DOI: 10.1246/cl.1998.1005. Efficient Photosensitization of Nanocrystalline TiO2 Films by a New Class of Sensitizer: cis-Dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II)

Efficient Photosensitization of Nanocrystalline TiO2 Films by a New Class of Sensitizer: cis-Dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II)

10.1246/cl.1998.1005

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract A new class of ruthenium(II) complexes containing carboxylated 1,10-phenanthroline were synthesized. Photosensitization of nanocrystalline TiO2 electrode by bis(tetrabutylammonium)dihydronium cis-dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II) showed a high incident photon-to-current conversion efficiency (IPCE: 70% at 540 nm). The overall solar-to-electric power conversion efficincy of 6.1% was obtained at AM-1.5 (100 mW/cm2).

Bibliography

Sugihara, H., Singh, L. P., Sayama, K., Arakawa, H., Nazeeruddin, M. K., & GrÃ¤tzel, M. (1998). Efficient Photosensitization of Nanocrystalline TiO2 Films by a New Class of Sensitizer: cis-Dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II). Chemistry Letters, 27(10), 1005â1006.

Authors 6

Hideki Sugihara (first)
Lok Pratap Singh (additional)
Kazuhiro Sayama (additional)
Hironori Arakawa (additional)
Md K Nazeeruddin (additional)
Michael Grätzel (additional)

References 10 Referenced 40

{'key': '2024011817440238400_r1'}
10.1021/ja00067a063
10.1021/j100125a029
10.1021/ja00152a028
10.1021/ic970008i
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{'key': '2024011817440238400_r7'}
10.1021/jp970683d
10.1002/jhet.5570180332
{'key': '2024011817440238400_r10'}

Dates

Type	When
Created	21 years, 9 months ago (Nov. 20, 2003, 1:02 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 12:50 p.m.)
Indexed	1 year, 2 months ago (May 31, 2024, 9:32 p.m.)
Issued	26 years, 10 months ago (Oct. 1, 1998)
Published	26 years, 10 months ago (Oct. 1, 1998)
Published Online	21 years, 9 months ago (Nov. 19, 2003)
Published Print	26 years, 10 months ago (Oct. 1, 1998)

Funders 0

None

BibTeX

@article{Sugihara_1998, title={Efficient Photosensitization of Nanocrystalline TiO2 Films by a New Class of Sensitizer: cis-Dithiocyanato bis(4,7-dicarboxy-1,10-phenanthroline)ruthenium(II)}, volume={27}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1998.1005}, DOI={10.1246/cl.1998.1005}, number={10}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Sugihara, Hideki and Singh, Lok Pratap and Sayama, Kazuhiro and Arakawa, Hironori and Nazeeruddin, Md K and Grätzel, Michael}, year={1998}, month=oct, pages={1005–1006} }

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