DOI: 10.1346/ccmn.1976.0240502. New Approach to the Problem of the Interlayer Bonding in Kaolinite

New Approach to the Problem of the Interlayer Bonding in Kaolinite

10.1346/ccmn.1976.0240502

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractThe possibility of recording the absorption band which is related to oscillations of free OH in a superficial plane of the octahedral sheet of kaolinite inspired the present authors to review the problem of cohesion forces in kaolinite. Structural and spectroscopic criteria as applied to kaolinite proved that the cohesion of adjacent kaolinite layers may be estimated in terms of bent hydrogen bonds. Energy calculations were performed with the aid of a Lennard-Jones function using a modified linear model of the hydrogen bonds. The entire energy is composed of four terms described by the general potential function, van der Waals repulsion and an electrostatic attraction. The energy values of the individual terms are within the limits characteristic of each of them.

Bibliography

WiÄckowski, T., & WiewiÃ³ra, A. (1976). New Approach to the Problem of the Interlayer Bonding in Kaolinite. Clays and Clay Minerals, 24(5), 219â223.

Authors 2

Tadeusz Więckowski (first)
Andrzej Wiewióra (additional)

References 22 Referenced 17

Kęcki, Z. (1975) Podstawy spektroskopii molekularnej. PWN, Warszawa.
{'key': 'S0009860400002792_bib21', 'first-page': '383', 'volume-title': 'Geologica', 'author': 'Wiewióra', 'year': '1974b'} / Geologica by Wiewióra (1974b)
{'key': 'S0009860400002792_bib19', 'first-page': '45', 'article-title': 'Discusiion on “The nature of the interlayer bonding in kaolin minerals by Cruz, Jacobs Fripiat”', 'volume': '1', 'author': 'Wiewióra', 'year': '1973', 'journal-title': 'Proc. 1972 Int. Clay Conf., Madrid'} / Proc. 1972 Int. Clay Conf., Madrid / Discusiion on “The nature of the interlayer bonding in kaolin minerals by Cruz, Jacobs Fripiat” by Wiewióra (1973)
10.1021/j150553a017
{'key': 'S0009860400002792_bib14', 'first-page': '7', 'volume-title': 'Ceramika', 'volume': '14', 'author': 'Pampuch', 'year': '1970'} / Ceramika by Pampuch (1970)
10.1063/1.1742196
{'key': 'S0009860400002792_bib13', 'first-page': '5', 'volume-title': 'Ceramika', 'volume': '3', 'author': 'Pampuch', 'year': '1964'} / Ceramika by Pampuch (1964)
Coulson, C. A. (1963) Wiazania chemiczne. PWN, Warszawa.
{'key': 'S0009860400002792_bib12', 'first-page': '177', 'volume-title': 'Correlation of spectroscopic and crystallographic data: Structure and bonding', 'author': 'Novak', 'year': '1974'} / Correlation of spectroscopic and crystallographic data: Structure and bonding by Novak (1974)
Cruz, M. , Jacobs, H. and Fripiat, J. (1963) The nature of the interlayer bonding in kaolin minerals: Proc. Int. Clay Conf. 1972, Madrid, 35–44.
Szczepaniak, K. (1969) Niektóre zagadmienia spektroskopii w podczerwieni słabych wiazań wodorowych: Wiazanie wodorowe, PWN, Warszawa.
Jacobs, H. (1971) Etude des hydroxyles de la kaolinite par spectroscopie i.r.: Université Catholique de Louvain. Dissertation presentée pour l'obtention du grade de Docteur en Sciences Agronomiques.
{'key': 'S0009860400002792_bib22', 'first-page': '723', 'article-title': 'Potassium acetate intercalation in kaolinite and its removal: effect of material characteristics', 'volume': '1', 'author': 'Wiewióra', 'year': '1969', 'journal-title': 'Proc. Int. Clay Conf. Tokyo'} / Proc. Int. Clay Conf. Tokyo / Potassium acetate intercalation in kaolinite and its removal: effect of material characteristics by Wiewióra (1969)
{'key': 'S0009860400002792_bib17', 'first-page': '17', 'volume-title': 'Int. Clay Conf.', 'author': 'Serratosa', 'year': '1963'} / Int. Clay Conf. by Serratosa (1963)
{'key': 'S0009860400002792_bib6', 'first-page': '471', 'article-title': 'Hydroxyl orientation in kaolinite, dickite and nacrite', 'volume': '58', 'author': 'Giese', 'year': '1963', 'journal-title': 'Am. Miner.'} / Am. Miner. / Hydroxyl orientation in kaolinite, dickite and nacrite by Giese (1963)
Plusnina, I. I. and Gribina, I. A. (1970) Infrakrasnye spektry kaolinite i montmorillonite v obłasti valentnykh i deformatyonnych kolebanii OH grupp i vody. Zb.: Svyazana voda v dyspersnykh systemakh Izdatelstvo Moskovskogo Universiteta, Moskva, 25–39.
10.1021/j150568a004
Ledoux, R. and White, J. (1964) I.r. studies of the hydroxyl groups in intercalated kaolinite complexes: Proc. 13th Nat. Conf. Madison Wisconsin, 289–315. (10.1346/CCMN.1964.0130128)
10.1016/0371-1951(64)80165-X
10.1126/science.145.3637.1189
10.1016/0584-8539(69)80027-9
{'key': 'S0009860400002792_bib20', 'first-page': '67', 'article-title': 'X-ray, i.r. and DTA studies of expanded kaolinite', 'volume': '5', 'author': 'Wiewióra', 'year': '1974a', 'journal-title': 'Mineralogia Polonica'} / Mineralogia Polonica / X-ray, i.r. and DTA studies of expanded kaolinite by Wiewióra (1974a)

