DOI: 10.1346/ccmn.1975.0230309. Hisingerite Occurring as a Weathering Product of Iron-Rich Saponite

Hisingerite Occurring as a Weathering Product of Iron-Rich Saponite

10.1346/ccmn.1975.0230309

Crossref journal-article

Cambridge University Press (CUP)

Clays and Clay Minerals (56)

Abstract

AbstractHisingerite occurs as a weathering product of iron-rich saponite in rhyolitic tuff of Oya, Tochigi Prefecture. The chemical composition: SiO2, 40·68%; Al2O3, 4·44%; Fe2O3, 28·54%; MgO, 1·85%; CaO, 1·42%; Na2O, 1·50%; K2O, 0·33%; H2O+, 6·43%; H2O−, 13·70%; total 98·89%. Very broad and weak X-ray powder reflections occur at 16, 4·5, 2·5, 1·7 and 1·5 Å, which correspond to the main peaks of nontronite. It is considered that trioctahedral iron-rich saponite was altered to hisingerite, a very poorly crystalline form of nontronite, by oxidation of iron and advanced leaching of octahedral Mg ions.

Bibliography

Kohyama, N., & Sudo, T. (1975). Hisingerite Occurring as a Weathering Product of Iron-Rich Saponite. Clays and Clay Minerals, 23(3), 215â218.

Authors 2

Norihiko Kohyama (first)
Toshio Sudo (additional)

References 8 Referenced 36

{'key': 'S0009860400030883_bib1', 'first-page': '865', 'article-title': 'An iron-rich montmorillonite found in a sediment core from the North Pacific', 'volume': '21', 'author': 'Aoki', 'year': '1974', 'journal-title': 'Deep-Sea Res.'} / Deep-Sea Res. / An iron-rich montmorillonite found in a sediment core from the North Pacific by Aoki (1974)
{'key': 'S0009860400030883_bib6', 'first-page': '1356', 'article-title': 'On the crystal chemistry of hisingerite', 'volume': '47', 'author': 'Lindqvist', 'year': '1962', 'journal-title': 'Am. Miner.'} / Am. Miner. / On the crystal chemistry of hisingerite by Lindqvist (1962)
{'key': 'S0009860400030883_bib7', 'first-page': '618', 'article-title': 'Hisingerite from Japan', 'volume': '37', 'author': 'Sudo', 'year': '1952', 'journal-title': 'Am. Miner.'} / Am. Miner. / Hisingerite from Japan by Sudo (1952)
{'key': 'S0009860400030883_bib8', 'first-page': '1412', 'article-title': 'New data for hisingerite and neotocite', 'volume': '46', 'author': 'Whelan', 'year': '1961', 'journal-title': 'Am. Miner.'} / Am. Miner. / New data for hisingerite and neotocite by Whelan (1961)
10.1016/0371-1951(64)80165-X
{'key': 'S0009860400030883_bib2', 'first-page': '45', 'article-title': 'Thucholite and hisingerite—pitchblende complexes from Nocholson Mine, Saskatchewan, Canada', 'volume': '10', 'author': 'Bowie', 'year': '1955', 'journal-title': 'Bull. Geol. Serv. Great Britain'} / Bull. Geol. Serv. Great Britain / Thucholite and hisingerite—pitchblende complexes from Nocholson Mine, Saskatchewan, Canada by Bowie (1955)
10.1346/CCMN.1973.0210405
{'key': 'S0009860400030883_bib4', 'first-page': '475', 'article-title': 'The structural relationship of non-tronite and montmorillonite', 'volume': '20', 'author': 'Gruner', 'year': '1935', 'journal-title': 'Am. Miner.'} / Am. Miner. / The structural relationship of non-tronite and montmorillonite by Gruner (1935)

Dates

Type	When
Created	18 years, 11 months ago (Sept. 12, 2006, 2:25 a.m.)
Deposited	1 month ago (July 29, 2025, 2:29 a.m.)
Indexed	4 weeks, 1 day ago (Aug. 2, 2025, 3:08 p.m.)
Issued	50 years, 2 months ago (June 1, 1975)
Published	50 years, 2 months ago (June 1, 1975)
Published Online	1 year, 1 month ago (July 1, 2024)
Published Print	50 years, 2 months ago (June 1, 1975)

Funders 0

None

BibTeX

@article{Kohyama_1975, title={Hisingerite Occurring as a Weathering Product of Iron-Rich Saponite}, volume={23}, ISSN={1552-8367}, url={http://dx.doi.org/10.1346/ccmn.1975.0230309}, DOI={10.1346/ccmn.1975.0230309}, number={3}, journal={Clays and Clay Minerals}, publisher={Cambridge University Press (CUP)}, author={Kohyama, Norihiko and Sudo, Toshio}, year={1975}, month=jun, pages={215–218} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>Hisingerite occurs as a weathering product of iron-rich saponite in rhyolitic tuff of Oya, Tochigi Prefecture. The chemical composition: SiO<jats:sub>2</jats:sub>, 40\u00b768%; Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, 4\u00b744%; Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, 28\u00b754%; MgO, 1\u00b785%; CaO, 1\u00b742%; Na<jats:sub>2</jats:sub>O, 1\u00b750%; K<jats:sub>2</jats:sub>O, 0\u00b733%; H<jats:sub>2</jats:sub>O<jats:sup>+</jats:sup>, 6\u00b743%; H<jats:sub>2</jats:sub>O<jats:sup>\u2212</jats:sup>, 13\u00b770%; total 98\u00b789%. Very broad and weak X-ray powder reflections occur at 16, 4\u00b75, 2\u00b75, 1\u00b77 and 1\u00b75 \u00c5, which correspond to the main peaks of nontronite. It is considered that trioctahedral iron-rich saponite was altered to hisingerite, a very poorly crystalline form of nontronite, by oxidation of iron and advanced leaching of octahedral Mg ions.</jats:p>",
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