DOI: 10.1246/cl.1998.1257. A Substrate Specific Chiral Modifier Activation on Enantio-differentiating Hydrogenation over Tartaric Acid-Modified Raney Nickel

A Substrate Specific Chiral Modifier Activation on Enantio-differentiating Hydrogenation over Tartaric Acid-Modified Raney Nickel

10.1246/cl.1998.1257

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract A comparative study of the reactivities of the hydrogenation of β-ketoesters over tartaric acid-modified and unmodified Raney nickels indicated that a substrate specific activation by the tartaric acid modification is the reason for the almost perfect enantio-differentiation in the reaction of methyl 3-cyclopropyl-3-oxopropanoate (4).

Bibliography

Nakagawa, S., Sugimura, T., & Tai, A. (1998). A Substrate Specific Chiral Modifier Activation on Enantio-differentiating Hydrogenation over Tartaric Acid-Modified Raney Nickel. Chemistry Letters, 27(12), 1257â1258.

Authors 3

Satoshi Nakagawa (first)
Takashi Sugimura (additional)
Akira Tai (additional)

References 7 Referenced 12

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10.1246/bcsj.67.2473
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10.1246/bcsj.51.3559
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Dates

Type	When
Created	21 years, 8 months ago (Dec. 22, 2003, 1:02 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 12:52 p.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 9:52 p.m.)
Issued	26 years, 9 months ago (Dec. 1, 1998)
Published	26 years, 9 months ago (Dec. 1, 1998)
Published Online	21 years, 8 months ago (Dec. 19, 2003)
Published Print	26 years, 9 months ago (Dec. 1, 1998)

Funders 0

None

BibTeX

@article{Nakagawa_1998, title={A Substrate Specific Chiral Modifier Activation on Enantio-differentiating Hydrogenation over Tartaric Acid-Modified Raney Nickel}, volume={27}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1998.1257}, DOI={10.1246/cl.1998.1257}, number={12}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Nakagawa, Satoshi and Sugimura, Takashi and Tai, Akira}, year={1998}, month=dec, pages={1257–1258} }

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