DOI: 10.1246/cl.1993.1409. Mechanistic Studies on Oxidation Reaction of Ethane-Bridged Porphyrin Dimers to <i>trans</i>-Ethylene-Bridged Species

Mechanistic Studies on Oxidation Reaction of Ethane-Bridged Porphyrin Dimers to trans-Ethylene-Bridged Species

10.1246/cl.1993.1409

Crossref journal-article

Oxford University Press (OUP)

Chemistry Letters (286)

Abstract

Abstract A facile aerobic oxidation of 1,2-bis(meso-octaethylporphyrinyl)ethane and other similar dimers to the corresponding trans-1,2-bis(meso-porphyrinyl)ethenes in several organic acids has been studied by UV-vis and 1H NMR spectroscopy and the general mechanism of the oxidation has been proposed. The key step of the oxidation is monoprotonation of the two porphyrin rings in dimer followed by two electron oxidation.

Bibliography

Borovkov, V. V., Ponomarev, G. V., Ishida, A., Kaneda, T., & Sakata, Y. (1993). Mechanistic Studies on Oxidation Reaction of Ethane-Bridged Porphyrin Dimers to trans-Ethylene-Bridged Species. Chemistry Letters, 22(8), 1409â1412.

Authors 5

Victor V Borovkov (first)
Gelii V Ponomarev (additional)
Akito Ishida (additional)
Takahiro Kaneda (additional)
Yoshiteru Sakata (additional)

References 14 Referenced 13

10.1021/cr00011a005
10.1021/ja00038a066
10.1021/ja00009a058
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10.1016/S0040-4039(00)60369-6
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Dates

Type	When
Created	19 years, 4 months ago (April 28, 2006, 2:20 a.m.)
Deposited	1 year, 7 months ago (Jan. 18, 2024, 4:59 p.m.)
Indexed	1 year, 7 months ago (Jan. 18, 2024, 7:02 p.m.)
Issued	32 years, 1 month ago (Aug. 1, 1993)
Published	32 years, 1 month ago (Aug. 1, 1993)
Published Online	19 years, 4 months ago (April 27, 2006)
Published Print	32 years, 1 month ago (Aug. 1, 1993)

Funders 0

None

BibTeX

@article{Borovkov_1993, title={Mechanistic Studies on Oxidation Reaction of Ethane-Bridged Porphyrin Dimers to trans-Ethylene-Bridged Species}, volume={22}, ISSN={1348-0715}, url={http://dx.doi.org/10.1246/cl.1993.1409}, DOI={10.1246/cl.1993.1409}, number={8}, journal={Chemistry Letters}, publisher={Oxford University Press (OUP)}, author={Borovkov, Victor V and Ponomarev, Gelii V and Ishida, Akito and Kaneda, Takahiro and Sakata, Yoshiteru}, year={1993}, month=aug, pages={1409–1412} }

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