Abstract
Abstract A porphyrin-C60 dyad with an acetylene spacer has been synthesized for the first time. The rate constant for charge separation in the dyad is larger by a factor of about three compared with a porphyrin-C60 dyad with an amide spacer, showing that the triple bond is a good electron transfer mediator.
References
13
Referenced
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Dates
Type | When |
---|---|
Created | 22 years ago (Sept. 1, 2003, 2:32 a.m.) |
Deposited | 1 year, 7 months ago (Jan. 18, 2024, 11:20 a.m.) |
Indexed | 1 year, 7 months ago (Jan. 20, 2024, 3:21 p.m.) |
Issued | 26 years ago (Sept. 1, 1999) |
Published | 26 years ago (Sept. 1, 1999) |
Published Online | 22 years ago (Sept. 1, 2003) |
Published Print | 26 years ago (Sept. 1, 1999) |
@article{Yamada_1999, title={Acceleration of Photoinduced Charge Separation in Porphyrin-C60 Dyad with an Acetylene Spacer}, volume={28}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1999.895}, DOI={10.1246/cl.1999.895}, number={9}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Yamada, Koji and Imahori, Hiroshi and Nishimura, Yoshinobu and Yamazaki, Iwao and Sakata, Yoshiteru}, year={1999}, month=sep, pages={895–896} }