DOI: 10.1246/cl.1993.327. Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active α-Alkoxycarbonyl-β-ketoiminato Manganese(III) Complexes

Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active α-Alkoxycarbonyl-β-ketoiminato Manganese(III) Complexes

10.1246/cl.1993.327

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract Optically active N,N′-ethylenebis(α-alkoxycarbonyl-β-ketoimine) was found to be a new class of effective ligand of manganese(III) complex catalyst for the asymmetric aerobic epoxidation of simple olefins, such as 1,2-dihydronaphthalene derivatives, to afford the corresponding optically active epoxides with good to high enantioselectivities.

Bibliography

Mukaiyama, T., Yamada, T., Nagata, T., & Imagawa, K. (1993). Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active Î±-Alkoxycarbonyl-Î²-ketoiminato Manganese(III) Complexes. Chemistry Letters, 22(2), 327â330.

Authors 4

Teruaki Mukaiyama (first)
Tohru Yamada (additional)
Takushi Nagata (additional)
Kiyomi Imagawa (additional)

References 24 Referenced 105

10.1021/ba-1963-0037.ch005
10.1002/9780470166086.ch6
10.1016/S0010-8545(00)80203-9
10.1016/S0010-8545(00)80090-9
10.1016/S0010-8545(00)80087-9
{'key': '2024011821281109900_r6'}
10.1007/BFb0118884
10.1246/bcsj.63.179
{'key': '2024011821281109900_r9'}
10.1246/bcsj.64.2109
{'key': '2024011821281109900_r11'}
{'key': '2024011821281109900_r12'}
{'key': '2024011821281109900_r13'}
10.1002/jlac.19616410102
10.1016/S0040-4039(00)88562-7
10.1021/ic50172a022
10.1246/bcsj.54.3743
{'key': '2024011821281109900_r18'}
{'key': '2024011821281109900_r19'}
{'key': '2024011821281109900_r20'}
10.1021/jo00834a076
10.1021/ja00163a052
{'key': '2024011821281109900_r23'}
{'key': '2024011821281109900_r24'}

Dates

Type	When
Created	19 years, 5 months ago (March 21, 2006, 12:57 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 4:28 p.m.)
Indexed	3 days, 19 hours ago (Aug. 28, 2025, 8:44 a.m.)
Issued	32 years, 7 months ago (Feb. 1, 1993)
Published	32 years, 7 months ago (Feb. 1, 1993)
Published Online	19 years, 5 months ago (March 21, 2006)
Published Print	32 years, 7 months ago (Feb. 1, 1993)

Funders 0

None

BibTeX

@article{Mukaiyama_1993, title={Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active α-Alkoxycarbonyl-β-ketoiminato Manganese(III) Complexes}, volume={22}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1993.327}, DOI={10.1246/cl.1993.327}, number={2}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Mukaiyama, Teruaki and Yamada, Tohru and Nagata, Takushi and Imagawa, Kiyomi}, year={1993}, month=feb, pages={327–330} }

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