Abstract
Abstract The most stable perfluorocarbon, CF4, was decomposed to CO2 at above 550 °C in the presence of water vapor over AlPO4 in which 10 atomic % of Al ions are substituted by Ce. Catalytic activity slightly decreased within first 50 h and then took a stationary state for succeeding 50 h. No changes in the structure of catalyst were observed after 100 h reaction. Mg pyrophosphate and phosphates of Ca, B, Fe, Zn, Bi, and Ni were not active up to 700 °C. The addition of Ce, La, Pr, Nd, Gd, Yb, Er, or Y into AlPO4 increased the catalytic activity.
References
5
Referenced
44
10.1038/249810a0
{'key': '2024011816005568200_r2'}
{'key': '2024011816005568200_r3'}
{'key': '2024011816005568200_r4'}
10.1023/A:1019094828720
Dates
Type | When |
---|---|
Created | 22 years, 2 months ago (June 2, 2003, 2:07 a.m.) |
Deposited | 1 year, 7 months ago (Jan. 18, 2024, 11:06 a.m.) |
Indexed | 4 weeks ago (Aug. 2, 2025, 12:20 a.m.) |
Issued | 26 years, 3 months ago (May 1, 1999) |
Published | 26 years, 3 months ago (May 1, 1999) |
Published Online | 22 years, 2 months ago (June 1, 2003) |
Published Print | 26 years, 3 months ago (May 1, 1999) |
@article{Takita_1999, title={Catalytic Decomposition of CF4 over AlPO4-Based Catalysts}, volume={28}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1999.417}, DOI={10.1246/cl.1999.417}, number={5}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Takita, Yusaku and Morita, Chiharu and Ninomiya, Maiko and Wakamatsu, Hironori and Nishiguchi, Hiroyasu and Ishihara, Tatsumi}, year={1999}, month=may, pages={417–418} }