DOI: 10.1246/cl.1996.27. Crystal Structure of [Ru(bpy)2(CO)(<i>η</i>1-C(O)OH)]+ (bpy = 2,2′-bipyridine) as a Key Intermediate in CO2/CO Conversion

Crystal Structure of [Ru(bpy)2(CO)(η1-C(O)OH)]+ (bpy = 2,2′-bipyridine) as a Key Intermediate in CO2/CO Conversion

10.1246/cl.1996.27

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Molecular structure of [Ru(bpy)2(CO)(η1-C(O)OH)](CF3SO3)(H2O) (bpy = 2,2′-bipyridine) has revealed that protonation of [Ru(η1-CO2)(bpy)2(CO)] as a key step in CO2/CO conversion shortens the Ru-C(O)OH bond distance compared with the Ru-CO2 one due to enhancement of dπ-pπ* interaction in the former.

Bibliography

Toyohara, K., Nagao, H., Adachi, T., Yoshida, T., & Tanaka, K. (1996). Crystal Structure of [Ru(bpy)2(CO)(Î·1-C(O)OH)]+ (bpy = 2,2â²-bipyridine) as a Key Intermediate in CO2/CO Conversion. Chemistry Letters, 25(1), 27â28.

Authors 5

Kiyotsuna Toyohara (first)
Hirotaka Nagao (additional)
Tomohiro Adachi (additional)
Toshikatsu Yoshida (additional)
Koji Tanaka (additional)

References 13 Referenced 31

Dates

Type	When
Created	19 years, 6 months ago (March 1, 2006, 1:23 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 1:02 p.m.)
Indexed	1 year, 7 months ago (Jan. 20, 2024, 12:27 a.m.)
Issued	29 years, 8 months ago (Jan. 1, 1996)
Published	29 years, 8 months ago (Jan. 1, 1996)
Published Online	19 years, 6 months ago (March 1, 2006)
Published Print	29 years, 8 months ago (Jan. 1, 1996)

Funders 0

None

BibTeX

@article{Toyohara_1996, title={Crystal Structure of [Ru(bpy)2(CO)(η1-C(O)OH)]+ (bpy = 2,2′-bipyridine) as a Key Intermediate in CO2/CO Conversion}, volume={25}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1996.27}, DOI={10.1246/cl.1996.27}, number={1}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Toyohara, Kiyotsuna and Nagao, Hirotaka and Adachi, Tomohiro and Yoshida, Toshikatsu and Tanaka, Koji}, year={1996}, month=jan, pages={27–28} }

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