DOI: 10.1246/cl.2005.344. Ruthenium(II) Tricarboxyterpyridyl Complex with a Fluorine-substituted β-Diketonato Ligand for Highly Efficient Dye-sensitized Solar Cells

Ruthenium(II) Tricarboxyterpyridyl Complex with a Fluorine-substituted β-Diketonato Ligand for Highly Efficient Dye-sensitized Solar Cells

10.1246/cl.2005.344

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract We have developed a new β-diketonato Ru(II) complex, Ru(4,4′,4″-tricarboxy-2,2′:6′,2″-terpyridine) [4,4,4-trifluoro-1-(4-fluorophenyl)butane-1,3-dionato](NCS)[(C4H9)4N]2 (1) which shows very efficient panchromatic sensitization of nanocrystalline TiO2 solar cell over the whole visible range extending into the near IR region (ca. 950 nm). A solar energy conversion efficiency of 8.9% was attained under standard AM 1.5 irradiation (100 mW cm−2) with a short-circuit photocurrent density of 20.4 mA cm−2, an open-circuit photovoltage of 0.65 V, and a fill factor of 0.67.

Bibliography

Islam, A., Chowdhury, F. A., Chiba, Y., Komiya, R., Fuke, N., Ikeda, N., & Han, L. (2005). Ruthenium(II) Tricarboxyterpyridyl Complex with a Fluorine-substituted Î²-Diketonato Ligand for Highly Efficient Dye-sensitized Solar Cells. Chemistry Letters, 34(3), 344â345.

Authors 7

Ashraful Islam (first)
Firoz A Chowdhury (additional)
Yasuo Chiba (additional)
Ryoichi Komiya (additional)
Nobuhiro Fuke (additional)
Noriaki Ikeda (additional)
Liyuan Han (additional)

References 16 Referenced 34

10.1038/353737a0
10.1021/ja00067a063
{'key': '2024011922105646900_r3'}
{'key': '2024011922105646900_r4'}
10.1021/la010343q
{'key': '2024011922105646900_r6'}
10.1021/ja003299u
10.1021/ic980340+
{'key': '2024011922105646900_r9'}
10.1246/cl.2004.986
{'key': '2024011922105646900_r11'}
10.1039/B202392J
10.1016/S0022-1139(02)00221-X
{'key': '2024011922105646900_r14'}
{'key': '2024011922105646900_r15'}
10.1021/jp022656f

Dates

Type	When
Created	20 years, 6 months ago (Feb. 7, 2005, 1:05 a.m.)
Deposited	1 year, 7 months ago (Jan. 19, 2024, 5:11 p.m.)
Indexed	1 year, 1 month ago (July 15, 2024, 8:36 a.m.)
Issued	20 years, 6 months ago (Feb. 5, 2005)
Published	20 years, 6 months ago (Feb. 5, 2005)
Published Online	20 years, 6 months ago (Feb. 5, 2005)
Published Print	20 years, 5 months ago (March 1, 2005)

Funders 0

None

BibTeX

@article{Islam_2005, title={Ruthenium(II) Tricarboxyterpyridyl Complex with a Fluorine-substituted β-Diketonato Ligand for Highly Efficient Dye-sensitized Solar Cells}, volume={34}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.2005.344}, DOI={10.1246/cl.2005.344}, number={3}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Islam, Ashraful and Chowdhury, Firoz A and Chiba, Yasuo and Komiya, Ryoichi and Fuke, Nobuhiro and Ikeda, Noriaki and Han, Liyuan}, year={2005}, month=feb, pages={344–345} }

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