DOI: 10.1246/cl.1998.1199. Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (η5-C5Me5)MCl Complexes (M = Rh and Ir) of (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine

Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (η5-C5Me5)MCl Complexes (M = Rh and Ir) of (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine

10.1246/cl.1998.1199

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract The rhodium and iridium (η5-C5Me5)MCl complexes (3a: M = Rh; 3b: M = Ir) of (1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine were found to be catalyst precursors for asymmetric transfer hydrogenation of acetophenone, 2-acetonaphthone, 1-tetralone, and 1-indanone to give (S)-1-phenylethanol (90% ee), (S)-1-(2-naphthyl)ethanol (85% ee), (S)-1-tetralol (97% ee), and (S)-indanol (99% ee), respectively.

Bibliography

Mashima, K., Abe, T., & Tani, K. (1998). Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (Î·5-C5Me5)MCl Complexes (M = Rh and Ir) of (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine. Chemistry Letters, 27(12), 1199â1200.

Authors 3

Kazushi Mashima (first)
Tomoyuki Abe (additional)
Kazuhide Tani (additional)

References 25 Referenced 158

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10.1021/ar9502341
10.1021/ja00133a037
{'key': '2024011817441376200_r4'}
10.1021/ja954126l
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10.1002/anie.199702851
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{'key': '2024011817441376200_r10'}
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{'key': '2024011817441376200_r12'}
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{'key': '2024011817441376200_r16'}
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10.1016/S0022-328X(97)00378-1
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{'key': '2024011817441376200_r22'}
{'key': '2024011817441376200_r23'}
10.1021/om9507890
{'key': '2024011817441376200_r25'}

Dates

Type	When
Created	21 years, 8 months ago (Dec. 21, 2003, 8:02 p.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 7:51 a.m.)
Indexed	3 months ago (May 28, 2025, 4:04 a.m.)
Issued	26 years, 9 months ago (Dec. 1, 1998)
Published	26 years, 9 months ago (Dec. 1, 1998)
Published Online	21 years, 8 months ago (Dec. 19, 2003)
Published Print	26 years, 9 months ago (Dec. 1, 1998)

Funders 0

None

BibTeX

@article{Mashima_1998, title={Asymmetric Transfer Hydrogenation of Ketonic Substrates Catalyzed by (η5-C5Me5)MCl Complexes (M = Rh and Ir) of (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine}, volume={27}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1998.1199}, DOI={10.1246/cl.1998.1199}, number={12}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Mashima, Kazushi and Abe, Tomoyuki and Tani, Kazuhide}, year={1998}, month=dec, pages={1199–1200} }

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