DOI: 10.1246/cl.2004.986. Synthesis and Application of Ruthenium(II) Tricarboxyterpyridyl Complex with a Nitrogen Chelete Ligand for Solar Cells Based on Nanocrystalline TiO2 Films

Synthesis and Application of Ruthenium(II) Tricarboxyterpyridyl Complex with a Nitrogen Chelete Ligand for Solar Cells Based on Nanocrystalline TiO2 Films

10.1246/cl.2004.986

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The ethylenediamine Ru(II) tricarboxyterpyridine complex [Ru(tctpy)(en)(NCS)]Cl (1) was newly synthesized, and its photophysical and photovoltaic properties were characterized. Solar cells based on nanocrystalline TiO2 films sensitized with 1 exhibited efficient sensitization over the visible and near-infrared region. These solar cells generated a large short-circuit photocurrent of 17.7 mA cm−2 and an open-circuit potential of 0.68 V under simulated AM 1.5 solar irradiation (100 mW cm−2) with a solar energy conversion efficiency of 8.5%.

Bibliography

Yamaguchi, T., Yanagida, M., Katoh, R., Sugihara, H., & Arakawa, H. (2004). Synthesis and Application of Ruthenium(II) Tricarboxyterpyridyl Complex with a Nitrogen Chelete Ligand for Solar Cells Based on Nanocrystalline TiO2 Films. Chemistry Letters, 33(8), 986â987.

Authors 5

Takeshi Yamaguchi (first)
Masatoshi Yanagida (additional)
Ryuzi Katoh (additional)
Hideki Sugihara (additional)
Hironori Arakawa (additional)

References 14 Referenced 18

10.1038/353737a0
10.1021/ja00067a063
10.1021/ic990916a
10.1021/ja003299u
10.1039/B202392J
10.1021/j100109a029
10.1021/cr00033a003
10.1021/jp021484j
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10.1021/la010343q

Dates

Type	When
Created	21 years, 1 month ago (July 5, 2004, 2:02 a.m.)
Deposited	1 year, 7 months ago (Jan. 20, 2024, 1:50 a.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 2:20 a.m.)
Issued	21 years, 1 month ago (July 5, 2004)
Published	21 years, 1 month ago (July 5, 2004)
Published Online	21 years, 1 month ago (July 5, 2004)
Published Print	21 years, 1 month ago (Aug. 1, 2004)

Funders 0

None

BibTeX

@article{Yamaguchi_2004, title={Synthesis and Application of Ruthenium(II) Tricarboxyterpyridyl Complex with a Nitrogen Chelete Ligand for Solar Cells Based on Nanocrystalline TiO2 Films}, volume={33}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.2004.986}, DOI={10.1246/cl.2004.986}, number={8}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Yamaguchi, Takeshi and Yanagida, Masatoshi and Katoh, Ryuzi and Sugihara, Hideki and Arakawa, Hironori}, year={2004}, month=jul, pages={986–987} }

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