DOI: 10.1246/cl.2006.546. Galvanostatic Transient Studies on Copper Coordination Polymer under Hydrogen Absorption

Galvanostatic Transient Studies on Copper Coordination Polymer under Hydrogen Absorption

10.1246/cl.2006.546

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Hydrogen electrode reaction (HER) was investigated for a copper coordination polymer, catena-μ-N,N′-bis(hydroxyethyl)dithiooxamidatocopper(II) (CuCP) by galvanostatic transient measurements using a palladium cathode. Individual steps in the Volmer–Tafel reaction were successfully observed for the colloidal CuCP in alkaline solution under hydrogen absorption. The Volmer step was found to be promoted with CuCP and its hydrogen-absorbed polymer (CuCPH) from shorter decay times in transient curves and smaller overpotentials in Tafel plots. In contrast, the inhibition of the Tafel step was observed, which is due to the larger overpotentials. Difference in reducibility between the polymers and plausible reduction mechanisms is discussed.

Bibliography

Fujishima, M., Enyo, M., Kanda, S., Ikeda, R., & Kitagawa, H. (2006). Galvanostatic Transient Studies on Copper Coordination Polymer under Hydrogen Absorption. Chemistry Letters, 35(5), 546â547.

Authors 5

Musashi Fujishima (first)
Michio Enyo (additional)
Seiichi Kanda (additional)
Ryuichi Ikeda (additional)
Hiroshi Kitagawa (additional)

References 16 Referenced 6

Dates

Type	When
Created	19 years, 3 months ago (May 5, 2006, 1:45 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 9:24 a.m.)
Indexed	1 year, 7 months ago (Jan. 19, 2024, 7:02 p.m.)
Issued	19 years, 4 months ago (May 1, 2006)
Published	19 years, 4 months ago (May 1, 2006)
Published Online	19 years, 3 months ago (May 5, 2006)
Published Print	19 years, 4 months ago (May 1, 2006)

Funders 0

None

BibTeX

@article{Fujishima_2006, title={Galvanostatic Transient Studies on Copper Coordination Polymer under Hydrogen Absorption}, volume={35}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.2006.546}, DOI={10.1246/cl.2006.546}, number={5}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Fujishima, Musashi and Enyo, Michio and Kanda, Seiichi and Ikeda, Ryuichi and Kitagawa, Hiroshi}, year={2006}, month=may, pages={546–547} }

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