Abstract
Abstract Cellulose, a major component of woody biomass, reacts in hot-compressed water at 350 °C and 160–200 atm in the presence of a supported group 10 metal catalyst (2 wt%) for 10 min to give gas, consisting of hydrogen, carbon dioxide, and methane. Hydrogen was produced in high yield (8.1 mmol/g cellulose) and high selectivity (H2/CH4 = ca. 6) catalyzed by a supported Ni, Pd, or Pt. Among them, Pd supported on Al2O3 particularly had highest catalytic activity for this gasification.
References
13
Referenced
17
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{'key': '2024011803181414600_r3'}
{'key': '2024011803181414600_r4'}
10.1021/ie960119+
10.1021/ie980525o
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{'key': '2024011803181414600_r8'}
10.1016/S0920-5861(98)00277-6
10.1252/jcej.31.131
10.1252/jcej.31.488
10.1016/S0896-8446(98)00059-X
10.1016/S0016-2361(99)00047-2
Dates
Type | When |
---|---|
Created | 20 years, 3 months ago (May 2, 2005, 2:06 a.m.) |
Deposited | 1 year, 7 months ago (Jan. 17, 2024, 10:18 p.m.) |
Indexed | 1 year, 7 months ago (Jan. 17, 2024, 11:08 p.m.) |
Issued | 24 years, 10 months ago (Oct. 1, 2000) |
Published | 24 years, 10 months ago (Oct. 1, 2000) |
Published Online | 20 years, 3 months ago (May 1, 2005) |
Published Print | 24 years, 10 months ago (Oct. 1, 2000) |
@article{Usui_2000, title={Selective Hydrogen Production from Cellulose at Low Temperature Catalyzed by Supported Group 10 Metal}, volume={29}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.2000.1166}, DOI={10.1246/cl.2000.1166}, number={10}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Usui, Yoko and Minowa, Tomoaki and Inoue, Seiichi and Ogi, Tomoko}, year={2000}, month=oct, pages={1166–1167} }