journal-title': 'C.r. hebd. Séan. Acad. Sci., Paris'} / C.r. hebd. Séan. Acad. Sci., Paris / Effet de chauffage sur les montmorillonites saturées de cations de petit rayon by Glaeser (1967)
{'key': 'S0009860400003311_bib17', 'first-page': '7', 'article-title': 'Diffuse scattering by X-rays and electrons in mica and mica-like minerals', 'volume': '481', 'author': 'Kodama', 'year': '1975', 'journal-title': 'Clay Mineralogy'} / Clay Mineralogy / Diffuse scattering by X-rays and electrons in mica and mica-like minerals by Kodama (1975)
10.3406/argil.1975.1235
10.3406/argil.1972.1161
{'key': 'S0009860400003311_bib20', 'first-page': '1', 'article-title': 'Discussion à propos des critères de classification des phyllosilicates 2/1', 'volume': '21', 'author': 'Mering', 'year': '1967', 'journal-title': 'Bull. grpe fr. Argiles'} / Bull. grpe fr. Argiles / Discussion à propos des critères de classification des phyllosilicates 2/1 by Mering (1967)
10.1346/CCMN.1975.0230101
{'key': 'S0009860400003311_bib7', 'first-page': '117', 'article-title': 'A glycol sodium vermiculite complex', 'volume': '10', 'author': 'Bradley', 'year': '1963', 'journal-title': 'Clays and Clay Minerals'} / Clays and Clay Minerals / A glycol sodium vermiculite complex by Bradley (1963)
Alcover, J. F. , Gatineau, L. , Mering, J. and Kodama, H. (1974) The distribution of Ba cations in vermiculites and vermiculitized micas: Clays & Clay Minerals (in press).
Roy, R. (1961) The preparation and properties of synthetic clay minerals: Colloque International du C.N.R.S. sur la Genèse et Synthèse des Argiles, Paris, pp. 83–98.
{'key': 'S0009860400003311_bib9', 'first-page': '261', 'article-title': 'Synthetic sodium phlogopite and its two hydrates stabilities, properties and mineralogic implications', 'volume': '59', 'author': 'Carman', 'year': '1974', 'journal-title': 'Am. Miner.'} / Am. Miner. / Synthetic sodium phlogopite and its two hydrates stabilities, properties and mineralogic implications by Carman (1974)
{'key': 'S0009860400003311_bib22', 'first-page': '363', 'article-title': "Principes et détermination qualitative des minéraux argileux à l'aide des rayons X", 'volume': '26', 'author': 'Robert', 'year': '1975', 'journal-title': 'Ann. agron.'} / Ann. agron. / Principes et détermination qualitative des minéraux argileux à l'aide des rayons X by Robert (1975)
10.1097/00010694-195407000-00007
10.1346/CCMN.1974.0220503
10.1039/tf9484400349
{'key': 'S0009860400003311_bib28', 'first-page': '839', 'article-title': 'The effects and geologic significance of potassium “fixation” by expandable clay minerals derived from muscovite, biotite, chlorite and volcanic materials', 'volume': '43', 'author': 'Weaver', 'year': '1958', 'journal-title': 'Am. Miner.'} / Am. Miner. / The effects and geologic significance of potassium “fixation” by expandable clay minerals derived from muscovite, biotite, chlorite and volcanic materials by Weaver (1958)
{'key': 'S0009860400003311_bib2', 'first-page': '225', 'article-title': 'The effect of the interlayer cations in the expansion of the mica type of crystal lattice', 'volume': '35', 'author': 'Barshad', 'year': '1950', 'journal-title': 'Am. Miner.'} / Am. Miner. / The effect of the interlayer cations in the expansion of the mica type of crystal lattice by Barshad (1950)
Lagaly, G. and Weiss, A. (1969) Determination of the layer charge in mica type layer silicates. Proc. Int. Clay Conf., Tokyo, 61–80.
10.1130/0016-7606(1961)72[1455:CAASFT]2.0.CO;2
10.1180/claymin.1963.005.29.01
{'key': 'S0009860400003311_bib15', 'first-page': '209', 'article-title': 'Swelling properties of synthetic smectites in relation to lattice substitutions', 'volume': '6', 'author': 'Harward', 'year': '1965', 'journal-title': 'Clays and Clay Minerals'} / Clays and Clay Minerals / Swelling properties of synthetic smectites in relation to lattice substitutions by Harward (1965)
10.3406/argil.1973.1190 / Bull. grpe fr. Argiles / Relations d'ordre–désordre dans la répartition des substitutions des phyllosilicates 2/1 du groupe des smectites by Besson (1973)
Glaeser, R. and Mering, J. (1975) Influence du taux de substitution isomorphique en couche tétraédrique sur les propriétés et l'organisation structurale des smectites dioctaédriques: Proc. 20ème Congrès International des argiles, Mexico, pp. 173–183.
Brindley, G. W. and MacEwan, D. M. C. (1953) Structural mineralogy of ceramic clays. Symp. Brit. Ceramic Soc. Stoke on Trent, pp. 15–59.
Calle, C. de la Suquet, H. , Dubernat, J. and Pezerat, H. (1977) Evolution of the structure of two-layer hydrates of high-charge vermiculites with the relative humidity: communication at the European Clay Mineral Conf., Oslo.
10.1180/claymin.1958.003.20.05
Weir, A. H. (1960) Relationship between physical properties structure and composition of smectites: Thesis, London University.
{'key': 'S0009860400003311_bib21', 'first-page': '990', 'article-title': 'An X-ray study of an ethylene-glycol montmorillonite complex', 'volume': '50', 'author': 'Reynolds', 'year': '1965', 'journal-title': 'Am. Miner.'} / Am. Miner. / An X-ray study of an ethylene-glycol montmorillonite complex by Reynolds (1965)

Dates

Type	When
Created	19 years ago (Aug. 25, 2006, 3:32 a.m.)
Deposited	1 month ago (Aug. 4, 2025, 7:32 a.m.)
Indexed	1 day, 13 hours ago (Sept. 3, 2025, 6:23 a.m.)
Issued	48 years, 3 months ago (June 1, 1977)
Published	48 years, 3 months ago (June 1, 1977)
Published Online	1 year, 2 months ago (July 1, 2024)
Published Print	48 years, 3 months ago (June 1, 1977)

Funders 0

None

BibTeX

@article{Suquet_1977, title={Synthesis and Swelling Properties of Saponites with Increasing Layer Charge}, volume={25}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1977.0250310}, DOI={10.1346/ccmn.1977.0250310}, number={3}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Suquet, H. and Iiyama, J. T. and Kodama, H. and Pezerat, H.}, year={1977}, month=jun, pages={231–242} }

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