DOI: 10.1246/cl.1998.1263. Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, γ-SiW10{Fe(OH2)}2O386−, Including Radical-chain Mechanism

Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, γ-SiW10{Fe(OH2)}2O386−, Including Radical-chain Mechanism

10.1246/cl.1998.1263

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The tetrabutylammonium salt of γ-SiW10{Fe(OH2)}2O386− showed high turnover number of 135-147 for the oxidation of cyclohexane with 1 atm molecular oxygen and the value is of the highest level among silicotungstates with various iron contents and other catalysts reported. Results obtained with radical initiator and scavenger, and the selectivity for oxygenation of adamantane suggest that the reaction involves a radical-chain path.

Bibliography

Nozaki, C., Misono, M., & Mizuno, N. (1998). Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, Î³-SiW10{Fe(OH2)}2O386â, Including Radical-chain Mechanism. Chemistry Letters, 27(12), 1263â1264.

Authors 3

Chika Nozaki (first)
Makoto Misono (additional)
Noritaka Mizuno (additional)

References 24 Referenced 12

{'key': '2024011817442907700_r1'}
{'key': '2024011817442907700_r2'}
10.1016/0010-8545(95)01141-B
{'key': '2024011817442907700_r4'}
10.1021/cr00036a005
10.1021/cr960401q
{'key': '2024011817442907700_r7'}
{'key': '2024011817442907700_r8'}
10.1038/41039
{'key': '2024011817442907700_r10'}
{'key': '2024011817442907700_r11'}
10.1021/ja00046a048
{'key': '2024011817442907700_r13'}
{'key': '2024011817442907700_r14'}
10.1021/jo951970l
10.1016/0304-5102(92)80126-2
{'key': '2024011817442907700_r17'}
10.1002/9780470132586.ch16
10.1021/ic00137a042
10.1021/ja980006c
{'key': '2024011817442907700_r21'}
10.1002/anie.199515871
10.1039/cs9962500229
10.1039/cs9962500237

Dates

Type	When
Created	21 years, 8 months ago (Dec. 22, 2003, 1:02 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 12:51 p.m.)
Indexed	1 year, 7 months ago (Jan. 18, 2024, 7:01 p.m.)
Issued	26 years, 9 months ago (Dec. 1, 1998)
Published	26 years, 9 months ago (Dec. 1, 1998)
Published Online	21 years, 8 months ago (Dec. 19, 2003)
Published Print	26 years, 9 months ago (Dec. 1, 1998)

Funders 0

None

BibTeX

@article{Nozaki_1998, title={Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, γ-SiW10{Fe(OH2)}2O386−, Including Radical-chain Mechanism}, volume={27}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1998.1263}, DOI={10.1246/cl.1998.1263}, number={12}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Nozaki, Chika and Misono, Makoto and Mizuno, Noritaka}, year={1998}, month=dec, pages={1263–1264} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        1,
        19
      ]
    ],
    "date-time": "2024-01-19T00:01:33Z",
    "timestamp": 1705622493303
  },
  "reference-count": 24,
  "publisher": "Oxford University Press (OUP)",
  "issue": "12",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1998,
            12,
            1
          ]
        ],
        "date-time": "1998-12-01T00:00:00Z",
        "timestamp": 912470400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://academic.oup.com/pages/standard-publication-reuse-rights"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1998,
        12,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title>\n               <jats:p>The tetrabutylammonium salt of \u03b3-SiW10{Fe(OH2)}2O386\u2212 showed high turnover number of 135-147 for the oxidation of cyclohexane with 1 atm molecular oxygen and the value is of the highest level among silicotungstates with various iron contents and other catalysts reported. Results obtained with radical initiator and scavenger, and the selectivity for oxygenation of adamantane suggest that the reaction involves a radical-chain path.</jats:p>",
  "DOI": "10.1246/cl.1998.1263",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        12,
        22
      ]
    ],
    "date-time": "2003-12-22T06:02:38Z",
    "timestamp": 1072072958000
  },
  "page": "1263-1264",
  "source": "Crossref",
  "is-referenced-by-count": 12,
  "title": "Oxidation of Cyclohexane with Molecular Oxygen Efficiently Catalyzed by Di-Iron(III)-Substituted Silicotungstate, \u03b3-SiW10{Fe(OH2)}2O386\u2212, Including Radical-chain Mechanism",
  "prefix": "10.1093",
  "volume": "27",
  "author": [
    {
      "given": "Chika",
      "family": "Nozaki",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo"
        }
      ]
    },
    {
      "given": "Makoto",
      "family": "Misono",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo"
        }
      ]
    },
    {
      "given": "Noritaka",
      "family": "Mizuno",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo"
        }
      ]
    }
  ],
  "member": "286",
  "published-online": {
    "date-parts": [
      [
        2003,
        12,
        19
      ]
    ]
  },
  "reference": [
    {
      "key": "2024011817442907700_r1"
    },
    {
      "key": "2024011817442907700_r2"
    },
    {
      "key": "2024011817442907700_r3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0010-8545(95)01141-B"
    },
    {
      "key": "2024011817442907700_r4"
    },
    {
      "key": "2024011817442907700_r5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr00036a005"
    },
    {
      "key": "2024011817442907700_r6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr960401q"
    },
    {
      "key": "2024011817442907700_r7"
    },
    {
      "key": "2024011817442907700_r8"
    },
    {
      "key": "2024011817442907700_r9",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/41039"
    },
    {
      "key": "2024011817442907700_r10"
    },
    {
      "key": "2024011817442907700_r11"
    },
    {
      "key": "2024011817442907700_r12",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00046a048"
    },
    {
      "key": "2024011817442907700_r13"
    },
    {
      "key": "2024011817442907700_r14"
    },
    {
      "key": "2024011817442907700_r15",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo951970l"
    },
    {
      "key": "2024011817442907700_r16",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0304-5102(92)80126-2"
    },
    {
      "key": "2024011817442907700_r17"
    },
    {
      "key": "2024011817442907700_r18",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/9780470132586.ch16"
    },
    {
      "key": "2024011817442907700_r19",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic00137a042"
    },
    {
      "key": "2024011817442907700_r20",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja980006c"
    },
    {
      "key": "2024011817442907700_r21"
    },
    {
      "key": "2024011817442907700_r22",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.199515871"
    },
    {
      "key": "2024011817442907700_r23",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/cs9962500229"
    },
    {
      "key": "2024011817442907700_r24",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/cs9962500237"
    }
  ],
  "container-title": "Chemistry Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/27/12/1263/56072181/cl.1998.1263.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://academic.oup.com/chemlett/article-pdf/27/12/1263/56072181/cl.1998.1263.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        18
      ]
    ],
    "date-time": "2024-01-18T17:51:40Z",
    "timestamp": 1705600300000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://academic.oup.com/chemlett/article/27/12/1263/7402720"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1998,
        12,
        1
      ]
    ]
  },
  "references-count": 24,
  "journal-issue": {
    "issue": "12",
    "published-online": {
      "date-parts": [
        [
          2003,
          12,
          19
        ]
      ]
    },
    "published-print": {
      "date-parts": [
        [
          1998,
          12,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1246/cl.1998.1263",
  "relation": {},
  "ISSN": [
    "0366-7022",
    "1348-0715"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1998,
        12
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1998,
        12,
        1
      ]
    ]
  }
}