DOI: 10.1246/cl.1998.1143. Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes in the Presence of Pivalic Anhydride

Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes in the Presence of Pivalic Anhydride

10.1246/cl.1998.1143

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Carboxylic acids are catalytically hydrogenated into corresponding aldehydes by palladium complexes in the presence of pivalic (trimethylacetic) anhydride under H2. Less hindered aliphatic and aromatic acids are reduced to aldehydes in high yields. The method is also applicable to hydrogenation of dibasic carboxylic acids and carboxylic acids containing heterocyclic groups.

Bibliography

Nagayama, K., Shimizu, I., & Yamamoto, A. (1998). Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes in the Presence of Pivalic Anhydride. Chemistry Letters, 27(11), 1143â1144.

Authors 3

Kazuhiro Nagayama (first)
Isao Shimizu (additional)
Akio Yamamoto (additional)

References 7 Referenced 65

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10.1246/bcsj.44.288
10.1246/bcsj.48.2490
10.1021/jo00053a008
10.1021/ja01151a503
10.1016/0926-860X(92)80212-U
{'key': '2024011817441876400_r7'}

Dates

Type	When
Created	21 years, 8 months ago (Dec. 22, 2003, 1:02 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 12:51 p.m.)
Indexed	1 week, 4 days ago (Aug. 23, 2025, 1 a.m.)
Issued	26 years, 10 months ago (Nov. 1, 1998)
Published	26 years, 10 months ago (Nov. 1, 1998)
Published Online	21 years, 8 months ago (Dec. 19, 2003)
Published Print	26 years, 10 months ago (Nov. 1, 1998)

Funders 0

None

BibTeX

@article{Nagayama_1998, title={Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes in the Presence of Pivalic Anhydride}, volume={27}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1998.1143}, DOI={10.1246/cl.1998.1143}, number={11}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Nagayama, Kazuhiro and Shimizu, Isao and Yamamoto, Akio}, year={1998}, month=nov, pages={1143–1144} }

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