Dates

Type	When
Created	19 years ago (Aug. 23, 2006, 3:31 a.m.)
Deposited	1 month ago (Aug. 4, 2025, 7:32 a.m.)
Indexed	3 weeks ago (Aug. 14, 2025, 8:08 p.m.)
Issued	48 years, 11 months ago (Oct. 1, 1976)
Published	48 years, 11 months ago (Oct. 1, 1976)
Published Online	1 year, 2 months ago (July 1, 2024)
Published Print	48 years, 11 months ago (Oct. 1, 1976)

Funders 0

None

BibTeX

@article{Wi_ckowski_1976, title={New Approach to the Problem of the Interlayer Bonding in Kaolinite}, volume={24}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1976.0240502}, DOI={10.1346/ccmn.1976.0240502}, number={5}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Więckowski, Tadeusz and Wiewióra, Andrzej}, year={1976}, month=oct, pages={219–223} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        15
      ]
    ],
    "date-time": "2025-08-15T00:08:05Z",
    "timestamp": 1755216485507,
    "version": "3.43.0"
  },
  "reference-count": 22,
  "publisher": "Cambridge University Press (CUP)",
  "issue": "5",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2024,
            7,
            1
          ]
        ],
        "date-time": "2024-07-01T00:00:00Z",
        "timestamp": 1719792000000
      },
      "content-version": "unspecified",
      "delay-in-days": 17440,
      "URL": "https://www.cambridge.org/core/terms"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1976,
        10
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>The possibility of recording the absorption band which is related to oscillations of free OH in a superficial plane of the octahedral sheet of kaolinite inspired the present authors to review the problem of cohesion forces in kaolinite. Structural and spectroscopic criteria as applied to kaolinite proved that the cohesion of adjacent kaolinite layers may be estimated in terms of bent hydrogen bonds. Energy calculations were performed with the aid of a Lennard-Jones function using a modified linear model of the hydrogen bonds. The entire energy is composed of four terms described by the general potential function, van der Waals repulsion and an electrostatic attraction. The energy values of the individual terms are within the limits characteristic of each of them.</jats:p>",
  "DOI": "10.1346/ccmn.1976.0240502",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        8,
        23
      ]
    ],
    "date-time": "2006-08-23T07:31:03Z",
    "timestamp": 1156318263000
  },
  "page": "219-223",
  "source": "Crossref",
  "is-referenced-by-count": 17,
  "title": "New Approach to the Problem of the Interlayer Bonding in Kaolinite",
  "prefix": "10.1017",
  "volume": "24",
  "author": [
    {
      "given": "Tadeusz",
      "family": "Wi\u0119ckowski",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Andrzej",
      "family": "Wiewi\u00f3ra",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "56",
  "published-online": {
    "date-parts": [
      [
        2024,
        7,
        1
      ]
    ]
  },
  "reference": [
    {
      "key": "S0009860400002792_bib8",
      "unstructured": "K\u0119cki, Z. (1975) Podstawy spektroskopii molekularnej. PWN, Warszawa."
    },
    {
      "key": "S0009860400002792_bib21",
      "first-page": "383",
      "volume-title": "Geologica",
      "author": "Wiewi\u00f3ra",
      "year": "1974b"
    },
    {
      "key": "S0009860400002792_bib19",
      "first-page": "45",
      "article-title": "Discusiion on \u201cThe nature of the interlayer bonding in kaolin minerals by Cruz, Jacobs Fripiat\u201d",
      "volume": "1",
      "author": "Wiewi\u00f3ra",
      "year": "1973",
      "journal-title": "Proc. 1972 Int. Clay Conf., Madrid"
    },
    {
      "key": "S0009860400002792_bib16",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150553a017"
    },
    {
      "key": "S0009860400002792_bib14",
      "first-page": "7",
      "volume-title": "Ceramika",
      "volume": "14",
      "author": "Pampuch",
      "year": "1970"
    },
    {
      "key": "S0009860400002792_bib10",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1742196"
    },
    {
      "key": "S0009860400002792_bib13",
      "first-page": "5",
      "volume-title": "Ceramika",
      "volume": "3",
      "author": "Pampuch",
      "year": "1964"
    },
    {
      "key": "S0009860400002792_bib2",
      "unstructured": "Coulson, C. A. (1963) Wiazania chemiczne. PWN, Warszawa."
    },
    {
      "key": "S0009860400002792_bib12",
      "first-page": "177",
      "volume-title": "Correlation of spectroscopic and crystallographic data: Structure and bonding",
      "author": "Novak",
      "year": "1974"
    },
    {
      "key": "S0009860400002792_bib3",
      "unstructured": "Cruz, M. , Jacobs, H. and Fripiat, J. (1963) The nature of the interlayer bonding in kaolin minerals: Proc. Int. Clay Conf. 1972, Madrid, 35\u201344."
    },
    {
      "key": "S0009860400002792_bib18",
      "unstructured": "Szczepaniak, K. (1969) Niekt\u00f3re zagadmienia spektroskopii w podczerwieni s\u0142abych wiaza\u0144 wodorowych: Wiazanie wodorowe, PWN, Warszawa."
    },
    {
      "key": "S0009860400002792_bib7",
      "unstructured": "Jacobs, H. (1971) Etude des hydroxyles de la kaolinite par spectroscopie i.r.: Universit\u00e9 Catholique de Louvain. Dissertation present\u00e9e pour l'obtention du grade de Docteur en Sciences Agronomiques."
    },
    {
      "key": "S0009860400002792_bib22",
      "first-page": "723",
      "article-title": "Potassium acetate intercalation in kaolinite and its removal: effect of material characteristics",
      "volume": "1",
      "author": "Wiewi\u00f3ra",
      "year": "1969",
      "journal-title": "Proc. Int. Clay Conf. Tokyo"
    },
    {
      "key": "S0009860400002792_bib17",
      "first-page": "17",
      "volume-title": "Int. Clay Conf.",
      "author": "Serratosa",
      "year": "1963"
    },
    {
      "key": "S0009860400002792_bib6",
      "first-page": "471",
      "article-title": "Hydroxyl orientation in kaolinite, dickite and nacrite",
      "volume": "58",
      "author": "Giese",
      "year": "1963",
      "journal-title": "Am. Miner."
    },
    {
      "key": "S0009860400002792_bib15",
      "unstructured": "Plusnina, I. I. and Gribina, I. A. (1970) Infrakrasnye spektry kaolinite i montmorillonite v ob\u0142asti valentnykh i deformatyonnych kolebanii OH grupp i vody. Zb.: Svyazana voda v dyspersnykh systemakh Izdatelstvo Moskovskogo Universiteta, Moskva, 25\u201339."
    },
    {
      "key": "S0009860400002792_bib11",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j150568a004"
    },
    {
      "key": "S0009860400002792_bib9",
      "doi-asserted-by": "crossref",
      "unstructured": "Ledoux, R. and White, J. (1964) I.r. studies of the hydroxyl groups in intercalated kaolinite complexes: Proc. 13th Nat. Conf. Madison Wisconsin, 289\u2013315.",
      "DOI": "10.1346/CCMN.1964.0130128"
    },
    {
      "key": "S0009860400002792_bib5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0371-1951(64)80165-X"
    },
    {
      "key": "S0009860400002792_bib4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.145.3637.1189"
    },
    {
      "key": "S0009860400002792_bib1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0584-8539(69)80027-9"
    },
    {
      "key": "S0009860400002792_bib20",
      "first-page": "67",
      "article-title": "X-ray, i.r. and DTA studies of expanded kaolinite",
      "volume": "5",
      "author": "Wiewi\u00f3ra",
      "year": "1974a",
      "journal-title": "Mineralogia Polonica"
    }
  ],
  "container-title": "Clays and Clay Minerals",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0009860400002792",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2025,
        8,
        4
      ]
    ],
    "date-time": "2025-08-04T11:32:32Z",
    "timestamp": 1754307152000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.cambridge.org/core/product/identifier/S0009860400002792/type/journal_article"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1976,
        10
      ]
    ]
  },
  "references-count": 22,
  "journal-issue": {
    "issue": "5",
    "published-print": {
      "date-parts": [
        [
          1976,
          10
        ]
      ]
    }
  },
  "alternative-id": [
    "S0009860400002792"
  ],
  "URL": "http://dx.doi.org/10.1346/CCMN.1976.0240502",
  "relation": {},
  "ISSN": [
    "0009-8604",
    "1552-8367"
  ],
  "subject": [],
  "container-title-short": "Clays and clay miner.",
  "published": {
    "date-parts": [
      [
        1976,
        10
      ]
    ]
  }
}